HRP20230536T1 - Stabilizirani pripravci fluoroolefina i postupci za njihovu proizvodnju, skladištenje i uporabu - Google Patents

Stabilizirani pripravci fluoroolefina i postupci za njihovu proizvodnju, skladištenje i uporabu Download PDF

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HRP20230536T1
HRP20230536T1 HRP20230536TT HRP20230536T HRP20230536T1 HR P20230536 T1 HRP20230536 T1 HR P20230536T1 HR P20230536T T HRP20230536T T HR P20230536TT HR P20230536 T HRP20230536 T HR P20230536T HR P20230536 T1 HRP20230536 T1 HR P20230536T1
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hfc
hfo
group
composition according
preparation
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HRP20230536TT
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Sheng Peng
Jian SUN-BLANKS
Barbara Haviland Minor
Brian E. KIPP
Mary E. Koban
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The Chemours Company Fc, Llc
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Publication of HRP20230536T1 publication Critical patent/HRP20230536T1/hr

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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/04Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M171/00Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
    • C10M171/008Lubricant compositions compatible with refrigerants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B13/00Compression machines, plants or systems, with reversible cycle
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/102Alcohols
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/106Carbon dioxide
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    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/122Halogenated hydrocarbons
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    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10Components
    • C09K2205/12Hydrocarbons
    • C09K2205/126Unsaturated fluorinated hydrocarbons
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/22All components of a mixture being fluoro compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • C10M2201/022Hydrogen peroxide; Oxygenated water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/063Peroxides
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/04Well-defined cycloaliphatic compounds
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/06Peroxides; Ozonides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09Characteristics associated with water
    • C10N2020/097Refrigerants
    • C10N2020/101Containing Hydrofluorocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/30Refrigerators lubricants or compressors lubricants

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Fire-Extinguishing Compositions (AREA)
  • Paints Or Removers (AREA)

Claims (14)

1. Pripravak koji sadrži najmanje jedan fluorolefin i 10 do 2,000 ppm po težini najmanje jednog inhibitora izabranog iz grupe koja se sastoji od limonena, α-terpinena i α-tokoferola koji smanjuje konverziju fluorolefina u oligomere ili polimere, i pri čemu pripravak sadrži manje od 1 tež.% oligomernih, homopolimera ili drugih polimernih proizvoda porijeklom od fluorolefina, pri čemu fluorolefin sadrži najmanje jedan član od HFO-1234yf i HFO-1234ze, i pri čemu pripravak dalje sadrži najmanje jedan član izabran iz grupe koja se sastoji od HCC-40, HCFC-22, CFC-115, HCFC-124, HCFC-1122 i CFC-1113.
2. Pripravak prema zahtjevu 1, naznačen time što pripravak sadrži manje od 0.03 tež.% oligomernih, homopolimera ili drugih polimernih proizvoda.
3. Pripravak prema zahtjevu 1 ili 2, koji dalje sadrži najmanje jedan član izabran iz grupe koja se sastoji od zraka, kisika, kumen hidroperoksida i fluorolefinskih poliperoksida, peroksida, hidroperoksida, persulfata, perkarbonata, perborata i hidropersulfata.
4. Pripravak prema bilo kojem od zahtjeva 1 do 3, naznačen time što inhibitor sadrži najmanje jedan od limonena i α-terpinena.
5. Pripravak prema bilo kojem od zahtjeva 1 do 4, koji dalje sadrži najmanje jedan lubrikant.
6. Pripravak prema bilo kojem od zahtjeva 1 do 5, koji dalje sadrži najmanje jedan član izabran iz grupe koja se sastoji od HFC-32, HFC-125, HFC-134a, HFC-152a, 236fa, HFC-227ea i ugljik-dioksida.
7. Pripravak prema bilo kojem od zahtjeva 1 do 6, koji dalje sadrži najmanje jedan član izabran iz grupe koja se sastoji od HFC-134a, HFO-1243zf, HFO-1225ye, HFO-1234ze, 3,3,3-trifluoro-1-propin, HCFO-1233xf, HFC-244bb i HFC-245cb.
8. Pripravak prema bilo kojem od zahtjeva 1 do 7, naznačen time što je inhibitor prisutan u količini od 10 do 1,000 ppm.
9. Pripravak prema bilo kojem od zahtjeva 1 do 8 koji dalje sadrži najmanje jedan antioksidans izabran iz grupe koja se sastoji od butiliranog hidroksitoluena, butiliranog hidroksianizola, tercijarnog-butilhidrokinona, galata, 2-fenil-2-propanola, 1-(2,4,5-trihidroksifenil)-1-butanona, fenola, derivata bisfenol metana i 2,2'-metilen bis (4-metil-6-t-butil fenola).
10. Pripravak prema bilo kojem od zahtjeva 1 do 9, naznačen time što inhibitor sadrži tekućinu na temperaturi od -80 do 180°C.
11. Pripravak prema bilo kojem od zahtjeva 1 do 10 koji dalje sadrži najmanje jedan član izabranog iz grupe koja se sastoji od HFO-1225yeZ, HFO-1243zf, HFO-1234ze, HFC-236ea, HFC-245fa i 3,3,3-trifluoropropin, poželjno pri čemu član sadrži HFO-1234ze, HFO-1225yeZ i 3,3,3-trifluoropropin.
12. Pripravak prema bilo kojem od zahtjeva 1 do 11, naznačen time što je u biti bez najmanje jednog od amonijaka i CF3I.
13. Postupak za zagrijavanje ili hlađenje uporabom pripravka prema bilo kojem od zahtjeva 1 do 12.
14. Kontejner sa rashladnim sredstvom koji sadrži pripravak prema bilo kojem od zahtjeva 1 do 12.
HRP20230536TT 2018-04-30 2019-04-30 Stabilizirani pripravci fluoroolefina i postupci za njihovu proizvodnju, skladištenje i uporabu HRP20230536T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862664751P 2018-04-30 2018-04-30
EP19723293.7A EP3775091B1 (en) 2018-04-30 2019-04-30 Stabilized fluoroolefin compositions and methods for their production, storage and usage
PCT/US2019/029777 WO2019213004A1 (en) 2018-04-30 2019-04-30 Stabilized fluoroolefin compositions and methods for their production, storage and usage

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HRP20230536T1 true HRP20230536T1 (hr) 2023-08-04

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HRP20230536TT HRP20230536T1 (hr) 2018-04-30 2019-04-30 Stabilizirani pripravci fluoroolefina i postupci za njihovu proizvodnju, skladištenje i uporabu
HRP20230824TT HRP20230824T8 (hr) 2018-04-30 2019-04-30 Stabilizirani pripravci fluoroolefina i postupak za njihovu proizvodnju, skladištenje i uporabu
HRP20221489TT HRP20221489T1 (hr) 2018-04-30 2019-10-29 Stabilizirane kompozicije flouroolefina i postupci za njihovu proizvodnju, skladištenje i primjenu

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HRP20221489TT HRP20221489T1 (hr) 2018-04-30 2019-10-29 Stabilizirane kompozicije flouroolefina i postupci za njihovu proizvodnju, skladištenje i primjenu

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US (4) US20210108119A1 (hr)
EP (9) EP3775091B1 (hr)
JP (6) JP7332629B2 (hr)
KR (3) KR20210002626A (hr)
CN (3) CN112074585A (hr)
AU (3) AU2019261937A1 (hr)
BR (3) BR112020017602A2 (hr)
CA (3) CA3091689A1 (hr)
CY (1) CY1126114T1 (hr)
DK (4) DK3775091T3 (hr)
ES (3) ES2951148T3 (hr)
FI (4) FI4206298T3 (hr)
HR (3) HRP20230536T1 (hr)
HU (3) HUE062279T2 (hr)
LT (4) LT4206298T (hr)
MX (3) MX2020009298A (hr)
PL (3) PL3978580T3 (hr)
PT (4) PT4206298T (hr)
RS (3) RS64327B1 (hr)
SI (3) SI3978580T1 (hr)
WO (3) WO2019213004A1 (hr)

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KR20240035834A (ko) 2021-07-15 2024-03-18 더 케무어스 컴퍼니 에프씨, 엘엘씨 Hfo-1234yf, hfc-32, 및 hfc-152a의 조성물, 및 조성물을 사용하기 위한 시스템
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WO2023229963A1 (en) 2022-05-23 2023-11-30 The Chemours Company Fc, Llc High purity fluoroolefin compositions and methods of impurity removal
WO2023229995A2 (en) 2022-05-23 2023-11-30 The Chemours Company Fc, Llc Systems, equipment and methods for stabilizing hydrofluoroolefins in refrigerant systems
WO2023229983A1 (en) 2022-05-23 2023-11-30 The Chemours Company Fc, Llc Integrated system and process for producing reclaimed, stabilized and traceable refrigerant compositions

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