HRP20220930T1 - Postupak proizvodnje zamjenskog zemnog plina iz sinteznog plina - Google Patents

Postupak proizvodnje zamjenskog zemnog plina iz sinteznog plina Download PDF

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HRP20220930T1
HRP20220930T1 HRP20220930TT HRP20220930T HRP20220930T1 HR P20220930 T1 HRP20220930 T1 HR P20220930T1 HR P20220930T T HRP20220930T T HR P20220930TT HR P20220930 T HRP20220930 T HR P20220930T HR P20220930 T1 HRP20220930 T1 HR P20220930T1
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Croatia
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gas
produced
hydrogen
synthesis gas
methane
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HRP20220930TT
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Chris Chapman
Massimiliano MATERAZZI
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Advanced Plasma Power Limited
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
    • C01B3/047—Decomposition of ammonia
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/094—Char
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C10J2300/1238—Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/02—Combustion or pyrolysis
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/04—Gasification
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/06—Heat exchange, direct or indirect
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/36—Applying radiation such as microwave, IR, UV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/38—Applying an electric field or inclusion of electrodes in the apparatus
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/42—Fischer-Tropsch steps
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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Claims (15)

1. Postupak proizvodnje zamjenskog zemnog plina, gdje se postupak sastoji od koraka: (1) osiguravanja sinteznog plina koji sadrži vodik i ugljični monoksid; (2) dobivanja sinteznog plina obogaćen vodikom; (3) podvrgavanja sinteznog plina obogaćen vodikom reakciji metaniziranja kako bi se prevelo barem dio plina u metan, čime se dobije plin obogaćen metanom; i (4) rekuperiranja iz plina obogaćenog metanom plina koji sadrži metan, pri čemu se korak (2) sastoji u osiguravanju plinovitog vodika i kombiniranju plinovitog vodika sa sinteznim plinom, pri čemu: (i) barem dio plinovitog vodika se proizvodi razgradnjom amonijaka i/ili (ii) barem dio plinovitog vodika se proizvodi reformiranjem vodenom parom ugljikovodičnog polaznog materijala.
2. Postupak u skladu s patentnim zahtjevom 1, pri čemu se barem dio plinovitog vodika proizvodi elektrolizom vode.
3. Postupak u skladu s patentnim zahtjevom 1 ili patentnim zahtjevom 2, pri čemu se barem dio plinovitog vodika proizvodi razgradnjom amonijaka kojeg se dobiva Haber-Boschovim postupkom i/ili sintezom amonijaka u čvrstom stanju.
4. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se barem dio plinovitog vodika dobije pirolizom i/ili krekiranjem ugljikovodika, po mogućnosti, pri čemu je piroliza i/ili krekiranje ugljikovodika dio postupka proizvodnje industrijske čađe.
5. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se barem dio plinovitog vodika proizvodi reformiranjem vodenom parom ugljikovodičnog polaznog materijala koji je metan.
6. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se barem dio plinovitog vodika proizvodi reformiranjem vodenom parom ugljikovodičnog polaznog materijala, a barem dio plinovitog vodika se proizvodi reakcijom pretvorbe vodenog plina, te pri čemu se reakciju pretvorbe vodenog plina provodi na ugljičnom monoksidu dobivenom reformiranjem vodenom parom.
7. Postupak u skladu s patentnim zahtjevom 6, pri čemu se ugljični dioksid dobiven u reakciji pretvorbe vodenog plina podvrgava Sabatierovoj reakciji kako bi se proizvelo metan i vodu, po mogućnosti pri čemu barem dio metana dobivenog Sabatierovom reakcijom se reciklira kako bi ga se upotrijebilo kao ugljikovodični polazni materijal u koraku reformiranja metana vodenom parom.
8. Postupak u skladu s patentnim zahtjevom 7, pri čemu se vodik namijenjen upotrebi u Sabatierovoj reakciji proizvodi elektrolizom vode, gdje, po mogućnosti, kisik dobiven elektrolizom vode: reagira s polaznim materijalom kako bi se proizvelo sintezni plin za korak (1); i/ili upotrebljava u koraku reformiranja vodenom parom.
9. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se korak (3) sastoji u podvrgavanju plina obogaćenog metanom u Sabatierovoj reakciji kako bi se prevelo barem dio bilo koje količine prisutnog ugljičnog dioksida u metan.
10. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se toplinu koju stvaraju egzotermne reakcije u postupku rekuperira uz pomoć izmjenjivača topline, gdje se rekuperiranu toplinu upotrebljava za predgrijavanje sinteznog plina prije koraka (2) i/ili za predgrijavanje sinteznog plina obogaćenog vodikom prije koraka (3).
11. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu sintezni plin obogaćen vodikom ima omjer između ugljičnog monoksida i ugljičnog dioksida od 3 ili više, po mogućnosti 5 ili više, poželjnije 10 ili više.
12. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se sintezni plin proizvodi rasplinjavanjem i/ili obradom plazmom i/ili pirolizom i/ili izgaranjem i/ili toplinskom pretvorbom polaznog materijala, po mogućnosti pri čemu je polazni materijal otpadni materijal i/ili sadrži biomasu.
13. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se sintezni plin proizvodi u postupku obrade otpada koji se sastoji u: (i) koraku rasplinjavanja koji se sastoji u obradi otpada u jedinici za rasplinjavanje u prisutnosti kisika i vodene pare kako bi se proizvelo plin izgaranja i čvrsti karbonizirani materijal koji nije suspendiran u zraku; i (ii) koraku obrade plazmom koji se sastoji u podvrgavanju plina izgaranja i čvrstog karboniziranog materijala koji nije suspendiran u zraku obradi plazmom u jedinici za obradu plazmom u prisutnosti kisika i, izborno, vodene pare, pri čemu je jedinica za obradu plazmom odvojena od jedinice za rasplinjavanje.
14. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, pri čemu se sintezni plin proizvodi: (i) toplinskom obradom polaznog materijala kako bi se proizvelo sintezni plin; i (ii) obradom sinteznog plina plazmom u jedinici za obradu plazmom u prisutnosti dodatnog ugljičnog dioksida kako bi se proizvelo refinirani sintezni plin, pri čemu se dodatni ugljični dioksid dodaje polaznom materijalu tijekom toplinske obrade i/ili sinteznom plinu prije obrade plazmom i/ili uvodi u jedinicu za obradu plazmom.
15. Postupak u skladu s bilo kojim od prethodnih patentnih zahtjeva, gdje postupak dodatno uključuje izgaranje zamjenskog zemnog plina kao goriva, izborno u kombinaciji s barem dijelom zemnog plina.
HRP20220930TT 2015-06-04 2016-06-03 Postupak proizvodnje zamjenskog zemnog plina iz sinteznog plina HRP20220930T1 (hr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1509684.5A GB2539021A (en) 2015-06-04 2015-06-04 Process for producing a substitute natural gas
PCT/GB2016/051647 WO2016193751A1 (en) 2015-06-04 2016-06-03 Process for producing a substitute natural gas from synthesis gas
EP16727818.3A EP3303524B1 (en) 2015-06-04 2016-06-03 Process for producing a substitute natural gas from synthesis gas

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HRP20220930T1 true HRP20220930T1 (hr) 2022-10-28

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US (1) US20180171250A1 (hr)
EP (1) EP3303524B1 (hr)
ES (1) ES2922890T3 (hr)
GB (1) GB2539021A (hr)
HR (1) HRP20220930T1 (hr)
PL (1) PL3303524T3 (hr)
PT (1) PT3303524T (hr)
WO (1) WO2016193751A1 (hr)

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FR3038908A1 (fr) * 2015-07-16 2017-01-20 Gdf Suez Dispositif et procede de production de gaz de synthese
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