HRP20170073T1 - Pripravak otapala na bazi oksida organskog sulfida zamaskiranog mirisa - Google Patents
Pripravak otapala na bazi oksida organskog sulfida zamaskiranog mirisa Download PDFInfo
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- HRP20170073T1 HRP20170073T1 HRP20170073TT HRP20170073T HRP20170073T1 HR P20170073 T1 HRP20170073 T1 HR P20170073T1 HR P20170073T T HRP20170073T T HR P20170073TT HR P20170073 T HRP20170073 T HR P20170073T HR P20170073 T1 HRP20170073 T1 HR P20170073T1
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- 239000000203 mixture Substances 0.000 title claims 15
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 title claims 3
- 239000002904 solvent Substances 0.000 title claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 23
- 239000003795 chemical substances by application Substances 0.000 claims 16
- 230000000873 masking effect Effects 0.000 claims 16
- -1 alkyl radical Chemical class 0.000 claims 14
- 150000002576 ketones Chemical class 0.000 claims 11
- 239000004215 Carbon black (E152) Substances 0.000 claims 8
- 229930195733 hydrocarbon Natural products 0.000 claims 8
- 150000002430 hydrocarbons Chemical class 0.000 claims 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 7
- 150000001298 alcohols Chemical class 0.000 claims 7
- 125000004122 cyclic group Chemical group 0.000 claims 7
- 150000003505 terpenes Chemical class 0.000 claims 7
- 235000007586 terpenes Nutrition 0.000 claims 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 6
- 150000005690 diesters Chemical class 0.000 claims 6
- 150000005691 triesters Chemical class 0.000 claims 6
- 150000001299 aldehydes Chemical class 0.000 claims 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 claims 4
- 150000005840 aryl radicals Chemical class 0.000 claims 4
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 claims 4
- HCRBXQFHJMCTLF-ZCFIWIBFSA-N ethyl (2r)-2-methylbutanoate Chemical compound CCOC(=O)[C@H](C)CC HCRBXQFHJMCTLF-ZCFIWIBFSA-N 0.000 claims 4
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 claims 4
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 claims 4
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 claims 4
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 claims 4
- PQLMXFQTAMDXIZ-UHFFFAOYSA-N isoamyl butyrate Chemical compound CCCC(=O)OCCC(C)C PQLMXFQTAMDXIZ-UHFFFAOYSA-N 0.000 claims 4
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 claims 4
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 3
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 3
- FLKPEMZONWLCSK-UHFFFAOYSA-N phthalic acid di-n-ethyl ester Natural products CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000001069 triethyl citrate Substances 0.000 claims 3
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims 3
- 235000013769 triethyl citrate Nutrition 0.000 claims 3
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 claims 2
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims 2
- WEEGYLXZBRQIMU-UHFFFAOYSA-N Eucalyptol Chemical compound C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims 2
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 claims 2
- QUMXDOLUJCHOAY-UHFFFAOYSA-N alpha-methylbenzyl acetate Natural products CC(=O)OC(C)C1=CC=CC=C1 QUMXDOLUJCHOAY-UHFFFAOYSA-N 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 claims 2
- 229940007550 benzyl acetate Drugs 0.000 claims 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims 2
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims 2
- 150000001860 citric acid derivatives Chemical class 0.000 claims 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims 2
- 239000006184 cosolvent Substances 0.000 claims 2
- KSMVZQYAVGTKIV-UHFFFAOYSA-N decanal Chemical compound CCCCCCCCCC=O KSMVZQYAVGTKIV-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 239000001813 ethyl (2R)-2-methylbutanoate Substances 0.000 claims 2
- 229940090910 ethyl 2-methylbutyrate Drugs 0.000 claims 2
- 125000005842 heteroatom Chemical group 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 229940117955 isoamyl acetate Drugs 0.000 claims 2
- 229940094941 isoamyl butyrate Drugs 0.000 claims 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims 2
- 150000002690 malonic acid derivatives Chemical class 0.000 claims 2
- UODXCYZDMHPIJE-UHFFFAOYSA-N menthanol Chemical compound CC1CCC(C(C)(C)O)CC1 UODXCYZDMHPIJE-UHFFFAOYSA-N 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- NDVASEGYNIMXJL-UHFFFAOYSA-N sabinene Chemical compound C=C1CCC2(C(C)C)C1C2 NDVASEGYNIMXJL-UHFFFAOYSA-N 0.000 claims 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 claims 2
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 claims 1
- NDVASEGYNIMXJL-NXEZZACHSA-N (+)-sabinene Natural products C=C1CC[C@@]2(C(C)C)[C@@H]1C2 NDVASEGYNIMXJL-NXEZZACHSA-N 0.000 claims 1
- NFLGAXVYCFJBMK-IUCAKERBSA-N (-)-isomenthone Chemical compound CC(C)[C@@H]1CC[C@H](C)CC1=O NFLGAXVYCFJBMK-IUCAKERBSA-N 0.000 claims 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims 1
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 claims 1
- WRFXXJKURVTLSY-UHFFFAOYSA-N 2,6-dimethyloctan-2-ol Chemical compound CCC(C)CCCC(C)(C)O WRFXXJKURVTLSY-UHFFFAOYSA-N 0.000 claims 1
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 claims 1
- YTAQZPGBTPDBPW-UHFFFAOYSA-N 2-phenylchromene-3,4-dione Chemical compound O1C2=CC=CC=C2C(=O)C(=O)C1C1=CC=CC=C1 YTAQZPGBTPDBPW-UHFFFAOYSA-N 0.000 claims 1
- DLHQZZUEERVIGQ-UHFFFAOYSA-N 3,7-dimethyl-3-octanol Chemical compound CCC(C)(O)CCCC(C)C DLHQZZUEERVIGQ-UHFFFAOYSA-N 0.000 claims 1
- MGYMHQJELJYRQS-UHFFFAOYSA-N Ascaridole Chemical compound C1CC2(C)OOC1(C(C)C)C=C2 MGYMHQJELJYRQS-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- 241000134874 Geraniales Species 0.000 claims 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 claims 1
- 239000005792 Geraniol Substances 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 claims 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N Methyl butyrate Chemical class CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 claims 1
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 claims 1
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims 1
- 150000001242 acetic acid derivatives Chemical class 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims 1
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims 1
- KQAZVFVOEIRWHN-UHFFFAOYSA-N alpha-thujene Natural products CC1=CCC2(C(C)C)C1C2 KQAZVFVOEIRWHN-UHFFFAOYSA-N 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- MGYMHQJELJYRQS-ZJUUUORDSA-N ascaridole Natural products C1C[C@]2(C)OO[C@@]1(C(C)C)C=C2 MGYMHQJELJYRQS-ZJUUUORDSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 229930006739 camphene Natural products 0.000 claims 1
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 claims 1
- 229930003633 citronellal Natural products 0.000 claims 1
- 235000000983 citronellal Nutrition 0.000 claims 1
- 235000000484 citronellol Nutrition 0.000 claims 1
- 229930008394 dihydromyrcenol Natural products 0.000 claims 1
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 claims 1
- 239000000686 essence Substances 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 229940113087 geraniol Drugs 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- MNWFXJYAOYHMED-UHFFFAOYSA-N heptanoic acid Chemical class CCCCCCC(O)=O MNWFXJYAOYHMED-UHFFFAOYSA-N 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical class CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 229930002839 ionone Natural products 0.000 claims 1
- 150000002499 ionone derivatives Chemical class 0.000 claims 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 235000001510 limonene Nutrition 0.000 claims 1
- 229940087305 limonene Drugs 0.000 claims 1
- 229930007744 linalool Natural products 0.000 claims 1
- 229940041616 menthol Drugs 0.000 claims 1
- 229930007503 menthone Natural products 0.000 claims 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 claims 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims 1
- 229940067107 phenylethyl alcohol Drugs 0.000 claims 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000003254 radicals Chemical group 0.000 claims 1
- 229930006696 sabinene Natural products 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229930006978 terpinene Natural products 0.000 claims 1
- 150000003507 terpinene derivatives Chemical class 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical class CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
- C07C315/06—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/14—Preparation of carboxylic acid amides by formation of carboxamide groups together with reactions not involving the carboxamide groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
- C07C317/04—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/26—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Paper (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Claims (24)
1. Pripravak otapala koji sadrži:
a) barem 50% i poželjno barem 70%, i najpoželjnije barem 80% težine barem jednog oksida organskog sulfida opće formule (1):
[image]
gdje
- X i Y, koji mogu biti jednaki ili različiti, se odabiru, nezavisno jedan od drugoga, između kisika, sumpora, -SO-, -SO2-, -NH- i -NR"-;
- a i b, koji mogu biti jednaki ili različiti, predstavljaju, nezavisno jedan od drugoga, 0 ili 1; n je jednak 1 ili 2;
- R, R’ i R", koji mogu biti jednaki ili različiti, se odabiru, nezavisno jedan od drugoga, između linearnog ili razgranatog alkil radikala s 1 do 12 atoma ugljika, linearnog ili razgranatog alkenil radikala s 2 do 12 atoma ugljika, i aril radikala sa 6 to 10 atoma ugljika; R, R’ i R" mogu biti supstituirani radikalima odabranim između alkila, alkenila, arila i halogena, i mogu sadržavati jedan ili više heteroatoma odabrana između O, S, N, P i Si; R i R’ također mogu formirati, zajedno s atomima koji ih nose, cikličku strukturu ugljikovodične baze koja po izboru sadrži jedan ili više heteroatoma odabrana između O, S i N, ta ciklička struktura ukupno sadrži 5, 6, 7, 8 ili 9 člana u prstenu; i
b) od 10 ppm do 2%, poželjno od 10 ppm do 1%, težine u odnosu na ukupnu težinu pripravka, barem jednog sredstva za maskiranje mirisa koje obuhvaća barem jedan spoj odabran između monoestera, diestera i/ili triestera, alkohola, aldehida, ketona i terpena.
2. Pripravak prema zahtjevu 1, gdje je sadržaj sredstva(sredstava) za maskiranje mirisa b) između 0.001% i 0.2% težine u odnosu na ukupnu težinu pripravka i poželjno između 100 ppm i 1000 ppm, na primjer 500 ppm težine.
3. Pripravak prema zahtjevu 1 ili 2, gdje a predstavlja 0, -(Y)b- predstavlja -(S)x-, gdje x predstavlja 0 ili 1, poželjno 0, i R i R’ su jednaki i odabrani između linearnog ili razgranatog alkil radikala s 1 do 12 atoma ugljika, poželjno 1 do 6 atoma ugljika i još poželjnije 1 do 4 atoma ugljika, linearnog ili razgranatog alkenil radikala s 2 do 12 atoma ugljika, poželjno 2 do 6 atoma ugljika i još poželjnije 2 do 4 atoma ugljika, i aril radikala, poželjno fenila.
4. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje komponenta a) pripravka prema predstavljenom izumu odgovara formuli (1’) :
[image]
gdje se R odabire između između linearnog ili razgranatog alkil radikala s 1 do 4 atoma ugljika, linearnog ili razgranatog alkenil radikala s 2 do 4 atoma ugljika, i aril radikala, poželjno fenila, n je jednak 1 ili 2; x predstavlja 0 ili 1; R’ se odabire između između linearnog ili razgranatog alkil radikala s 1 do 4 atoma ugljika, linearnog ili razgranatog alkenilen radikala s 2 do 4 atoma ugljika, i aril radikala, poželjno fenila.
5. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje komponenta a) pripravka prema predstavljenom izumu odgovara formuli (1a)
[image]
gdje se R i R’, koji mogu biti jednaki ili različiti, odabiru između između linearnog ili razgranatog alkil radikala s 1 do 4 atoma ugljika, linearnog ili razgranatog alkenil radikala s 2 do 4 atoma ugljika, i fenil radikala; n je jednak 1 ili 2; i x je jednak 0.
6. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje komponenta a) jest DMSO.
7. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa b) obuhvaća jedan ili više spojeva odabranih između:
b1) monoestera;
b2) diestera i/ili triestera;
b3) alkohola, po mogućnosti monoalkohola, s 1 do 30 atoma ugljika, poželjno 6 do 20 atoma ugljika i još poželjnije 8 do 11 atoma ugljika, ti atomi ugljika formiraju linearni ili razgranati lanac koji po izboru sadrži jedno ili više nezasićenja u obliku dvostrukih veza, i po izboru sadrži 5- ili 6-eročlanu cikličku strukturu koja je zasićena ili djelomično ili potpuno nezasićena;
b4) aldehida i ketona formule Ra-CO-Rb, gdje Ra predstavlja linearni ili razgranati lanac ugljikovodične baze s 1 do 6 atoma ugljika, po izboru sadrži jedno ili više nezasićenja u obliku dvostrukih veza, i Rb predstavlja atom vodika, ciklički lanac na bazi ugljikovodika ili linearni ili razgranati lanac ugljikovodične baze koji je po izboru, ali poželjno, supstituiran cikličkom strukturom, Rb obuhvaća 6 do 12 atoma ugljika, po izboru obuhvaća jedno ili više nezasićenja u obliku dvostrukih veza i po izboru je supstituiran jednom ili više hidroksilnih skupina; i
b5) terpena.
8. Pripravak prema zahtjevu 7, gdje se b1) odabire između estera zasićenih ili nezasićenih C2-C20 kiselina, kao što su acetati, propionati, butirati, metilbutirati, pentanoati, heksanoati, heptanoati, kaproati, oleati, linoleati ili linolenati etila, propila, butila, pentila, 2-metilbutila, izoamila, heksila, benzila, feniletila, mentila, karvila, i slično, i također njihove smjese.
9. Pripravak prema zahtjevu 7, gdje se b2) odabire između orto-ftalata (poželjno dietil orto-ftalata), citrata (poželjno trietil citrat) i malonata (poželjno dietil malonata).
10. Pripravak prema zahtjevu 7, gdje se b3) odabire između mentola, neomentola, feniletil alkohola, benzil alkohola, citronelola, dihidromircenola, dihidroterpineola, dimetola, ethilinalola, geraniola, linalola, tetrahidrolinalola, tetrahidromircenola, nerola, i također smjesa dvaju ili više njih.
11. Pripravak prema zahtjevu 7, gdje se b4) odabire između propionaldehida, butiraldehida, valeraldehida, kapraldehida, benzaldehida, geraniala, nerala, citronelala i, općenito, aldehida koji sadrže skupine na bazi ugljikovodika koje obuhvaćaju jedno ili više nezasićenja olefinske vrste, menton, izomenton, 1,8-cineol, askaridol, flavonon, damaskone, damaskenone, ionone, irizone, metil-ionone dvaju ili više njih u svim omjerima.
12. Pripravak prema zahtjevu 7, gdje se b5) odabire između terpinena, mircena, limonena, terpinolena, pinena, sabinena, kamfena, smjesa dvaju ili više njih, i također esencija na bazi terpena, posebno onih koje sadrže te sastojke.
13. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje se sredstvo za maskiranje mirisa odabire između sredstava za maskiranje mirisa koja obuhvaćaju:
- barem jednu komponentu b1);
- barem jednu komponentu b1) i barem jednu komponentu b2);
- barem jednu komponentu b1) i barem jednu komponentu b3) ;
- barem jednu komponentu b1) i barem jednu komponentu b4);
- barem jednu komponentu b1) i barem jednu komponentu b5) ;
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b3);
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b4);
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b5);
- barem jednu komponentu b1), barem jednu komponentu b3) i barem jednu komponentu b4);
- barem jednu komponentu b1), barem jednu komponentu b3) i barem jednu komponentu b5);
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b4);
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b5);
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3), barem jednu komponentu b4) i barem jednu komponentu b5);
- barem jednu komponentu b2);
- barem jednu komponentu b2) i barem jednu komponentu b3) ;
- barem jednu komponentu b2) i barem jednu komponentu b4) ;
- barem jednu komponentu b2) i barem jednu komponentu b5) ;
- barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b4);
- barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b5);
- barem jednu komponentu b2), barem jednu komponentu b4) i barem jednu komponentu b5);
- barem jednu komponentu b2), barem jednu komponentu b3), barem jednu komponentu b4) i barem jednu komponentu b5);
- barem jednu komponentu b3);
- barem jednu komponentu b3) i barem jednu komponentu b4);
- barem jednu komponentu b3) i barem jednu komponentu b5) ;
- barem jednu komponentu b3), barem jednu komponentu b4) i barem jednu komponentu b5);
- barem jednu komponentu b4);
- barem jednu komponentu b4) i barem jednu komponentu b5); i
- barem jednu komponentu b5).
14. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje se sredstvo za maskiranje mirisa odabire između sredstava za maskiranje mirisa koja obuhvaćaju:
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b3);
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b4);
- barem jednu komponentu b1), barem jednu komponentu b2) i barem jednu komponentu b5);
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b4);
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3) i barem jednu komponentu b5); i
- barem jednu komponentu b1), barem jednu komponentu b2), barem jednu komponentu b3), barem jednu komponentu b4) i barem jednu komponentu b5).
15. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži od 1% do 40%, poželjno od 2% do 35% i još poželjnije od 5% do 30% težine barem jednog monoestera b1) u odnosu na ukupnu težinu pripravka b).
16. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži od 10% do 70%, poželjno od 15% do 65% i još poželjnije od 20% do 60% težine barem jednog diestera i/ili triestera b2) u odnosu na ukupnu težinu pripravka b).
17. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži od 1% do 30% i poželjno od 5% do 25% težine barem jednog alkohola b3) u odnosu na ukupnu težinu pripravka b).
18. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži od 0.5% do 20% i poželjno od 1% do 10% težine barem jednog aldehida i/ili ketona b4) u odnosu na ukupnu težinu pripravka b).
19. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži do 20% i poželjno od 1% do 10% težine barem jednog terpena naznačenog u b5) u odnosu na ukupnu težinu pripravka b).
20. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži:
b1) od 1% do 40% težine barem jednog monoestera;
b2) od 10% do 70% težine barem jednog diestera i/ili triestera;
b3) od 1% do 30% težine barem jednog alkohola;
b4) od 0.5% do 20% težine barem jednog aldehida i/ili ketona formule Ra-CO-Rb, gdje Ra predstavlja linearni ili razgranati lanac ugljikovodične baze s 1 do 6 atoma ugljika, po izboru obuhvaća jedno ili više nezasićenja u obliku dvostrukih veza, i Rb predstavlja ciklički lanac ugljikovodične baze ili linearni ili razgranati lanac ugljikovodične baze koji je po izboru, ali poželjno, supstituiran cikličkom strukturom, Rb ima od 6 do 12 atoma ugljika, po izboru obuhvaća jedno ili više nezasićenja u obliku dvostrukih veza i po izboru je supstituiran jednom ili više hidroksilnih skupina; i
b5) po izboru do 20% težine barem jednog terpena.
21. Pripravak prema bilo kojem od prethodnih zahtjeva, gdje sredstvo za maskiranje mirisa sadrži:
- od 5% do 30% težine barem jednog monoestera b1), odabranog između izoamil acetata, etil 2-metilbutirata, izoamil butirata, feniletil acetata, etil kaproata, benzil acetata i heksil acetata, i njihovih smjesa;
- od 20% do 60% težine barem jednog diestera i/ili triestera b2) odabranog između orto-ftalata, kao što je dietil orto-ftalat; citrata, kao što je trietil citrat; malonata, kao što je dietil malonat, i njihovih smjesa;
- od 5% do 25% težine barem jednog alkohola, poželjno barem dva alkohola, i još poželjnije barem tri alkohola, kako je prethodno opisano u b3);
- od 1% do 10% težine barem jednog ketona, poželjno barem dva ketona, još poželjnije barem tri ketona, kako je prethodno opisano u b4); i
- od 1% do 10% težine barem jednog, poželjno barem dva, i poželjno smjese terpena referenciranih gore u b5).
22. Pripravak prema bilo kojem od prethodnih zahtjeva, koji sadrži:
a) od 50% do 95%, poželjno od 70% do 90% i najpoželjnije 80% težine barem jednog oksida organskog sulfida opće formule (1);
b) od 10 ppm do 2%, poželjno od 10 ppm do 1% težine, u odnosu na ukupnu težinu pripravka, barem jednog sredstva za maskiranje mirisa b); i
c) od 5% do 50%, poželjno od 10% do 30% i najpoželjnije 20% težine barem jednog ko-otapala.
23. Pripravak prema zahtjevu 22, gdje se ko-otapalo odabire između spojeva koji su barem djelomično ili potpuno topljivi u oksidima organskih sulfida a), poželjno se odabire između karbonata, estera, ketona, amina, amida i alkohola, još poželjnije između alkohola, koji su poželjno zasićeni, poželjno s 1 do 10 atoma ugljika, i još poželjnije između metanola, etanola, propanola, butanola, pentanola, etilen glikola, propilen glikola i glicerola (1,2,3-propantriol).
24. Pripravak prema zahtjevu 22, koji sadrži:
a) 80% težine DMSO;
b) od 10 ppm do 2%, poželjno od 10 ppm do 1% težine, u odnosu na ukupnu težinu pripravka, sredstva za maskiranje mirisa koje obuhvaća:
- od 5% do 30% težine barem jednog monoestera b1), odabranog između izoamil acetata, etil 2-metilbutirata, izoamil butirata, feniletil acetata, etil kaproata, benzil acetata i heksil acetata, i njihovih smjesa;
- od 20% do 60% težine barem jednog diestera i/ili triestera b2) odabranog između orto-ftalata, kao što je dietil orto-ftalat; citrata, kao što je trietil citrat; malonata, kao što je dietil malonat, i njihovih smjesa;
- od 5% do 25% težine barem jednog alkohola, poželjno barem dva alkohola, i još poželjnije barem tri alkohola, kako je prethodno opisano u b3);
- od 1% do 10% težine barem jednog ketona, poželjno barem dva ketona, još poželjnije barem tri ketona, kako je prethodno opisano u b4); i
- od 1% do 10% težine barem jednog, poželjno barem dva, i poželjno smjese terpena referenciranih gore u b5); i
c) 20% težine glicerola.
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| FR0955398A FR2948661B1 (fr) | 2009-07-31 | 2009-07-31 | Composition a base de sulfure organique a odeur masquee |
| US23468009P | 2009-08-18 | 2009-08-18 | |
| FR1050157A FR2948662B1 (fr) | 2009-07-31 | 2010-01-12 | Composition de solvant a base d'oxyde de sulfure organique a odeur masquee |
| PCT/FR2010/051615 WO2011012820A1 (fr) | 2009-07-31 | 2010-07-29 | Composition de solvant à base d'oxyde de sulfure organique à odeur masquée |
| EP10763202.8A EP2459527B1 (fr) | 2009-07-31 | 2010-07-29 | Composition de solvant à base d'oxyde de sulfure organique à odeur masquée |
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| FR2948661B1 (fr) * | 2009-07-31 | 2011-07-29 | Arkema France | Composition a base de sulfure organique a odeur masquee |
| FR2975995B1 (fr) | 2011-06-06 | 2015-03-20 | Arkema France | Solvants de polymeres fluores |
| US9114180B2 (en) | 2012-03-30 | 2015-08-25 | Robertet, Inc. | Malodor neutralizing compositions containing acids and alicyclic ketones |
| JP6122333B2 (ja) * | 2013-04-12 | 2017-04-26 | コーデックケミカル株式会社 | 洗浄剤組成物及び該組成物を含有する洗浄剤並びにそれらを用いた洗浄方法 |
| FR3007766B1 (fr) * | 2013-07-01 | 2017-11-03 | Arkema France | Polysulfures phenoliques a odeur amelioree |
| WO2016204212A1 (ja) * | 2015-06-17 | 2016-12-22 | 花王株式会社 | ポリスルフィド化合物の臭いの抑制剤 |
| JP6371336B2 (ja) * | 2015-06-17 | 2018-08-08 | 花王株式会社 | ポリスルフィド化合物の臭いの抑制剤 |
| FR3041357B1 (fr) | 2015-09-17 | 2017-09-01 | Rhodia Operations | Solvants de decapage des resines photosensibles |
| FR3048964B1 (fr) | 2016-03-17 | 2023-06-09 | Arkema France | Procede de production de gaz de synthese enrichi en hydrogene |
| FR3048965B1 (fr) | 2016-03-17 | 2023-06-09 | Arkema France | Procede de production de gaz de synthese enrichi en hydrogene |
| WO2019225754A1 (ja) * | 2018-05-25 | 2019-11-28 | 株式会社 資生堂 | 防臭剤及び不活性化剤 |
| FR3100105B1 (fr) | 2019-08-30 | 2023-12-08 | Arkema France | Formulation fumigante pour application en goutte a goutte |
| FR3135458A1 (fr) | 2022-05-10 | 2023-11-17 | Arkema France | Procede ameliore de deshydrogenation d’hydrocarbures |
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| FR2372251A1 (fr) * | 1976-11-26 | 1978-06-23 | Rhone Poulenc Textile | Nouveau procede de filage ou mise en forme de solutions de cellulose et articles ainsi obtenus |
| FR2659079A1 (fr) | 1990-03-05 | 1991-09-06 | Elf Aquitaine | Procede pour la fabrication de disulfures organiques. |
| US5218147A (en) * | 1992-02-10 | 1993-06-08 | Phillips Petroleum Company | Stable polysulfides and process therefor |
| US5559271A (en) * | 1995-07-26 | 1996-09-24 | Phillips Petroleum Company | Organic polysulfide compositions having reduced odor |
| FR2774376B1 (fr) * | 1998-02-03 | 2000-03-17 | Elf Aquitaine Exploration Prod | Production de polysulfures organiques stabilises et desodorises |
| US6042640A (en) * | 1998-06-29 | 2000-03-28 | Xerox Corporation | Deodorization of sulfur-containing solvents by oxidation |
| FR2781795B1 (fr) * | 1998-07-31 | 2000-09-08 | Atochem Elf Sa | Compositions a base de dimethyldisulfure a odeur masquee |
| DE10058459A1 (de) * | 2000-11-24 | 2002-06-06 | Haarmann & Reimer Gmbh | Rhinologica |
| US8007771B2 (en) * | 2006-07-07 | 2011-08-30 | The Procter & Gamble Company | Flavors for oral compositions |
| US20090005601A1 (en) * | 2007-06-29 | 2009-01-01 | Gaylord Chemical Company Llc | Process for preparing low malodor dimethyl sulfoxide |
| FR2948661B1 (fr) * | 2009-07-31 | 2011-07-29 | Arkema France | Composition a base de sulfure organique a odeur masquee |
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