HRP20160848T1 - Površinski modificirani kalcijev karbonat koji sadrži minerale i njegova uporaba - Google Patents

Površinski modificirani kalcijev karbonat koji sadrži minerale i njegova uporaba Download PDF

Info

Publication number
HRP20160848T1
HRP20160848T1 HRP20160848TT HRP20160848T HRP20160848T1 HR P20160848 T1 HRP20160848 T1 HR P20160848T1 HR P20160848T T HRP20160848T T HR P20160848TT HR P20160848 T HRP20160848 T HR P20160848T HR P20160848 T1 HRP20160848 T1 HR P20160848T1
Authority
HR
Croatia
Prior art keywords
calcium carbonate
mineral
carbonate containing
modified calcium
aqueous suspension
Prior art date
Application number
HRP20160848TT
Other languages
English (en)
Inventor
Daniel Edward Gerard
Joachim Schölkopf
Patrick Arthur Charles Gane
Fritz Lehner
Dennis Werner
Original Assignee
Omya International Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omya International Ag filed Critical Omya International Ag
Publication of HRP20160848T1 publication Critical patent/HRP20160848T1/hr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F11/00—Compounds of calcium, strontium, or barium
    • C01F11/18—Carbonates
    • C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/02—Compounds of alkaline earth metals or magnesium
    • C09C1/021—Calcium carbonates
    • C09C1/022—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C09C3/063—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D21H17/15—Polycarboxylic acids, e.g. maleic acid
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/385—Oxides, hydroxides or carbonates
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Claims (29)

1. Postupak za proizvodnju kugličastog sferičnog površinski modificiranog kalcijevog karbonata koji sadrži čestice koji obuhvaća korake: a) osiguravanja barem jedne vodene suspenzije koja sadrži kalcijev karbonat koji sadrži mineral; b) osiguravanja barem jedne kiseline koja se otapa u vodi; c) proizvoljno osiguravanje dodatnog plinovitog CO2 iz vanjskog izvora; d) dovođenje u kontakt uz miješanje navedene vodene suspenzije koja sadrži kalcijev karbonat koji sadrži mineral iz koraka a) s navedenom kiselinom iz koraka b) i s navedenim CO2 nastalim na licu mjesta i/ili koji se dobavlja iz vanjskog izvora iz koraka c), e) proizvoljno uklanjanje vode iz vodene suspenzije; naznačen time da se barem jedno sredstvo za obradu dodaje prije, tijekom ili poslije dovođenja u kontakt navedene vodene suspenzije koja sadrži kalcijev karbonat koji sadrži mineral iz koraka a) s navedenom kiselinom iz koraka b) i s navedenim CO2 nastalim na licu mjesta i/ili koji se dobavlja iz vanjskog izvora iz koraka c), te pri čemu se barem jedno sredstvo za obradu bira iz skupine koju čine željezni sulfat, željezov sulfat, željezni klorid, željezov klorid, aluminijev sulfat, i/ili njihovi hidratni oblici, te pri čemu se sredstvo za obradu dodaje u količinama sve do 8 tež.% na bazi suhe težine suspenzije.
2. Postupak prema zahtjevu 1, naznačen time da se navedeni kalcijev karbonat koji sadrži mineral bira iz skupine koju čine mramor, kreda, vapnenac, kalcit, dolomit, istaloženi kalcijev karbonat (PCC), te od njihovih smjesa.
3. Postupak prema zahtjevu 1 ili 2, naznačen time da navedeni kalcijev karbonat koji sadrži mineral u suspenziji ima weight median particle diameter od 0.01 µm do 10 µm, poželjno od 0.2 µm do 2 µm, poželjnije od 0.5 µm do 1 µm.
4. Postupak prema jednom od zahtjeva 1 do 3, naznačen time da navedena suspenzija iz koraka a) ima sadržaj čvrstih tvari od više od 4 tež.-%, poželjno od 5 tež.-% do oko 20 tež.-%, bazirano na težini suspenzije.
5. Postupak prema jednom od zahtjeva 1 do 4, naznačen time da se navedena suspenzija iz koraka a) stabilizira dodavanjem jednog ili više disperzijskih sredstava.
6. Postupak prema jednom od zahtjeva 1 do 5, naznačen time da barem jedna kiselina koja se otapa u vodi iz koraka b) ima pKa od 0 do 6, poželjno ima pKa od 0 do 2.5.
7. Postupak prema jednom od zahtjeva 1 do 6, naznačen time da se barem jedna kiselina koja se otapa u vodi iz koraka b) bira od fosforne kiseline, limunske kiseline, borne kiseline, ili njihovih smjesa.
8. Postupak prema jednom od zahtjeva 1 do 7, naznačen time da se barem jedna kiselina koja se otapa u vodi dozira u molarnoj količini u odnosu na broj molova kalcijevog karbonata koji sadrži mineral u rasponu od 0.01 mol/mol do oko 1 mol/mol, poželjno od 0.1 do 0.6 mol/mol.
9. Postupak prema jednom od zahtjeva 1 do 8, naznačen time da se barem one kiselina koja se otapa u vodi osigurana u koraku b) dodaje u jednom ili više koraka, poželjno u jednom koraku u navedenu vodenu suspenziju koja sadrži kalcijev karbonat.
10. Postupak prema jednom od zahtjeva 1 do 9, naznačen time da se dodavanje barem jedne kiseline koja se otapa u vodi iz koraka b) i dovođenje u kontakt navedene vodene suspenzije koja sadrži kalcijev karbonat koji sadrži mineral iz koraka a) s navedenom kiselinom iz koraka b) i s navedenim CO2 nastalim na licu mjesta i/ili koji se dobavlja iz vanjskog izvora iz koraka c) odvija u miješanom reaktoru uz miješanje tako da nastaje u biti laminarno strujanje.
11. Postupak prema jednom od zahtjeva 1 do 10, naznačen time da se postupak odvija u vodenom okruženju u temperaturnom rasponu iznad i uključujući 20°C, kao što je od oko 25°C do oko 95°C, poželjno u rasponu od oko 30°C do oko 80°C, poželjnije od oko 50°C do oko 75°C.
12. Postupak prema jednom od zahtjeva 1 do 11, naznačen time da se sredstvo za obradu dodaje u količinama od 0.01 tež.% do oko 5 tež.%, poželjnije od oko 0.05 tež.% do oko 4 tež.%, još poželjnije od oko 0.4 tež.% do oko 3 tež.%, bazirano na suhoj težini suspenzije.
13. Postupak prema zahtjevima 1 do 12, naznačen time da se sredstvo za obradu, poželjno aluminijev sulfat ili njegov hidrat, poželjnije aluminijev sulfat heksadekahidrat, dozira u jednom ili više koraka, poželjno u jednom koraku u navedenu suspenziju koja sadrži kalcijev karbonat koji sadrži mineral.
14. Postupak prema zahtjevu 13, naznačen time da sadržaj aluminijevog sulfata je sve do 5 tež.% bazirano na težini suhe suspenzije.
15. Postupak prema jednom od zahtjeva 1 do 14, naznačen time da se sredstvo za obradu dodaje prije, za vrijeme ili nakon koraka b).
16. Vodena suspenzija kugličastog površinski modificiranog kalcijevog karbonata koji sadrži mineral koja je dobivena prema bilo kojem postupku iz zahtjeva 1 do 15, naznačena time da navedeni površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu veću od 15 m2/g.
17. Vodena suspenzija prema zahtjevu 16, naznačena time da navedeni površinski modificirani kalcijev karbonat koji sadrži mineral ima medijan promjera zrna od 4 µm do oko 100 µm, poželjno od oko 5 µm do oko 75 µm, poželjnije od oko 10 µm do oko 50 µm, još poželjnije od oko 15 µm do oko 30 µm, određen uređajem Malvern Mastersizer.
18. Vodena suspenzija prema jednom od zahtjeva 16 ili 17, naznačena time da navedeni površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu od oko 20 m2/g do oko 200 m2/g, poželjno od oko 30 m2/g do oko 150 m2/g, poželjnije od oko 40 m2/g do oko 100 m2/g.
19. Vodena suspenzija prema zahtjevu 18, naznačena time da navedeni površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu od 30 m2/g do oko 90 m2/g i medijan promjera zrna od 10 µm do 50 µm, određenu uređajem Malvern Mastersizer.
20. Vodena suspenzija prema jednom od zahtjeva 16 do 19, naznačena time da kugličasti površinski modificirani kalcijev karbonat koji sadrži mineral ima usku distribuciju veličine čestica d98/d50 poželjno manju od 3, poželjnije manju od 2.5, poželjno u rasponu od 1.4 do 2.9.
21. Površinski modificirani kalcijev karbonat koji sadrži mineral koji je dobiven sušenjem vodene suspenzije prema bilo kojem od zahtjeva 16 do 20, naznačen time da navedeni površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu veću od 15 m2/g.
22. Površinski modificirani kalcijev karbonat koji sadrži mineral prema zahtjevu 21, naznačen time da površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu od oko 20 m2/g do oko 200 m2/g, poželjno od oko 30 m2/g do oko 150 m2/g, poželjnije od oko 40 m2/g do oko 100 m2/g.
23. Površinski modificirani kalcijev karbonat koji sadrži mineral prema zahtjevu 21, naznačen time da površinski modificirani kalcijev karbonat koji sadrži mineral ima medijan promjera zrna od 4 µm do oko 100 µm, poželjno od oko 5 µm do oko 75 µm, poželjnije od oko 10 µm do oko 50 µm, još poželjnije od oko 15 µm do oko 30 µm, određeno s uređajem Malvern Mastersizer.
24. Površinski modificirani kalcijev karbonat koji sadrži mineral prema zahtjevu 21, naznačen time da površinski modificirani kalcijev karbonat koji sadrži mineral ima BET specifičnu dodirnu površinu od 30 m2/g do oko 90 m2/g i medijan promjera zrna od 10 µm do 50 µm, određeno s uređajem Malvern Mastersizer.
25. Uporaba površinski modificiranog kalcijevog karbonata koji sadrži mineral iz vodene suspenzije prema bilo kojem od zahtjeva 16 do 20, ili suhog kugličastog površinski modificiranog kalcijevog karbonata koji sadrži mineral prema zahtjevu 21 do 24, naznačena time da je za sredstva za obradu papira, za premaze za papir, sredstva za obradu toaletnog papira, sredstva za obradu digitalnog foto papira, sredstva za obradu boja, sredstva za obradu premaza, sredstva za obradu ljepila, sredstva za obradu plastike, ili za obradu otpadnih voda.
26. Uporaba prema zahtjevu 25 naznačena time da se koristi kao matirajuće sredstvo za boje i prevlake.
27. Uporaba prema zahtjevu 26, naznačena time da je matirajuće sredstvo prisutno u količinama od 1 do 10 tež.%, poželjno od 2 do 7 tež.%, poželjnije od 3 do 5 tež.% bazirano na mokroj boji.
28. Uporaba prema zahtjevu 27, naznačena time da površina osušene boje ili premaza ima sjajnost od 85° u rasponu od ispod 10, poželjno od 0.5- 9.5, poželjnije od 1 do 8, još poželjnije od 2-6.5, mjereno prema DIN 67 530.
29. Sredstvo za obradu papira, toaletnog papira, digitalnog foto papira, boja, premaza, ljepila, plastike, ili otpadnih voda naznačeno time da sadrži kugličasti površinski modificirani kalcijev karbonat koji sadrži mineral iz vodene suspenzije prema bilo kojem od zahtjeva 16 do 20, ili suhi kugličasti površinski modificirani kalcijev karbonat koji sadrži mineral prema zahtjevu 21 do 24.
HRP20160848TT 2012-07-13 2016-07-12 Površinski modificirani kalcijev karbonat koji sadrži minerale i njegova uporaba HRP20160848T1 (hr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP12176320.5A EP2684916B1 (en) 2012-07-13 2012-07-13 Surface modified calcium carbonate containing minerals and its use

Publications (1)

Publication Number Publication Date
HRP20160848T1 true HRP20160848T1 (hr) 2016-09-23

Family

ID=46545652

Family Applications (1)

Application Number Title Priority Date Filing Date
HRP20160848TT HRP20160848T1 (hr) 2012-07-13 2016-07-12 Površinski modificirani kalcijev karbonat koji sadrži minerale i njegova uporaba

Country Status (24)

Country Link
US (2) US9650517B2 (hr)
EP (2) EP2684916B1 (hr)
JP (1) JP6196670B2 (hr)
KR (1) KR101740832B1 (hr)
CN (1) CN104520385B (hr)
AR (1) AR091733A1 (hr)
AU (1) AU2013288800B2 (hr)
BR (1) BR112015000335B1 (hr)
CA (1) CA2877047C (hr)
CL (1) CL2015000036A1 (hr)
ES (2) ES2584628T3 (hr)
HR (1) HRP20160848T1 (hr)
HU (1) HUE029716T2 (hr)
MX (2) MX2015000380A (hr)
MY (1) MY172814A (hr)
PH (1) PH12014502838A1 (hr)
PL (2) PL2684916T3 (hr)
PT (2) PT2684916T (hr)
RU (1) RU2616054C2 (hr)
SI (2) SI2684916T1 (hr)
TR (1) TR201901038T4 (hr)
TW (1) TWI494381B (hr)
UY (1) UY34903A (hr)
WO (1) WO2014009403A1 (hr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2883573T5 (pl) * 2013-12-13 2021-04-19 Omya International Ag Ścierna kompozycja czyszcząca
DK2957301T3 (en) * 2014-06-20 2017-07-03 Omya Int Ag Procedure for odor control
EP3045042A1 (en) * 2015-01-15 2016-07-20 Omya International AG Use of surface-reacted calcium carbonate as carrier for agrochemical compounds
EP3085742B1 (en) 2015-04-20 2018-02-21 Omya International AG Blend of calcium carbonates comprising particles of surface modified calcium carbonate (mcc) and particles of precipitated calcium carbonate (pcc) and its uses
EP3103844B1 (en) 2015-06-10 2018-08-08 Omya International AG Use of surface-reacted calcium carbonate as anti-blocking agent
EP3153549A1 (de) * 2015-10-30 2017-04-12 Kronos International, Inc. Herstellung von matten lacken und druckfarben
EP3176222A1 (en) * 2015-12-01 2017-06-07 Omya International AG Method for the production of granules comprising surface-reacted calcium carbonate
EP3275946A1 (en) * 2016-07-25 2018-01-31 Omya International AG Post treatment of surface-reacted calcium carbonate with different functional cations
US11053640B2 (en) 2017-01-17 2021-07-06 Neenah, Inc. Texturized printable coating and methods of making and using the same
EP3385335A1 (en) 2017-04-03 2018-10-10 Omya International AG Pigment composition comprising surface modified calcium carbonate and ground natural calcium carbonate
EP3467050A1 (en) 2017-10-04 2019-04-10 Omya International AG Coating compositions comprising ground natural calcium carbonate (gcc)
CA3061510A1 (en) * 2018-11-09 2020-05-09 Spray-Net Canada Inc. Method for rejuvenating a roof and roof coating composition
CN109593386B (zh) * 2019-01-14 2020-12-11 上海第二工业大学 一种改性重质碳酸钙、制备方法及其应用
CN109867986B (zh) * 2019-03-29 2020-10-27 厦门大学 一种高分子改性的纳米碳酸钙产品系列
CN110075555A (zh) * 2019-04-19 2019-08-02 贺州学院 一种改性重质碳酸钙微波间歇干燥的方法
CN110349496A (zh) * 2019-07-13 2019-10-18 安徽星光标识系统有限公司 仿大理石标识标牌及其加工方法
CN110511597A (zh) * 2019-09-18 2019-11-29 上海第二工业大学 一种多孔碳酸钙塑料填充材料及其制备方法
CN114804178B (zh) * 2022-05-19 2023-12-01 广西民泰纳米科技有限公司 一种聚酯族降解塑料专用纳米碳酸钙的制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3304154A (en) * 1964-02-17 1967-02-14 Kiouzes-Pezas Dimitrios Process for producing spheroidal alkaline earth metal carbonates
US3848059A (en) * 1972-12-22 1974-11-12 Nl Industries Inc Inorganic microspheres by a double emulsion technique
JPS5595617A (en) * 1979-01-09 1980-07-21 Shiseido Co Ltd Production of spherical calcium carbonate
DE3587060T2 (de) 1984-10-18 1993-05-19 Pfizer Kugelfoermiges ausgefaelltes calciumcarbonat, seine herstellung und seine verwendung.
DE4416895C1 (de) 1994-05-13 1995-10-19 Pluss Stauffer Ag Carbonathaltige mineralische Füllstoffe und ihre Verwendung als Mattierungsmittel
US5531821A (en) 1995-08-24 1996-07-02 Ecc International Inc. Surface modified calcium carbonate composition and uses therefor
FR2787802B1 (fr) * 1998-12-24 2001-02-02 Pluss Stauffer Ag Nouvelle charge ou pigment ou mineral traite pour papier, notamment pigment contenant du caco3 naturel, son procede de fabrication, compositions les contenant, et leurs applications
JP2003147275A (ja) 2001-11-14 2003-05-21 Nippon Paint Co Ltd つや消し塗料組成物およびつや消し塗膜形成方法
FR2852600B1 (fr) * 2003-03-18 2005-06-10 Nouveau pigment mineral contenant du carbonate de calcium, suspension aqueuse le contenant et ses usages
US7303794B2 (en) 2004-03-31 2007-12-04 Specialty Minerals (Michigan) Inc. Ink jet recording paper
FR2871474B1 (fr) 2004-06-11 2006-09-15 Omya Development Ag Nouveau pigment mineral sec contenant du carbonate de calcium, suspension aqueuse le contenant et ses usages
US20080168925A1 (en) 2005-03-31 2008-07-17 Imerys Kaolin, Inc. Aggregated Particulate Minerals, Compositions Comprising Aggregated Calcium Carbonate, Methods of Making and Uses Thereof
EP1712523A1 (en) * 2005-04-11 2006-10-18 Omya Development AG Precipitated calcium carbonate pigment, especially for use in inkjet printing paper coatings
EP1712597A1 (en) * 2005-04-11 2006-10-18 Omya Development AG Process for preparing precipitated calcium carbonate pigment, especially for use in inkjet printing pater coatings and precipitated calcium carbonate
ES2342495T3 (es) * 2007-03-21 2010-07-07 Omya Development Ag Procedimiento de eliminacion de compuestos disruptores endocrinos.
DK2070991T3 (da) * 2007-12-12 2010-12-20 Omya Development Ag Fremgangsmåde til frembringelse af overflademodificeret, udfældet calciumcarbonat
EP2264109B1 (en) 2009-06-15 2012-01-25 Omya Development AG Process for preparing surface-reacted calcium carbonate and its use
ES2382628T3 (es) 2009-06-15 2012-06-12 Omya Development Ag Proceso para la preparación de un carbonato cálcico que reacciona con la superficie aplicando un ácido débil
TWI510432B (zh) * 2010-04-09 2015-12-01 Omya Int Ag 經表面改質碳酸鈣在黏著劑、密封劑及／或填隙劑中之用途

Also Published As

Publication number Publication date
TW201420689A (zh) 2014-06-01
CL2015000036A1 (es) 2015-08-07
BR112015000335B1 (pt) 2021-08-17
TWI494381B (zh) 2015-08-01
US20150175806A1 (en) 2015-06-25
WO2014009403A1 (en) 2014-01-16
KR20150034756A (ko) 2015-04-03
JP6196670B2 (ja) 2017-09-13
UY34903A (es) 2014-02-28
EP2684916A1 (en) 2014-01-15
CA2877047A1 (en) 2014-01-16
PH12014502838A1 (en) 2015-02-23
US9650517B2 (en) 2017-05-16
HUE029716T2 (en) 2017-03-28
RU2015104794A (ru) 2016-08-27
RU2616054C2 (ru) 2017-04-12
CN104520385B (zh) 2016-12-07
ES2584628T3 (es) 2016-09-28
PL2684916T3 (pl) 2017-03-31
EP2684916B1 (en) 2016-04-27
MY172814A (en) 2019-12-12
MX2020001155A (es) 2020-03-12
AR091733A1 (es) 2015-02-25
PL2872569T3 (pl) 2019-04-30
PT2872569T (pt) 2019-02-04
BR112015000335A2 (pt) 2017-06-27
SI2684916T1 (sl) 2016-08-31
TR201901038T4 (tr) 2019-02-21
EP2872569B1 (en) 2018-11-07
PT2684916T (pt) 2016-07-25
AU2013288800A1 (en) 2015-01-29
CA2877047C (en) 2018-01-02
JP2015529615A (ja) 2015-10-08
EP2872569A1 (en) 2015-05-20
SI2872569T1 (sl) 2019-04-30
ES2710366T3 (es) 2019-04-24
US20170009077A1 (en) 2017-01-12
AU2013288800B2 (en) 2015-10-01
US9637637B2 (en) 2017-05-02
CN104520385A (zh) 2015-04-15
MX2015000380A (es) 2015-04-10
KR101740832B1 (ko) 2017-05-26

Similar Documents

Publication Publication Date Title
HRP20160848T1 (hr) Površinski modificirani kalcijev karbonat koji sadrži minerale i njegova uporaba
HRP20190938T1 (hr) Istaloženi kalcijev karbonat iz otpada nakon mlina za pulpiranje s povećanom svjetlinom, postupak njegove proizvodnje i njegova upotreba
HRP20160139T1 (hr) Vodena suspenzija površinski reaktivnog kalcijevog karbonata, dobiveni proizvodi i njihova uporaba
HRP20160787T1 (hr) Hidrofobizirane čestice kalcijevog karbonata
HRP20151154T1 (hr) Postupak pripreme samoljepljivih pigmentnih äśestica
HRP20130014T1 (hr) Postupak za pripremanje materijala od površinski obrađenog kalcijevog karbonata i njegova uporaba za kontrolu organskog materijala u vodenom mediju
CN107532010B (zh) 含表面改性碳酸钙的粒子(mcc)与含沉淀碳酸钙的粒子(pcc)的共混物及其用途
JP2019529299A5 (hr)
SI20478B (sl) Sestavljene zmesi sostrukturiranih ali soadsorbiranih mineralnih ali organskih polnil ali pigmentov in njihove uporabe
HRP20140231T1 (hr) Hibrid samoljepljivog pigmenta
CN104105763A (zh) 用于控制表面润湿性的组合物和方法
WO2010022936A4 (de) Verfahren zur herstellung eines gemisches umfassend mindestens einen anorganischen feststoff und mindestens ein fettsäuresalz, entsprechend hergestellte gemische und deren verwendung
JP2013538773A5 (hr)
RU2015102581A (ru) ВОДНАЯ СУСПЕНЗИЯ С ВЫСОКИМ СОДЕРЖАНИЕМ ТВЕРДЫХ ЧАСТИЦ НЕОРГАНИЧЕСКОГО ВЕЩЕСТВА, И/ИЛИ НАПОЛНИТЕЛЯ, И/ИЛИ ПИГМЕНТА В СРЕДЕ С КИСЛЫМ ЗНАЧЕНИЕМ рН
RU2012147584A (ru) Применение поверхностно-модифицированного карбоната кальция в клейких материалах, уплотнителях и/или герметиках
HRP20170709T1 (hr) Postupak za dobivanje mrvica koje sadrže kalcijev karbonat
HRP20140651T1 (hr) Stabilizacija vodenih mineralnih pripravaka pomoä†u reuterina
HRP20211786T1 (hr) Modificirano punilo na bazi minerala koje sadrži bakrene soli
CN107406691B (zh) 用于voc去除的铝硅酸盐及由其制成的涂料
TW201418386A (zh) 用於減少污垢之添加物，彼之製造方法及彼於塗料中之用途
CN105038568B (zh) 重工业环境木质古建筑耐酸性涂料、制备方法及应用方法
CN104004428B (zh) 一种环保型纳米聚丙烯酸酯涂料的制备方法
CN106495624B (zh) 内墙用硅藻泥干粉乳胶漆及其制备方法
Nooririnah et al. Effect of CO2 flow rate on the synthesis nanosized precipitated calcium carbonate, PCC
CN110003731A (zh) 一种乳液组合物