GB957987A - Process for the production of trifluoromethylmercapto-phenols - Google Patents
Process for the production of trifluoromethylmercapto-phenolsInfo
- Publication number
- GB957987A GB957987A GB4117762A GB4117762A GB957987A GB 957987 A GB957987 A GB 957987A GB 4117762 A GB4117762 A GB 4117762A GB 4117762 A GB4117762 A GB 4117762A GB 957987 A GB957987 A GB 957987A
- Authority
- GB
- United Kingdom
- Prior art keywords
- trifluoromethylmercapto
- reacting
- prepared
- phenol
- phenols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Trifluoromethylmercapto-phenol of the general formula: <FORM:0957987/C2/1> wherein X stands for a hydrogen atom or a substituent such as a bromine or chlorine atom or a hydroxyl or C1-4 alkyl radical are prepared by reacting an appropriate phenol with trifluoromethylsulphenyl chloride at a temperature of 0-200 DEG C., preferably in the presence of an inert solvent and of a Friedel-Crafts' catalyst. Examples are given. The trifluoromethylsulphenyl chloride used as starting material may be prepared by reacting perchloromethyl mercaptan and sodium fluoride in tetramethylene sulphone, bis-trifluoromethyl disulphide being obtained as a by-product. Specification 479,774 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF35276A DE1210881B (en) | 1961-11-03 | 1961-11-03 | Process for the preparation of trifluoromethyl mercaptophenols |
Publications (1)
Publication Number | Publication Date |
---|---|
GB957987A true GB957987A (en) | 1964-05-13 |
Family
ID=7095937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4117762A Expired GB957987A (en) | 1961-11-03 | 1962-10-31 | Process for the production of trifluoromethylmercapto-phenols |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH421995A (en) |
DE (1) | DE1210881B (en) |
GB (1) | GB957987A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4700006A (en) * | 1984-09-11 | 1987-10-13 | Nihon Tokushu Noyaku Seizo K.K. | Carbamoylimidazole derivatives |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3836149A1 (en) * | 1988-10-24 | 1990-05-10 | Bayer Ag | NEW 4-TRIFLUORMETHYLMERCAPTO AND 4-TRIFLUORMETHYLSULFONYL PHENOLS AND THEIR PRODUCTION |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1063177B (en) * | 1957-04-13 | 1959-08-13 | Bayer Ag | Process for the preparation of hydroxyaryl-alkyl-thioethers |
-
1961
- 1961-11-03 DE DEF35276A patent/DE1210881B/en active Pending
-
1962
- 1962-10-18 CH CH1227362A patent/CH421995A/en unknown
- 1962-10-31 GB GB4117762A patent/GB957987A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4700006A (en) * | 1984-09-11 | 1987-10-13 | Nihon Tokushu Noyaku Seizo K.K. | Carbamoylimidazole derivatives |
Also Published As
Publication number | Publication date |
---|---|
DE1210881B (en) | 1966-02-17 |
CH421995A (en) | 1966-10-15 |
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