GB921432A - Improvements in or relating to organic halopyrosulphates and aromatic sulphones - Google Patents

Improvements in or relating to organic halopyrosulphates and aromatic sulphones

Info

Publication number
GB921432A
GB921432A GB40820/59A GB4082059A GB921432A GB 921432 A GB921432 A GB 921432A GB 40820/59 A GB40820/59 A GB 40820/59A GB 4082059 A GB4082059 A GB 4082059A GB 921432 A GB921432 A GB 921432A
Authority
GB
United Kingdom
Prior art keywords
lower alkyl
halopyrosulphates
sulphone
chloropyrosulphate
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40820/59A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of GB921432A publication Critical patent/GB921432A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C381/00Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00Esters of sulfuric acids
    • C07C305/02Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/02Sulfonic acids having sulfo groups bound to acyclic carbon atoms
    • C07C309/24Sulfonic acids having sulfo groups bound to acyclic carbon atoms of a carbon skeleton containing six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C315/00Preparation of sulfones; Preparation of sulfoxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00Sulfones; Sulfoxides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises lower alkyl halopyrosulphates of the general formula X-SO2-O-SO2-OR11 wherein R11 is a lower alkyl group containing 1-6 carbon atoms and X is a halogen atom e.g. chlorine or bromine and a process for the production of symmetrical aromatic sulphones of the general formula R-SO2-R where R is an aryl group which may be substituted, characterized in that a substituted or unsubstituted aromatic hydrocarbon is reacted with a lower alkyl halopyrosulphate as defined above and the resulting sulphone is isolated by precipitation with water. The lower alkyl halopyrosulphates are produced by the reaction of a lower alkyl halide with sulphur trioxide. Methyl chloropyrosulphate is obtained by reacting methyl chloride with sulphur trioxide and 4,41-dimethyl-diphenyl sulphone, p,p1-dichlorodiphenyl sulphone and p,p1-dimethoxy-diphenyl sulphone are obtained by reacting methyl chloropyrosulphate with toluene, chlorbenzene and anisole respectively.
GB40820/59A 1958-07-05 1959-12-01 Improvements in or relating to organic halopyrosulphates and aromatic sulphones Expired GB921432A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1211412T 1958-07-05
FR782278A FR75120E (en) 1958-07-05 1958-12-22 Process for preparing sulfones

Publications (1)

Publication Number Publication Date
GB921432A true GB921432A (en) 1963-03-20

Family

ID=61024220

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40820/59A Expired GB921432A (en) 1958-07-05 1959-12-01 Improvements in or relating to organic halopyrosulphates and aromatic sulphones

Country Status (3)

Country Link
CH (1) CH382142A (en)
FR (2) FR1211412A (en)
GB (1) GB921432A (en)

Also Published As

Publication number Publication date
FR75120E (en) 1961-04-21
CH382142A (en) 1964-09-30
FR1211412A (en) 1960-03-16

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