GB921432A - Improvements in or relating to organic halopyrosulphates and aromatic sulphones - Google Patents
Improvements in or relating to organic halopyrosulphates and aromatic sulphonesInfo
- Publication number
- GB921432A GB921432A GB40820/59A GB4082059A GB921432A GB 921432 A GB921432 A GB 921432A GB 40820/59 A GB40820/59 A GB 40820/59A GB 4082059 A GB4082059 A GB 4082059A GB 921432 A GB921432 A GB 921432A
- Authority
- GB
- United Kingdom
- Prior art keywords
- lower alkyl
- halopyrosulphates
- sulphone
- chloropyrosulphate
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C381/00—Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
- C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/24—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of a carbon skeleton containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C315/00—Preparation of sulfones; Preparation of sulfoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises lower alkyl halopyrosulphates of the general formula X-SO2-O-SO2-OR11 wherein R11 is a lower alkyl group containing 1-6 carbon atoms and X is a halogen atom e.g. chlorine or bromine and a process for the production of symmetrical aromatic sulphones of the general formula R-SO2-R where R is an aryl group which may be substituted, characterized in that a substituted or unsubstituted aromatic hydrocarbon is reacted with a lower alkyl halopyrosulphate as defined above and the resulting sulphone is isolated by precipitation with water. The lower alkyl halopyrosulphates are produced by the reaction of a lower alkyl halide with sulphur trioxide. Methyl chloropyrosulphate is obtained by reacting methyl chloride with sulphur trioxide and 4,41-dimethyl-diphenyl sulphone, p,p1-dichlorodiphenyl sulphone and p,p1-dimethoxy-diphenyl sulphone are obtained by reacting methyl chloropyrosulphate with toluene, chlorbenzene and anisole respectively.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1211412T | 1958-07-05 | ||
FR782278A FR75120E (en) | 1958-07-05 | 1958-12-22 | Process for preparing sulfones |
Publications (1)
Publication Number | Publication Date |
---|---|
GB921432A true GB921432A (en) | 1963-03-20 |
Family
ID=61024220
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB40820/59A Expired GB921432A (en) | 1958-07-05 | 1959-12-01 | Improvements in or relating to organic halopyrosulphates and aromatic sulphones |
Country Status (3)
Country | Link |
---|---|
CH (1) | CH382142A (en) |
FR (2) | FR1211412A (en) |
GB (1) | GB921432A (en) |
-
1958
- 1958-07-05 FR FR1211412D patent/FR1211412A/en not_active Expired
- 1958-12-22 FR FR782278A patent/FR75120E/en not_active Expired
-
1959
- 1959-06-30 CH CH7514359A patent/CH382142A/en unknown
- 1959-12-01 GB GB40820/59A patent/GB921432A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR75120E (en) | 1961-04-21 |
CH382142A (en) | 1964-09-30 |
FR1211412A (en) | 1960-03-16 |
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