GB1033773A - Process for the production of substituted 1,4-dichloro anthraquinones - Google Patents

Process for the production of substituted 1,4-dichloro anthraquinones

Info

Publication number
GB1033773A
GB1033773A GB11444/63A GB1144463A GB1033773A GB 1033773 A GB1033773 A GB 1033773A GB 11444/63 A GB11444/63 A GB 11444/63A GB 1144463 A GB1144463 A GB 1144463A GB 1033773 A GB1033773 A GB 1033773A
Authority
GB
United Kingdom
Prior art keywords
anthraquinones
nitro
chlorine
hydrogen
anthraquinone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11444/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEF36343A external-priority patent/DE1161252B/en
Priority claimed from DEF36380A external-priority patent/DE1151517B/en
Priority claimed from DEF37160A external-priority patent/DE1154490B/en
Priority claimed from DEF38578A external-priority patent/DE1217009B/en
Priority claimed from DEF38977A external-priority patent/DE1173907B/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1033773A publication Critical patent/GB1033773A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/14—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof
    • C07C227/16—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton from compounds containing already amino and carboxyl groups or derivatives thereof by reactions not involving the amino or carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/02—Preparation of carboxylic acid amides from carboxylic acids or from esters, anhydrides, or halides thereof by reaction with ammonia or amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/22—Dyes with unsubstituted amino groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
    • C09B1/28—Dyes with amino groups substituted by hydrocarbon radicals substituted by alkyl, aralkyl or cyclo alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/36—Dyes with acylated amino groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
    • C09B5/02—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic ring being only condensed in peri position
    • C09B5/022—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic ring being only condensed in peri position not provided for in one of the sub groups C09B5/04 - C09B5/20
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/02—Ortho- or ortho- and peri-condensed systems
    • C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
    • C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
    • C07C2603/24—Anthracenes; Hydrogenated anthracenes

Abstract

Anthraquinones of the formula <FORM:1033773/C4-C5/1> in which R is nitro or the group <FORM:1033773/C4-C5/2> wherein R1 and R11 are each hydrogen or alkyl or together with the nitrogen N form a heterocyclic ring, or <FORM:1033773/C4-C5/3> represents a phthalimido radical or together with one of the anthraquinone oxygen atoms represents a sulphimido group, R1 is hydrogen or a substituent, R2 is hydrogen, chlorine, bromine or alkyl, R3 is chlorine, m is 0, 1 or 2 and n is 1 or 2, are made by chlorinating an anthraquinone of the formula <FORM:1033773/C4-C5/4> in which R, R1, R2 and n are as above and X is hydrogen or one X is hydrogen and the other is chlorine, or mixtures of such anthraquinones, with chlorine in at least 95% sulphuric acid optionally containing sulphur trioxide or in chlorosulphonic acid, in the presence of halogenation catalysts at between 10 DEG and 80 DEG C., conditions being such that sulphonation does not occur. Starting materials include 1-piperidino-and 1-morpholino-anthraquinones.ALSO:In examples (19-24), 1:4-dichloro-5-nitro-anthraquinone is made by chlorinating 1-nitro-anthraquinone or 1-nitro-5-chloro- or 1-nitro-8-chloro-anthraquinones or mixtures thereof, with chlorine in chlorosulphonic acid, oleum or sulphuric acid monohydrate at temperatures between 10 DEG and 80 DEG C.
GB11444/63A 1962-03-22 1963-03-22 Process for the production of substituted 1,4-dichloro anthraquinones Expired GB1033773A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DEF36343A DE1161252B (en) 1962-03-22 1962-03-22 Process for the preparation of 1, 4-dichloro-5-nitro-anthraquinone
DEF36380A DE1151517B (en) 1962-03-27 1962-03-27 Process for the production of 1, 4-dichloro-5-amino-anthraquinone
DEF37160A DE1154490B (en) 1962-06-26 1962-06-26 Process for the production of chloro-amino-anthraquinones
DEF38578A DE1217009B (en) 1962-12-18 1962-12-18 Process for the preparation of chlorinated 1-amino- or 1,4-diaminoanthraquinones
DEF38977A DE1173907B (en) 1963-02-11 1963-02-11 Process for the preparation of 1, 4-diamino-5, 8-dichloro-anthraquinones

Publications (1)

Publication Number Publication Date
GB1033773A true GB1033773A (en) 1966-06-22

Family

ID=27512037

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11444/63A Expired GB1033773A (en) 1962-03-22 1963-03-22 Process for the production of substituted 1,4-dichloro anthraquinones

Country Status (2)

Country Link
CH (1) CH431485A (en)
GB (1) GB1033773A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978094A (en) * 1973-07-31 1976-08-31 Ciba-Geigy Ag Process for the manufacture of 1,4-diamin O-5-nitroanthraquinone
US3978095A (en) * 1973-07-31 1976-08-31 Ciba-Geigy Ag Process for the manufacture of 1,4-diamino-5-nitroanthraquinone
FR2311768A1 (en) * 1975-05-17 1976-12-17 Bayer Ag PROCESS FOR THE PREPARATION OF CHLORANTHRAQUINONS FROM NITROANTHRAQUINONS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3978094A (en) * 1973-07-31 1976-08-31 Ciba-Geigy Ag Process for the manufacture of 1,4-diamin O-5-nitroanthraquinone
US3978095A (en) * 1973-07-31 1976-08-31 Ciba-Geigy Ag Process for the manufacture of 1,4-diamino-5-nitroanthraquinone
FR2311768A1 (en) * 1975-05-17 1976-12-17 Bayer Ag PROCESS FOR THE PREPARATION OF CHLORANTHRAQUINONS FROM NITROANTHRAQUINONS

Also Published As

Publication number Publication date
CH431485A (en) 1967-03-15

Similar Documents

Publication Publication Date Title
GB1033773A (en) Process for the production of substituted 1,4-dichloro anthraquinones
GB956336A (en) Improvements in materials for forming vesicular images
ES318983A1 (en) A procedure for the preparation of quinolein derivatives. (Machine-translation by Google Translate, not legally binding)
GB1157026A (en) Partial Chlorination of Acetoacetic Acid Monoalkylamides
GB962147A (en) Water-insoluble anthraquinone dyes and process for their manufacture
GB1118131A (en) Improvements in or relating to substituted benzimidazoles and the manufacture thereof
GB852604A (en) New anthraquinone dyestuffs
GB1119679A (en) 1-aminoanthraquinone derivatives and their production
GB1043999A (en) Anthraquinone dyes of the 2-arylaminoquinizarine series and a process for their production
GB877056A (en) Preparation of sulphonamides
GB896803A (en) Process for the manufacture of water-insoluble quinacridones free from sulphonic acid groups
GB1107515A (en) New anthraquinone dyestuffs and processes for their manufacture and use
GB1046522A (en) Process for the production of chlorinated 1-hydroxy-4-amino-anthraquinones
GB733458A (en) Anthraquinone dyestuffs
GB1015406A (en) Process for the production of 3,4-dihydro-benzoxazinones-(1,3,2) and products obtained thereby
GB902058A (en) Process for the preparation of di-benzoxazolyl-ethylene compounds
GB940780A (en) Process for the manufacture of quinacridone dyestuffs
GB1021634A (en) Process for the production of diamino-dihydroxy-anthraquinones
GB834456A (en) Anthraquinone vat dyestuffs and process for their manufacture
GB919864A (en) Process for the preparation of indoles substituted in the benzene ring
GB1119678A (en) 1-aminoanthraquinone derivatives and their production
GB736182A (en) Halogenation of steroid compounds
GB957987A (en) Process for the production of trifluoromethylmercapto-phenols
GB1070313A (en) Aromatic sulphonyl chlorides and sulphonamides
GB1094503A (en) Process for the chlorination of alpha-aminoanthraquinones