GB941365A - Process for polymerising 1, 3-butadiene - Google Patents
Process for polymerising 1, 3-butadieneInfo
- Publication number
- GB941365A GB941365A GB39026/60A GB3902660A GB941365A GB 941365 A GB941365 A GB 941365A GB 39026/60 A GB39026/60 A GB 39026/60A GB 3902660 A GB3902660 A GB 3902660A GB 941365 A GB941365 A GB 941365A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- butadiene
- cobalt
- triethyl
- specified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 title abstract 10
- 238000000034 method Methods 0.000 title abstract 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 6
- 150000003839 salts Chemical class 0.000 abstract 4
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical group CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- -1 aliphatic amines Chemical class 0.000 abstract 3
- 239000004411 aluminium Substances 0.000 abstract 3
- 229910052782 aluminium Inorganic materials 0.000 abstract 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical class [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 2
- AMFIJXSMYBKJQV-UHFFFAOYSA-L cobalt(2+);octadecanoate Chemical compound [Co+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AMFIJXSMYBKJQV-UHFFFAOYSA-L 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- 235000021317 phosphate Nutrition 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical class [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical class CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical class CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 125000005595 acetylacetonate group Chemical group 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 abstract 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 abstract 1
- 150000004648 butanoic acid derivatives Chemical class 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical class [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 abstract 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 abstract 1
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 abstract 1
- FJDJVBXSSLDNJB-LNTINUHCSA-N cobalt;(z)-4-hydroxypent-3-en-2-one Chemical compound [Co].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O FJDJVBXSSLDNJB-LNTINUHCSA-N 0.000 abstract 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000002823 nitrates Chemical class 0.000 abstract 1
- 150000003891 oxalate salts Chemical class 0.000 abstract 1
- 229910052763 palladium Chemical class 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 150000003003 phosphines Chemical class 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 abstract 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical group CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012991 xanthate Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/907—Specified means of reacting components of transition metal catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1915459 | 1959-11-18 | ||
| IT595360 | 1960-04-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB941365A true GB941365A (en) | 1963-11-13 |
Family
ID=26325741
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39026/60A Expired GB941365A (en) | 1959-11-18 | 1960-11-14 | Process for polymerising 1, 3-butadiene |
| GB39025/60A Expired GB942149A (en) | 1959-11-18 | 1960-11-14 | Process for polymerizing 1,3-butadiene |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39025/60A Expired GB942149A (en) | 1959-11-18 | 1960-11-14 | Process for polymerizing 1,3-butadiene |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3182051A (en:Method) |
| BE (2) | BE597164A (en:Method) |
| DE (2) | DE1142702B (en:Method) |
| ES (2) | ES262543A1 (en:Method) |
| GB (2) | GB941365A (en:Method) |
| NL (4) | NL257560A (en:Method) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297667A (en) * | 1963-02-28 | 1967-01-10 | Union Carbide Corp | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
| US3414575A (en) * | 1964-12-09 | 1968-12-03 | Dow Chemical Co | Anhydrous crystalline complexes of cobaltous salts and nitrogenous bases |
| US3482001A (en) * | 1966-05-23 | 1969-12-02 | Sun Oil Co | Dimerization of propylene to dimethylbutenes |
| US3498963A (en) * | 1966-09-26 | 1970-03-03 | Japan Synthetic Rubber Co Ltd | Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration |
| US3535303A (en) * | 1967-08-11 | 1970-10-20 | Japan Synthetic Rubber Co Ltd | Process for the preparation of unsaturated hydrocarbon polymers having a high percentage of vinyl opening configuration |
| US3914210A (en) * | 1974-09-26 | 1975-10-21 | Firestone Tire & Rubber Co | Process for polymerizing butadiene having a high proportion of syndiotactic 1,2-microstructure |
| JPS5688409A (en) * | 1979-12-20 | 1981-07-17 | Ube Ind Ltd | Preparation of reinforced polybutadiene rubber |
| US4389436A (en) * | 1981-12-28 | 1983-06-21 | Mobil Oil Corporation | Flexible film laminate and retortable food pouch therefrom |
| FI98916C (fi) * | 1994-03-24 | 1997-09-10 | Borealis Polymers Oy | Menetelmä eteenin ja -olefiinin kopolymeroimiseksi |
| US7009013B2 (en) * | 2002-07-22 | 2006-03-07 | Jsr Corporation | Process for producing crystalline 1,2-polybutadiene |
| WO2007023618A1 (en) * | 2005-08-26 | 2007-03-01 | Sumitomo Chemical Company, Limited | Homopolymer and copolymer, and production process thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU35089A1 (en:Method) * | 1956-04-13 | |||
| US2977349A (en) * | 1956-11-07 | 1961-03-28 | Goodrich Gulf Chem Inc | Process for polymerizing dienes |
| BE440565A (en:Method) * | 1957-06-06 | |||
| US2953556A (en) * | 1957-07-18 | 1960-09-20 | Goodrich Gulf Chem Inc | Polymer recovery process |
| NL233912A (en:Method) * | 1957-12-06 |
-
0
- NL NL257561D patent/NL257561A/xx unknown
- NL NL132382D patent/NL132382C/xx active
- BE BE597165D patent/BE597165A/xx unknown
- NL NL132383D patent/NL132383C/xx active
- NL NL257560D patent/NL257560A/xx unknown
- BE BE597164D patent/BE597164A/xx unknown
-
1960
- 1960-11-14 GB GB39026/60A patent/GB941365A/en not_active Expired
- 1960-11-14 GB GB39025/60A patent/GB942149A/en not_active Expired
- 1960-11-14 DE DEM47107A patent/DE1142702B/de active Pending
- 1960-11-15 US US69346A patent/US3182051A/en not_active Expired - Lifetime
- 1960-11-16 DE DEM47142A patent/DE1156239B/de active Pending
- 1960-11-17 ES ES0262543A patent/ES262543A1/es not_active Expired
- 1960-11-17 ES ES0262542A patent/ES262542A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1156239B (de) | 1963-10-24 |
| NL257560A (en:Method) | |
| DE1142702B (de) | 1963-01-24 |
| GB942149A (en) | 1963-11-20 |
| BE597165A (en:Method) | |
| BE597164A (en:Method) | |
| ES262542A1 (es) | 1961-06-01 |
| NL257561A (en:Method) | |
| NL132383C (en:Method) | |
| ES262543A1 (es) | 1961-06-01 |
| US3182051A (en) | 1965-05-04 |
| NL132382C (en:Method) |
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