GB1212428A - Process for production of polyolefins - Google Patents

Process for production of polyolefins

Info

Publication number
GB1212428A
GB1212428A GB3824368A GB3824368A GB1212428A GB 1212428 A GB1212428 A GB 1212428A GB 3824368 A GB3824368 A GB 3824368A GB 3824368 A GB3824368 A GB 3824368A GB 1212428 A GB1212428 A GB 1212428A
Authority
GB
United Kingdom
Prior art keywords
zinc
vocl
ticl
alcl
aug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3824368A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scholven Chemie AG
Original Assignee
Scholven Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scholven Chemie AG filed Critical Scholven Chemie AG
Publication of GB1212428A publication Critical patent/GB1212428A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1,212,428. Four or more component Zeigler catalyst for olefin polymerization. SCHOLVEN-CHEMIE A.G. 9 Aug., 1968 [12 Aug., 1967], No. 38243/68. Heading C3P. α-Olefins are polymerized by contacting with a catalyst comprising (a) coprecipitated titanium and vanadium compounds, (b) an organometallic compound of Groups I to III and (c) an alkyl zinc or cadmium compound, the molar ratio of (b) to (c) being between 1: 1 and 100: 1. Component (c) may be a zinc alkyl halide or dialkyl zinc or mixture thereof. In the examples the catalysts employed are Al(C 2 H 5 ) 3 - BF 3 - TiCl 4 - VOCl 3 - Al(C 2 H 5 ) 2 Cl or Al(C 2 H 5 ) 2 F - Al(C 2 H 5 ) 2 Cl - TiCl 4 - VOCl 3 - further Al(C 2 H 5 ) 2 Cl or Ti(OC 3 H 7 ) 4 - vanadium chloride - (C 2 H 5 ) 2 AlCl - further (C 2 H 5 ) 2 AlCl, together with Zn(C 2 H 5 ) 2 or Cd(C 2 H 5 ) 2 , Al(C 2 H 5 ) 3 , and Al(C 2 H 5 ) 2 Cl, in the homopolymerization of ethylene and copolymerization with butene.
GB3824368A 1967-08-12 1968-08-09 Process for production of polyolefins Expired GB1212428A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESC041142 1967-08-12

Publications (1)

Publication Number Publication Date
GB1212428A true GB1212428A (en) 1970-11-18

Family

ID=7436059

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3824368A Expired GB1212428A (en) 1967-08-12 1968-08-09 Process for production of polyolefins

Country Status (7)

Country Link
AT (1) AT283721B (en)
BE (1) BE718933A (en)
DE (1) DE1745461A1 (en)
FR (1) FR1575247A (en)
GB (1) GB1212428A (en)
LU (1) LU56637A1 (en)
NL (1) NL6811268A (en)

Also Published As

Publication number Publication date
AT283721B (en) 1970-08-25
LU56637A1 (en) 1968-11-14
BE718933A (en) 1969-01-16
DE1745461A1 (en) 1971-09-09
FR1575247A (en) 1969-07-18
NL6811268A (en) 1969-02-14

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees