GB1154884A - Process for the preparation of an Olefin Polymer having a Broad Molecular Weight Distribution - Google Patents

Process for the preparation of an Olefin Polymer having a Broad Molecular Weight Distribution

Info

Publication number
GB1154884A
GB1154884A GB1272367A GB1272367A GB1154884A GB 1154884 A GB1154884 A GB 1154884A GB 1272367 A GB1272367 A GB 1272367A GB 1272367 A GB1272367 A GB 1272367A GB 1154884 A GB1154884 A GB 1154884A
Authority
GB
United Kingdom
Prior art keywords
molecular weight
weight distribution
broad molecular
preparation
march
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1272367A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1154884A publication Critical patent/GB1154884A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1,154,884. Olefin polymers. FARBWERKE HOECHST A.G. 17 March, 1967 [19 March, 1966], No. 12723/67. Heading C3P. Olefin polymers having a broad molecular weight distribution are made by polymerizing ethylene with if desired up to 5% by weight of butene-1 or propylene, in an inert solvent or dispersing agent, in the presence of hydrogen, and a catalyst comprising diethyl aluminium monochloride; and (a) one part of the solid reaction product of TiCl 4 with one or more alkyl aluminium compounds containing chlorine, and (b) 0À1 to 0À4 part of the solid reaction product of Ti(OR) 4-n Cl n (in which n = 1 to 3, and R represents an isopropyl or isobutyl radical) with diethylaluminium monochloride and/or ethyl aluminium sesquichloride. Component (b) may be formed in situ in the presence of component (a) and similarly (a) may be formed in presence of (b). The polymerization is preferably effected in a diesel oil fraction, and the catalyst decomposed with n-butanol. The molecular weight distribution corresponds to the degree of molecular inhomogeneity (U-value).
GB1272367A 1966-03-19 1967-03-17 Process for the preparation of an Olefin Polymer having a Broad Molecular Weight Distribution Expired GB1154884A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0048707 1966-03-19

Publications (1)

Publication Number Publication Date
GB1154884A true GB1154884A (en) 1969-06-11

Family

ID=7102431

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1272367A Expired GB1154884A (en) 1966-03-19 1967-03-17 Process for the preparation of an Olefin Polymer having a Broad Molecular Weight Distribution

Country Status (8)

Country Link
AT (1) AT272635B (en)
BE (1) BE695775A (en)
DE (1) DE1595606A1 (en)
ES (1) ES338124A1 (en)
FR (1) FR1514892A (en)
GB (1) GB1154884A (en)
NL (1) NL6703831A (en)
SE (1) SE331571B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363902A (en) * 1980-03-17 1982-12-14 Wacker-Chemie Gmbh Process and heavy metal catalyst for the polymerization of α-olefins, particularly polyethylene
US4448944A (en) * 1981-06-20 1984-05-15 Hoechst Aktiengesellschaft Process for the preparation of a polyolefin, and a catalyst for this process
US4935474A (en) * 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363902A (en) * 1980-03-17 1982-12-14 Wacker-Chemie Gmbh Process and heavy metal catalyst for the polymerization of α-olefins, particularly polyethylene
US4448944A (en) * 1981-06-20 1984-05-15 Hoechst Aktiengesellschaft Process for the preparation of a polyolefin, and a catalyst for this process
US4935474A (en) * 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution

Also Published As

Publication number Publication date
DE1595606A1 (en) 1970-04-30
FR1514892A (en) 1968-02-23
ES338124A1 (en) 1968-05-01
SE331571B (en) 1971-01-04
BE695775A (en) 1967-09-20
AT272635B (en) 1969-07-10
NL6703831A (en) 1967-09-20

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