GB934444A - Polymerisation and copolymerisation of ethylene - Google Patents
Polymerisation and copolymerisation of ethyleneInfo
- Publication number
- GB934444A GB934444A GB4238359A GB4238359A GB934444A GB 934444 A GB934444 A GB 934444A GB 4238359 A GB4238359 A GB 4238359A GB 4238359 A GB4238359 A GB 4238359A GB 934444 A GB934444 A GB 934444A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- peroxide
- reactor
- polymerization
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 7
- 239000005977 Ethylene Substances 0.000 title abstract 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- -1 vinyl compound Chemical class 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 2
- 238000002347 injection Methods 0.000 abstract 2
- 239000007924 injection Substances 0.000 abstract 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 abstract 2
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000003505 polymerization initiator Substances 0.000 abstract 2
- 239000001294 propane Substances 0.000 abstract 2
- 150000003254 radicals Chemical class 0.000 abstract 2
- CWLGEPSKQDNHIO-JOBJLJCHSA-N (e)-n-[(e)-benzylideneamino]-1-phenylmethanimine Chemical compound C=1C=CC=CC=1/C=N/N=C/C1=CC=CC=C1 CWLGEPSKQDNHIO-JOBJLJCHSA-N 0.000 abstract 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004159 Potassium persulphate Substances 0.000 abstract 1
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- IWTBWSGPDGPTIB-UHFFFAOYSA-N butanoyl butaneperoxoate Chemical compound CCCC(=O)OOC(=O)CCC IWTBWSGPDGPTIB-UHFFFAOYSA-N 0.000 abstract 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N butyl alcohol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical class OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 abstract 1
- RHMZKSWPMYAOAZ-UHFFFAOYSA-N diethyl peroxide Chemical compound CCOOCC RHMZKSWPMYAOAZ-UHFFFAOYSA-N 0.000 abstract 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 abstract 1
- 235000019394 potassium persulphate Nutrition 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US78095358A | 1958-12-17 | 1958-12-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB934444A true GB934444A (en) | 1963-08-21 |
Family
ID=25121193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4238359A Expired GB934444A (en) | 1958-12-17 | 1959-12-14 | Polymerisation and copolymerisation of ethylene |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE585741A (enrdf_load_stackoverflow) |
| DE (1) | DE1294013C2 (enrdf_load_stackoverflow) |
| FR (1) | FR1248159A (enrdf_load_stackoverflow) |
| GB (1) | GB934444A (enrdf_load_stackoverflow) |
| NL (1) | NL246540A (enrdf_load_stackoverflow) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3725378A (en) * | 1958-12-17 | 1973-04-03 | Monsanto Co | Polymerization of ethylene |
| EP0121755A3 (en) * | 1983-03-12 | 1985-10-02 | Basf Aktiengesellschaft | Process for the manufacture of ethylene polymers at a pressure of at least 500 bar in a two-zone tubular reactor |
| WO2013059042A1 (en) | 2011-10-19 | 2013-04-25 | Dow Global Technologies Llc | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
| WO2016050462A1 (en) * | 2014-10-01 | 2016-04-07 | Basell Polyolefine Gmbh | Low density polyethylene with high elongation hardening |
| WO2017106940A1 (pt) * | 2015-12-22 | 2017-06-29 | Braskem S.A. | Dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e processo de produção de polímeros e copolímeros de etileno |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL126425C (enrdf_load_stackoverflow) * | 1961-07-21 | |||
| NL282622A (enrdf_load_stackoverflow) * | 1961-09-01 | |||
| DE2124221B2 (de) * | 1971-05-15 | 1980-10-30 | Imhausen International Co. Reg. Trust, Vaduz | Verfahren zur kontinuierlichen Polymerisation von Äthylen |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1065613B (de) * | 1954-06-30 | 1959-09-17 | Esso Research and Engineering Company, Elizabeth, N J (V St A) | Verfahren zur Polymerisation von Äthylen |
-
0
- BE BE585741D patent/BE585741A/xx unknown
- NL NL246540D patent/NL246540A/xx unknown
-
1959
- 1959-12-14 GB GB4238359A patent/GB934444A/en not_active Expired
- 1959-12-15 FR FR813119A patent/FR1248159A/fr not_active Expired
- 1959-12-17 DE DE1959M0043734 patent/DE1294013C2/de not_active Expired
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3725378A (en) * | 1958-12-17 | 1973-04-03 | Monsanto Co | Polymerization of ethylene |
| EP0121755A3 (en) * | 1983-03-12 | 1985-10-02 | Basf Aktiengesellschaft | Process for the manufacture of ethylene polymers at a pressure of at least 500 bar in a two-zone tubular reactor |
| WO2013059042A1 (en) | 2011-10-19 | 2013-04-25 | Dow Global Technologies Llc | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
| US9120880B2 (en) | 2011-10-19 | 2015-09-01 | Dow Global Technologies Llc | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
| EP3002300A1 (en) | 2011-10-19 | 2016-04-06 | Dow Global Technologies LLC | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
| EP3243849A2 (en) | 2011-10-19 | 2017-11-15 | Dow Global Technologies Llc | Polymerization processes with fresh ethylene distributions for preparation of low density ethylene-based polymers |
| WO2016050462A1 (en) * | 2014-10-01 | 2016-04-07 | Basell Polyolefine Gmbh | Low density polyethylene with high elongation hardening |
| CN107075019A (zh) * | 2014-10-01 | 2017-08-18 | 巴塞尔聚烯烃股份有限公司 | 具有高拉伸硬化的低密度聚乙烯 |
| US10364306B2 (en) | 2014-10-01 | 2019-07-30 | Basell Polyolefine Gmbh | Low density polyethylene with high elongation hardening |
| CN107075019B (zh) * | 2014-10-01 | 2020-05-05 | 巴塞尔聚烯烃股份有限公司 | 具有高拉伸硬化的低密度聚乙烯 |
| WO2017106940A1 (pt) * | 2015-12-22 | 2017-06-29 | Braskem S.A. | Dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e processo de produção de polímeros e copolímeros de etileno |
| US10829568B2 (en) | 2015-12-22 | 2020-11-10 | Braskem S.A. | Tubular reactor polymerization initiator injector device, tubular reactor for continuous polymerization of olefins, and a process for production of polymers and copolymers of ethylene |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1294013C2 (de) | 1980-07-03 |
| FR1248159A (fr) | 1960-12-09 |
| NL246540A (enrdf_load_stackoverflow) | |
| DE1294013B (enrdf_load_stackoverflow) | 1969-04-30 |
| BE585741A (enrdf_load_stackoverflow) |
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