GB917047A - Aliphatic olefinic compounds - Google Patents
Aliphatic olefinic compoundsInfo
- Publication number
- GB917047A GB917047A GB3532260A GB3532260A GB917047A GB 917047 A GB917047 A GB 917047A GB 3532260 A GB3532260 A GB 3532260A GB 3532260 A GB3532260 A GB 3532260A GB 917047 A GB917047 A GB 917047A
- Authority
- GB
- United Kingdom
- Prior art keywords
- olefin
- alcohol
- olefinic compounds
- aliphatic olefinic
- trimethylhexanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The dehydration of primary alcohols having at least 4 carbon atoms to obtain olefins is effected in the vapour phase over activated alumina, the flow rate being greater than that required for complete conversion and sufficient to ensure that the olefinic product contains at least 80% alpha-olefin. The temperature may be 250-400 DEG C. The alcohol may have the formula R1R2CH-CH2OH in which R1 is ethyl or a higher alkyl radical and R2 is hydrogen or alkyl, e.g. n-butyl, n-hexyl, n-octyl, n-decyl, n-dodecyl, n-tetradecyl, n-hexadecyl, or n-octadecyl alcohol, 2-methylpentanol, 2-ethylhexanol, or 3,5,5-trimethylhexanol. The olefin may be separated by filtration, after cooling if necessary or distillation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3532260A GB917047A (en) | 1960-10-14 | 1960-10-14 | Aliphatic olefinic compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3532260A GB917047A (en) | 1960-10-14 | 1960-10-14 | Aliphatic olefinic compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB917047A true GB917047A (en) | 1963-01-30 |
Family
ID=10376409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3532260A Expired GB917047A (en) | 1960-10-14 | 1960-10-14 | Aliphatic olefinic compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB917047A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4398050A (en) * | 1980-02-14 | 1983-08-09 | Sud Chemie, A.G. | Process for the production of olefins from synthesis gas |
US4490567A (en) * | 1982-04-08 | 1984-12-25 | Phillips Petroleum Company | Catalyst and process for dehydrating 2-alcohols |
EP2990395B1 (en) | 2013-04-23 | 2018-01-10 | Kao Corporation | Method for producing olefin |
-
1960
- 1960-10-14 GB GB3532260A patent/GB917047A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4398050A (en) * | 1980-02-14 | 1983-08-09 | Sud Chemie, A.G. | Process for the production of olefins from synthesis gas |
US4490567A (en) * | 1982-04-08 | 1984-12-25 | Phillips Petroleum Company | Catalyst and process for dehydrating 2-alcohols |
EP2990395B1 (en) | 2013-04-23 | 2018-01-10 | Kao Corporation | Method for producing olefin |
EP2990395B2 (en) † | 2013-04-23 | 2022-06-01 | Kao Corporation | Method for producing olefin |
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