GB886768A - Manufacture of sulphonated phosphonic esters - Google Patents
Manufacture of sulphonated phosphonic estersInfo
- Publication number
- GB886768A GB886768A GB2301058A GB2301058A GB886768A GB 886768 A GB886768 A GB 886768A GB 2301058 A GB2301058 A GB 2301058A GB 2301058 A GB2301058 A GB 2301058A GB 886768 A GB886768 A GB 886768A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- ammonium
- sulphonated
- manufacture
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002148 esters Chemical class 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 5
- 150000001340 alkali metals Chemical group 0.000 abstract 4
- -1 n-octyl Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- ZETCGWYACBNPIH-UHFFFAOYSA-N azane;sulfurous acid Chemical compound N.OS(O)=O ZETCGWYACBNPIH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/347—Other P-containing anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4015—Esters of acyclic unsaturated acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
Abstract
Wetting agents of formula <FORM:0886768/IV (b)/1> where R and R1 are C8-10 alkyl, and X is alkali metal or ammonium are prepared by heating a bis(C8-10 alkyl) ester of vinylphosphonic acid to 70 DEG C.-120 DEG C. with an alkali metal bisulphite or ammonium bisulphite in the presence of catalytic quantities of an oxygenyielding compound selected from alkali metal persulphates, ammonium persulphate, alkali metal perborates and alkali metal percarbonates. Preferably 0.5%-5% by weight of catalyst based on the ester is used. In examples R and R1 are n-octyl, n-decyl and 2-ethylhexyl and X is Na. Specifications 841,886 and 858,057 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF23506A DE1041045B (en) | 1957-07-17 | 1957-07-17 | Process for the production of wetting agents |
Publications (1)
Publication Number | Publication Date |
---|---|
GB886768A true GB886768A (en) | 1962-01-10 |
Family
ID=7090869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2301058A Expired GB886768A (en) | 1957-07-17 | 1958-07-17 | Manufacture of sulphonated phosphonic esters |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE569525A (en) |
CH (1) | CH371794A (en) |
DE (1) | DE1041045B (en) |
FR (1) | FR1206319A (en) |
GB (1) | GB886768A (en) |
NL (2) | NL229481A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1154470B (en) * | 1959-02-04 | 1963-09-19 | Bayer Ag | Process for the production of phosphonic or thio or dithiophosphonic acid esters |
BE587271A (en) * | 1959-02-04 | 1900-01-01 |
-
0
- NL NL100011D patent/NL100011C/xx active
- NL NL229481D patent/NL229481A/xx unknown
- BE BE569525D patent/BE569525A/xx unknown
-
1957
- 1957-07-17 DE DEF23506A patent/DE1041045B/en active Pending
-
1958
- 1958-07-15 CH CH6176658A patent/CH371794A/en unknown
- 1958-07-17 GB GB2301058A patent/GB886768A/en not_active Expired
- 1958-07-17 FR FR1206319D patent/FR1206319A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1041045B (en) | 1958-10-16 |
NL229481A (en) | |
BE569525A (en) | |
FR1206319A (en) | 1960-02-09 |
NL100011C (en) | |
CH371794A (en) | 1963-09-15 |
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