GB855485A - Improvements in the production of unsaturated hydrocarbons by cracking hydrocarbons - Google Patents

Improvements in the production of unsaturated hydrocarbons by cracking hydrocarbons

Info

Publication number
GB855485A
GB855485A GB8736/59A GB873659A GB855485A GB 855485 A GB855485 A GB 855485A GB 8736/59 A GB8736/59 A GB 8736/59A GB 873659 A GB873659 A GB 873659A GB 855485 A GB855485 A GB 855485A
Authority
GB
United Kingdom
Prior art keywords
solid
added
coke
hydrocarbons
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8736/59A
Inventor
Adolf Steinhofer
Otto Frey
Helmut Nonnenmacher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB855485A publication Critical patent/GB855485A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Gaseous unsaturated hydrocarbons, particularly ethylene and propylene, are prepared by cracking liquid hydrocarbons at 600-900 DEG C., in the presence of 20-200% by weight of steam in a fluidized bed of solid to which is added a small amount of a compound of an element of Group 1a or 2a of the Periodic Table. The liquid hydrocarbon may be a petroleum fraction, crude oil or residue. Normal pressure or increased pressure, e.g. 5-20 atmospheres may be used. Oxygen may also be added separately or mixed with the hydrocarbon. The solid material may be a synthetic or natural material containing magnesium, aluminium or silicon, e.g. sillimanite, corundum or magnesite, or carbon, e.g. high temperature coke anthracite, brown coal low temperature coke or oil coke, preferably that formed in the process. The added compound may be impregnated into the solid or added direct to the bed in solid, pulverulent form, particularly when coke is the solid. The solid may contain 0,01-1% of the element of Group 1a or 2a which is preferably added as the oxide or a compound forming the oxide such as the nitrate or carbonate. Specified elements are sodium, potassium, beryllium, calcium and magnesium. If the initial material contains sulphur this appears in the product as hydrogen sulphide and not the corrosive oxides.
GB8736/59A 1958-03-19 1959-03-13 Improvements in the production of unsaturated hydrocarbons by cracking hydrocarbons Expired GB855485A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1958B0048237 DE1072237B (en) 1958-03-19 1958-03-19 Process for the production of unsaturated hydrocarbons, in particular ethylene and propylene, by splitting hydrocarbons

Publications (1)

Publication Number Publication Date
GB855485A true GB855485A (en) 1960-11-30

Family

ID=29723043

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8736/59A Expired GB855485A (en) 1958-03-19 1959-03-13 Improvements in the production of unsaturated hydrocarbons by cracking hydrocarbons

Country Status (3)

Country Link
US (1) US3027415A (en)
DE (1) DE1072237B (en)
GB (1) GB855485A (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL274559A (en) * 1961-02-09
GB1397315A (en) * 1972-08-14 1975-06-11 Haldor Topsoe As Process for catalytic steam cracking
US3985641A (en) * 1974-04-15 1976-10-12 Phillips Petroleum Company Catalytic cracking of alkanes
JPS5251303A (en) * 1975-10-21 1977-04-25 Mitsubishi Chem Ind Ltd Process for preparation of olefins
JPS5262205A (en) * 1975-11-17 1977-05-23 Mitsubishi Chem Ind Ltd Process for preparation of olefins
US4409094A (en) * 1980-08-08 1983-10-11 Massachusetts Institute Of Technology Process for detoxifying coal tars
US4412911A (en) * 1982-02-24 1983-11-01 Exxon Research And Engineering Co. Process for reactivating perovskite catalysts and hydrocarbon treating processes utilizing the reactivated catalysts
US5071817A (en) * 1988-12-05 1991-12-10 Kolts John H Dehydrogenation catalyst
US4956515A (en) * 1988-12-05 1990-09-11 Phillips Petroleum Company Dehydrogenation process and catalyst

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2127953A (en) * 1936-07-25 1938-08-23 Phillips Petroleum Co Process of treating hydrocarbon oils
US2303547A (en) * 1940-06-18 1942-12-01 William T Hancock Method of refining hydrocarbons by cracking and catalysis
US2510994A (en) * 1947-12-26 1950-06-13 Houdry Process Corp Hydrocarbon conversion with the use of a precipitated and calcined beryllium oxide catalyst
US2867676A (en) * 1956-01-04 1959-01-06 Sinclair Refining Co Process for conducting high temperature conversions using fluidized solids as heat exchange media
US2871173A (en) * 1958-02-04 1959-01-27 Seymour Mfg Company Method of making ductile copper platings

Also Published As

Publication number Publication date
DE1072237B (en) 1959-12-31
US3027415A (en) 1962-03-27

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