GB851783A - Production of nitrilotriacetonitrile - Google Patents
Production of nitrilotriacetonitrileInfo
- Publication number
- GB851783A GB851783A GB6367/59A GB636759A GB851783A GB 851783 A GB851783 A GB 851783A GB 6367/59 A GB6367/59 A GB 6367/59A GB 636759 A GB636759 A GB 636759A GB 851783 A GB851783 A GB 851783A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- acids
- concentrated
- solution
- reacting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- LJAIDEYQVIJERM-UHFFFAOYSA-N 2-[bis(cyanomethyl)amino]acetonitrile Chemical compound N#CCN(CC#N)CC#N LJAIDEYQVIJERM-UHFFFAOYSA-N 0.000 title abstract 2
- LELOWRISYMNNSU-UHFFFAOYSA-N Hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 abstract 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 abstract 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N Sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 2
- 229910006069 SO3H Inorganic materials 0.000 abstract 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000009738 saturating Methods 0.000 abstract 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 abstract 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 abstract 1
- 235000010288 sodium nitrite Nutrition 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 1
- 239000004291 sulphur dioxide Substances 0.000 abstract 1
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
Abstract
Nitrilotriacetonitrile is prepared by reacting hydrocyanic acid and formaldehyde with one or more compounds of formula HO3S.NRR1, where R and R1 which may be the same or different, are H or -SO3H, e.g. by adding formaldehyde, gaseous or as aqueous solution, to an aqueous solution of the sulphuric and hydrocyanic acids; the reactants are preferably in approximately stoichiometric proportions. The sulphonic acids may be prepared by passing sulphur trioxide into concentrated aqueous ammonia; by saturating a concentrated hydroxylamine hydrochloride solution with sulphur dioxide; or, as salts, by reacting a concentrated sodium bisulphite solution with sodium nitrite with ice cooling: nitrilosulphonic acid can be obtained from the sodium salt so prepared, and can be hydrolysed to imido sulphonic and amidosulphonic acids. Specification 496,781 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE851783X | 1958-03-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB851783A true GB851783A (en) | 1960-10-19 |
Family
ID=6782285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6367/59A Expired GB851783A (en) | 1958-03-19 | 1959-02-24 | Production of nitrilotriacetonitrile |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB851783A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3546271A (en) * | 1968-06-27 | 1970-12-08 | Hooker Chemical Corp | Process for the production of amineacetonitriles |
-
1959
- 1959-02-24 GB GB6367/59A patent/GB851783A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3546271A (en) * | 1968-06-27 | 1970-12-08 | Hooker Chemical Corp | Process for the production of amineacetonitriles |
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