GB827371A - Manufacture of stable aqueous dispersions of synthetic resins capable of being hardened - Google Patents

Manufacture of stable aqueous dispersions of synthetic resins capable of being hardened

Info

Publication number
GB827371A
GB827371A GB5903/56A GB590856A GB827371A GB 827371 A GB827371 A GB 827371A GB 5903/56 A GB5903/56 A GB 5903/56A GB 590856 A GB590856 A GB 590856A GB 827371 A GB827371 A GB 827371A
Authority
GB
United Kingdom
Prior art keywords
aldehyde
resin
acid
polyvinyl
polyvinyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5903/56A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB827371A publication Critical patent/GB827371A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/28Chemically modified polycondensates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/05Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/34Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C08L61/04, C08L61/18 and C08L61/20
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/07Aldehydes; Ketones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Colloid Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

Stable aqueous dispersions are obtained by dispersing (a) a phenol-aldehyde (other than xylenol-aldehyde) resole and/or an epoxide resin and/or a furfuryl alcohol resin, such resin being not itself dispersible in an aqueous solution of polyvinyl alcohol, and the epoxide resin and the furfuryl alcohol resin being still soluble in organic solvents, and (b) a xylenol-aldehyde resole or a mixture of xylenol and aldehyde, the weight ratio of (a) to (b) being 1 : 9 to 9 : 1, in (c) an aqueous solution of polyvinyl alcohol and/or a water-soluble derivative p thereof. Phenols mentioned are phenol and cresol; aldehydes mentioned are formaldehyde, acetaldehyde and butyraldehyde. The epoxide resins are defined as reaction products of epichlorhydrin or other suitable chlorhydrins with polyhydric phenols (e.g. dihydroxydiphenyl - dimethyl methane, resorcinol or novolaks) or with polyhydric alcohols. Organic solvents for dissolving (a) and (b) include methanol, ethanol, isopropanol, butanol, methyl or ethyl acetate, acetone or mixtures thereof. Or reactive nonvolatile solvents may be used, e.g. furfuryl alcohol, furfural, aldol, and reaction products of acetaldehyde and formaldehyde provided they are still liquid. Derivatives of polyvinyl alcohol mentioned under (c) are partially hydrolysed polyvinyl acetal (e.g. butyral, propional, valeral or acetal), partially hydrolysed polyvinyl acetate and the reaction product of polyvinyl alcohol with butyraldehyde sulphonic acid (or the Na or NH4 salts thereof). Optional additives include (i) fillers, e.g. silicon, silicon carbide, graphite, coke, silicon dioxide, quartz, titanium dioxide, barium sulphate, hardened phenol-aldehyde resins, polyvinyl chloride, polytetrafluorethylene, polytrifluorochlorethylene, polyisobutylene, or polyethylene; (ii) acid hardeners, e.g. 1 : 5-naphthalene disulphonic acid, paratoluene sulphonic acid, b -naphthaleneor paratoluene - sulphochloride, trichloracetic acid, maleic anhydride, hydrogen chloride, phosphoric or sulphuric acids; and (iii) chlorhydrins, e.g. 1 : 3-dichloropropanol, monochloropropanol, dichlorhydrin, 1 : 2-dichloropropanol, glycol chlorhydrin, epichlorhydrin or dichlorotertiary-isobutanol. Uses.-Application to floors, waste-water conduits or pits to give chemical and mechanical protection.
GB5903/56A 1955-02-25 1956-02-24 Manufacture of stable aqueous dispersions of synthetic resins capable of being hardened Expired GB827371A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF16912A DE1023882B (en) 1955-02-25 1955-02-25 Process for the production of stable aqueous dispersions of curable synthetic resins

Publications (1)

Publication Number Publication Date
GB827371A true GB827371A (en) 1960-02-03

Family

ID=7088390

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5903/56A Expired GB827371A (en) 1955-02-25 1956-02-24 Manufacture of stable aqueous dispersions of synthetic resins capable of being hardened

Country Status (5)

Country Link
BE (1) BE545569A (en)
CH (1) CH364898A (en)
DE (1) DE1023882B (en)
GB (1) GB827371A (en)
NL (1) NL105559C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4124554A (en) * 1977-02-03 1978-11-07 Union Carbide Corporation Post-formed aqueous phenolic resin dispersions
FR2638750B1 (en) * 1988-11-08 1992-06-05 Ceca Sa PROCESS FOR OBTAINING STABLE AQUEOUS DISPERSIONS OF LOW-FORMOL PHENOLIC RESOLS

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR700411A (en) * 1929-08-14 1931-02-28 Ig Farbenindustrie Ag Process for the preparation of high molecular weight substances

Also Published As

Publication number Publication date
CH364898A (en) 1962-10-15
BE545569A (en) 1959-10-09
NL204682A (en) 1963-03-15
NL105559C (en) 1963-08-15
DE1023882B (en) 1958-02-06

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