GB785314A - Improvements in and relating to the polymerisation of olefines - Google Patents
Improvements in and relating to the polymerisation of olefinesInfo
- Publication number
- GB785314A GB785314A GB3736154A GB3736154A GB785314A GB 785314 A GB785314 A GB 785314A GB 3736154 A GB3736154 A GB 3736154A GB 3736154 A GB3736154 A GB 3736154A GB 785314 A GB785314 A GB 785314A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- group
- organo
- metal
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004411 aluminium Substances 0.000 abstract 18
- 229910052782 aluminium Inorganic materials 0.000 abstract 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 10
- -1 hydrocarbon radical Chemical group 0.000 abstract 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- 150000002894 organic compounds Chemical class 0.000 abstract 6
- 229910052708 sodium Inorganic materials 0.000 abstract 6
- 239000011734 sodium Substances 0.000 abstract 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 4
- 150000002736 metal compounds Chemical class 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 229930195733 hydrocarbon Natural products 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 abstract 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 abstract 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001805 chlorine compounds Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 abstract 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 150000002170 ethers Chemical class 0.000 abstract 2
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 abstract 2
- 229910052733 gallium Inorganic materials 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 150000004678 hydrides Chemical class 0.000 abstract 2
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 abstract 2
- 229910052738 indium Inorganic materials 0.000 abstract 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 2
- 229910052758 niobium Inorganic materials 0.000 abstract 2
- 239000010955 niobium Substances 0.000 abstract 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 229910052715 tantalum Inorganic materials 0.000 abstract 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 2
- 229910052716 thallium Inorganic materials 0.000 abstract 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 abstract 2
- 150000003568 thioethers Chemical class 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 2
- 150000003624 transition metals Chemical class 0.000 abstract 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 239000010937 tungsten Substances 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 238000005194 fractionation Methods 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL203032D NL203032A (enrdf_load_stackoverflow) | 1954-12-24 | ||
| BE543941D BE543941A (enrdf_load_stackoverflow) | 1954-12-24 | ||
| NL107439D NL107439C (enrdf_load_stackoverflow) | 1954-12-24 | ||
| NL229912D NL229912A (enrdf_load_stackoverflow) | 1954-12-24 | ||
| GB3736154A GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
| FR1142456D FR1142456A (fr) | 1954-12-24 | 1955-12-23 | Polymérisation d'oléfines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3736154A GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB785314A true GB785314A (en) | 1957-10-23 |
Family
ID=10395877
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3736154A Expired GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE543941A (enrdf_load_stackoverflow) |
| FR (1) | FR1142456A (enrdf_load_stackoverflow) |
| GB (1) | GB785314A (enrdf_load_stackoverflow) |
| NL (3) | NL107439C (enrdf_load_stackoverflow) |
Cited By (55)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2930783A (en) * | 1955-11-04 | 1960-03-29 | Huels Chemische Werke Ag | Method of purifying low-pressure polyolefines |
| US2935542A (en) * | 1958-09-09 | 1960-05-03 | Exxon Research Engineering Co | Propylene polymers oils |
| US2935498A (en) * | 1957-07-01 | 1960-05-03 | Eastman Kodak Co | Polymerization of alpha-olefins to solid polymers with a three-component catalyst |
| US2945018A (en) * | 1958-01-21 | 1960-07-12 | Shell Oil Co | Olefin polymerization |
| US2962490A (en) * | 1955-08-22 | 1960-11-29 | Phillips Petroleum Co | Process and catalyst for production of olefin polymers |
| US2965626A (en) * | 1956-03-28 | 1960-12-20 | Standard Oil Co | Ethylene polymerization process |
| US2965625A (en) * | 1958-01-27 | 1960-12-20 | Shell Oil Co | Process of polymerizing a conjugated diene |
| US2976260A (en) * | 1958-11-28 | 1961-03-21 | Eastman Kodak Co | Poly-alpha-olefins containing certain 4-alkoxy-2-hydroxybenzophenones and alkylene-bis-phenols |
| US2993883A (en) * | 1959-03-25 | 1961-07-25 | Phillips Petroleum Co | Production of polymers of ethylene with a catalyst of a chromyl halide, an aluminum halide, and a hydrocarbon metal halide |
| US2996459A (en) * | 1958-02-03 | 1961-08-15 | Monsanto Chemicals | Method for preparing a ziegler polymerization catalyst |
| US3012024A (en) * | 1957-11-25 | 1961-12-05 | Celanese Corp | Dry feed in forming slurry in olefin polymerization |
| US3032509A (en) * | 1958-02-03 | 1962-05-01 | Exxon Research Engineering Co | Partially-reduced cocrystallized transition metal halide polymerization catalyst |
| US3040014A (en) * | 1959-05-27 | 1962-06-19 | Exxon Research Engineering Co | Melt index and brittleness of polypropylene |
| US3042626A (en) * | 1956-05-21 | 1962-07-03 | Du Pont | Polymerization catalyst and process |
| US3047557A (en) * | 1957-10-19 | 1962-07-31 | Hoechst Ag | Process for polymerizing olefins with catalysts of ticl dialkyl aluminum fluorides in combination with another dialkyl aluminum halide |
| US3051692A (en) * | 1960-06-06 | 1962-08-28 | Phillips Petroleum Co | Production of solid olefin polymers |
| US3063979A (en) * | 1959-03-11 | 1962-11-13 | Du Pont | Polymerization catalysts |
| US3066127A (en) * | 1959-09-30 | 1962-11-27 | Shell Oil Co | Polymerization process |
| US3073809A (en) * | 1958-07-31 | 1963-01-15 | Union Carbide Corp | Process for producing ethylene-1-olefin copolymers |
| US3076796A (en) * | 1958-04-11 | 1963-02-05 | Union Carbide Corp | Ethylene polymerization catalysts |
| US3078264A (en) * | 1956-01-30 | 1963-02-19 | Celanese Corp | Polymerization of ethylene and catalyst therefor |
| US3103501A (en) * | 1961-08-03 | 1963-09-10 | - olefins containing alkylidene- | |
| US3108145A (en) * | 1960-11-29 | 1963-10-22 | Sun Oil Co | Preparation of olefin polymers |
| US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
| US3131171A (en) * | 1958-11-14 | 1964-04-28 | Monsanto Chemicals | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride |
| US3134822A (en) * | 1959-12-01 | 1964-05-26 | Gulf Research Development Co | Benzene alkylation with a catalyst consisting essentially of either sbcl or sncl and an alkyl aluminum sesquichloride |
| US3143537A (en) * | 1959-03-05 | 1964-08-04 | Eastman Kodak Co | Olefin polymerization using an aluminum alkyl-transition element compound-alkali metal fluoride catalyst composition |
| US3156736A (en) * | 1959-01-08 | 1964-11-10 | Shell Oil Co | Process for preparation of synthetic lubricants |
| US3159607A (en) * | 1958-05-20 | 1964-12-01 | Dal Mon Research Co | Polymerization process |
| US3162620A (en) * | 1961-05-04 | 1964-12-22 | Du Pont | Ethylene polymers prepared in the form of a coherent film at a quiescent liquid catalyst surface |
| US3164577A (en) * | 1960-10-12 | 1965-01-05 | Grace W R & Co | Propylene polymerization catalyst |
| US3165503A (en) * | 1959-04-07 | 1965-01-12 | Goodrich Gulf Chem Inc | Method of polymerizing butadiene-1, 3-hydrocarbons |
| US3179649A (en) * | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
| US3208985A (en) * | 1957-12-11 | 1965-09-28 | Wacker Chemie Gmbh | Olefin polymerization with a heavy metal compound-organohydrogen siloxane catalyst |
| US3225022A (en) * | 1960-12-27 | 1965-12-21 | Monsanto Co | Catalyst compositions comprising aluminum chloride |
| US3313792A (en) * | 1962-03-16 | 1967-04-11 | Shell Oil Co | Process for polymerizing conjugated dienes with a catalyst comprising an aluminum halide, a salt of cobalt or nickel, and a compound of the formula sihxy (4-x) |
| US3328378A (en) * | 1961-05-17 | 1967-06-27 | Wacker Chemie Gmbh | Method for polymerizing unsaturated organic compounds |
| US3342793A (en) * | 1962-05-07 | 1967-09-19 | Snia Viscosa | Polymerization of alpha-olefins in the presence of ticl3.1/3alcl3, alkali metal and an alkyl phosphoramide or sulfuric amide |
| US3370052A (en) * | 1957-12-11 | 1968-02-20 | Montedison Spa | Process for the production of high molecular weight amorphous copolymerizates of ethylene and a higher alpha-olefin in increased yields |
| US3378606A (en) * | 1962-09-10 | 1968-04-16 | Uniroyal Inc | Semicrystalline stereoblock copolymers |
| US3418304A (en) * | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
| US3450682A (en) * | 1963-11-14 | 1969-06-17 | Mitsui Petrochemical Ind | Process for preparation of crystalline high polymers of olefins |
| US3453250A (en) * | 1961-10-18 | 1969-07-01 | Montedison Spa | Cyclic polyene/mono-olefin copolymerizates and processes for producing them |
| US3502637A (en) * | 1958-02-11 | 1970-03-24 | Montedison Spa | Homogeneous stereospecific catalysts and polymerization of butadiene therewith |
| US3511821A (en) * | 1963-10-23 | 1970-05-12 | Exxon Research Engineering Co | Terpolymers of isobutylene-methylcyclopentadiene and a crosslinking agent |
| US3678025A (en) * | 1970-05-22 | 1972-07-18 | Dow Chemical Co | Preparation of linear alpha olefin polymers having broad molecular weight distributions |
| US4058653A (en) | 1972-09-14 | 1977-11-15 | Ethylene Plastique | Process for the preparation of polymers of but-1-ene |
| US4063009A (en) | 1954-01-19 | 1977-12-13 | Studiengesellschaft Kohle M.B.H. | Polymerization of ethylenically unsaturated hydrocarbons |
| US4304890A (en) | 1976-04-19 | 1981-12-08 | Chisso Corporation | Method for producing propylene copolymers using a catalyst activated prior to copolymerization |
| US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
| US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
| US5155079A (en) * | 1991-06-07 | 1992-10-13 | Quantum Chemical Corporation | Multiple site olefin polymerization catalysts |
| US5204304A (en) * | 1991-06-04 | 1993-04-20 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
| US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
| US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE551905A (enrdf_load_stackoverflow) * | 1955-10-19 | |||
| US3021320A (en) * | 1956-01-30 | 1962-02-13 | Celanese Corp | Polymerization of ethylene with catalysts of alkali metal borohydrides, aluminum halides and group ivb metal halides |
| BE555591A (enrdf_load_stackoverflow) * | 1956-03-08 | |||
| NL113758C (enrdf_load_stackoverflow) * | 1956-04-16 | |||
| DE1180135B (de) * | 1956-04-18 | 1964-10-22 | Du Pont | Verfahren zur katalytischen Polymerisation von Alkenen |
| LU35350A1 (enrdf_load_stackoverflow) * | 1956-08-06 | |||
| BE559674A (enrdf_load_stackoverflow) * | 1956-08-08 | |||
| NL218674A (enrdf_load_stackoverflow) * | 1956-09-17 | |||
| DE1166478B (de) * | 1956-11-01 | 1964-03-26 | Hoechst Ag | Verfahren zur Reinigung von Polymerisaten von olefinisch ungesaettigten Kohlenwasserstoffen |
| US3107236A (en) * | 1956-12-17 | 1963-10-15 | Sun Oil Co | Preparation of polypropylene |
| US3210334A (en) * | 1957-03-25 | 1965-10-05 | Union Carbide Corp | Catalytic polymerization of ethylene |
| NL120959C (enrdf_load_stackoverflow) * | 1957-04-27 | |||
| BE574129A (enrdf_load_stackoverflow) * | 1957-12-23 | |||
| US3008942A (en) * | 1958-01-16 | 1961-11-14 | American Cyanamid Co | Polymerization system for vinyl aromatic monomers |
| US2996494A (en) * | 1958-11-06 | 1961-08-15 | Eastman Kodak Co | Olefin polymerization catalysts containing alkali metal tetraphenylborate, aluminum chloride and transition element compounds |
| DE1115453B (de) * | 1958-12-05 | 1961-10-19 | Basf Ag | Verfahren zur Herstellung von isotaktischem Polypropylen |
| DE1139646B (de) * | 1958-12-19 | 1962-11-15 | Goodrich Gulf Chem Inc | Verfahren zur Polymerisation von Butadien-(1, 3)-Kohlenwasserstoffen |
| DE1105618B (de) * | 1959-01-26 | 1961-04-27 | Huels Chemische Werke Ag | Verfahren zur Herstellung von isotaktischen Polystyrolen |
| DE1273818B (de) * | 1959-02-24 | 1968-07-25 | Hibernia Ag | Verfahren zur Herstellung von Olefinpolymerisaten |
| DE1301901B (de) * | 1959-03-02 | 1969-08-28 | Gulf Oil Corp | Verfahren zur Polymerisation von alpha-Olefinen mit mindestens drei Kohlenstoffatomen |
| US3000867A (en) * | 1959-04-15 | 1961-09-19 | Du Pont | Novel ethylene-propylene copolymer and method for producing same |
| BE591405A (enrdf_load_stackoverflow) * | 1959-06-12 | |||
| DE1183245B (de) * | 1959-06-24 | 1964-12-10 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Polyolefinen einheitlichen Polymerisationsgrades |
| IT989188B (it) * | 1973-06-15 | 1975-05-20 | Snam Progetti | Processo per la polimerizzazione dell etilene |
-
0
- NL NL229912D patent/NL229912A/xx unknown
- NL NL203032D patent/NL203032A/xx unknown
- NL NL107439D patent/NL107439C/xx active
- BE BE543941D patent/BE543941A/xx unknown
-
1954
- 1954-12-24 GB GB3736154A patent/GB785314A/en not_active Expired
-
1955
- 1955-12-23 FR FR1142456D patent/FR1142456A/fr not_active Expired
Cited By (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4063009A (en) | 1954-01-19 | 1977-12-13 | Studiengesellschaft Kohle M.B.H. | Polymerization of ethylenically unsaturated hydrocarbons |
| US2962490A (en) * | 1955-08-22 | 1960-11-29 | Phillips Petroleum Co | Process and catalyst for production of olefin polymers |
| US2930783A (en) * | 1955-11-04 | 1960-03-29 | Huels Chemische Werke Ag | Method of purifying low-pressure polyolefines |
| US3078264A (en) * | 1956-01-30 | 1963-02-19 | Celanese Corp | Polymerization of ethylene and catalyst therefor |
| US2965626A (en) * | 1956-03-28 | 1960-12-20 | Standard Oil Co | Ethylene polymerization process |
| US3042626A (en) * | 1956-05-21 | 1962-07-03 | Du Pont | Polymerization catalyst and process |
| US2935498A (en) * | 1957-07-01 | 1960-05-03 | Eastman Kodak Co | Polymerization of alpha-olefins to solid polymers with a three-component catalyst |
| US3047557A (en) * | 1957-10-19 | 1962-07-31 | Hoechst Ag | Process for polymerizing olefins with catalysts of ticl dialkyl aluminum fluorides in combination with another dialkyl aluminum halide |
| US3012024A (en) * | 1957-11-25 | 1961-12-05 | Celanese Corp | Dry feed in forming slurry in olefin polymerization |
| US3370052A (en) * | 1957-12-11 | 1968-02-20 | Montedison Spa | Process for the production of high molecular weight amorphous copolymerizates of ethylene and a higher alpha-olefin in increased yields |
| US3208985A (en) * | 1957-12-11 | 1965-09-28 | Wacker Chemie Gmbh | Olefin polymerization with a heavy metal compound-organohydrogen siloxane catalyst |
| US2945018A (en) * | 1958-01-21 | 1960-07-12 | Shell Oil Co | Olefin polymerization |
| US2965625A (en) * | 1958-01-27 | 1960-12-20 | Shell Oil Co | Process of polymerizing a conjugated diene |
| US3032509A (en) * | 1958-02-03 | 1962-05-01 | Exxon Research Engineering Co | Partially-reduced cocrystallized transition metal halide polymerization catalyst |
| US2996459A (en) * | 1958-02-03 | 1961-08-15 | Monsanto Chemicals | Method for preparing a ziegler polymerization catalyst |
| US3502637A (en) * | 1958-02-11 | 1970-03-24 | Montedison Spa | Homogeneous stereospecific catalysts and polymerization of butadiene therewith |
| US3076796A (en) * | 1958-04-11 | 1963-02-05 | Union Carbide Corp | Ethylene polymerization catalysts |
| US3159607A (en) * | 1958-05-20 | 1964-12-01 | Dal Mon Research Co | Polymerization process |
| US3073809A (en) * | 1958-07-31 | 1963-01-15 | Union Carbide Corp | Process for producing ethylene-1-olefin copolymers |
| US2935542A (en) * | 1958-09-09 | 1960-05-03 | Exxon Research Engineering Co | Propylene polymers oils |
| US3131171A (en) * | 1958-11-14 | 1964-04-28 | Monsanto Chemicals | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride |
| US2976260A (en) * | 1958-11-28 | 1961-03-21 | Eastman Kodak Co | Poly-alpha-olefins containing certain 4-alkoxy-2-hydroxybenzophenones and alkylene-bis-phenols |
| US3156736A (en) * | 1959-01-08 | 1964-11-10 | Shell Oil Co | Process for preparation of synthetic lubricants |
| US3143537A (en) * | 1959-03-05 | 1964-08-04 | Eastman Kodak Co | Olefin polymerization using an aluminum alkyl-transition element compound-alkali metal fluoride catalyst composition |
| US3063979A (en) * | 1959-03-11 | 1962-11-13 | Du Pont | Polymerization catalysts |
| US2993883A (en) * | 1959-03-25 | 1961-07-25 | Phillips Petroleum Co | Production of polymers of ethylene with a catalyst of a chromyl halide, an aluminum halide, and a hydrocarbon metal halide |
| US3165503A (en) * | 1959-04-07 | 1965-01-12 | Goodrich Gulf Chem Inc | Method of polymerizing butadiene-1, 3-hydrocarbons |
| US3040014A (en) * | 1959-05-27 | 1962-06-19 | Exxon Research Engineering Co | Melt index and brittleness of polypropylene |
| US3066127A (en) * | 1959-09-30 | 1962-11-27 | Shell Oil Co | Polymerization process |
| US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
| US3134822A (en) * | 1959-12-01 | 1964-05-26 | Gulf Research Development Co | Benzene alkylation with a catalyst consisting essentially of either sbcl or sncl and an alkyl aluminum sesquichloride |
| US3051692A (en) * | 1960-06-06 | 1962-08-28 | Phillips Petroleum Co | Production of solid olefin polymers |
| US3164577A (en) * | 1960-10-12 | 1965-01-05 | Grace W R & Co | Propylene polymerization catalyst |
| US3108145A (en) * | 1960-11-29 | 1963-10-22 | Sun Oil Co | Preparation of olefin polymers |
| US3225022A (en) * | 1960-12-27 | 1965-12-21 | Monsanto Co | Catalyst compositions comprising aluminum chloride |
| US3162620A (en) * | 1961-05-04 | 1964-12-22 | Du Pont | Ethylene polymers prepared in the form of a coherent film at a quiescent liquid catalyst surface |
| US3328378A (en) * | 1961-05-17 | 1967-06-27 | Wacker Chemie Gmbh | Method for polymerizing unsaturated organic compounds |
| US3103501A (en) * | 1961-08-03 | 1963-09-10 | - olefins containing alkylidene- | |
| US3453250A (en) * | 1961-10-18 | 1969-07-01 | Montedison Spa | Cyclic polyene/mono-olefin copolymerizates and processes for producing them |
| US3179649A (en) * | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
| US3313792A (en) * | 1962-03-16 | 1967-04-11 | Shell Oil Co | Process for polymerizing conjugated dienes with a catalyst comprising an aluminum halide, a salt of cobalt or nickel, and a compound of the formula sihxy (4-x) |
| US3342793A (en) * | 1962-05-07 | 1967-09-19 | Snia Viscosa | Polymerization of alpha-olefins in the presence of ticl3.1/3alcl3, alkali metal and an alkyl phosphoramide or sulfuric amide |
| US3378606A (en) * | 1962-09-10 | 1968-04-16 | Uniroyal Inc | Semicrystalline stereoblock copolymers |
| US3418304A (en) * | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
| US3511821A (en) * | 1963-10-23 | 1970-05-12 | Exxon Research Engineering Co | Terpolymers of isobutylene-methylcyclopentadiene and a crosslinking agent |
| US3450682A (en) * | 1963-11-14 | 1969-06-17 | Mitsui Petrochemical Ind | Process for preparation of crystalline high polymers of olefins |
| US3678025A (en) * | 1970-05-22 | 1972-07-18 | Dow Chemical Co | Preparation of linear alpha olefin polymers having broad molecular weight distributions |
| US4058653A (en) | 1972-09-14 | 1977-11-15 | Ethylene Plastique | Process for the preparation of polymers of but-1-ene |
| US4304890A (en) | 1976-04-19 | 1981-12-08 | Chisso Corporation | Method for producing propylene copolymers using a catalyst activated prior to copolymerization |
| US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
| US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
| US5204304A (en) * | 1991-06-04 | 1993-04-20 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
| US5155079A (en) * | 1991-06-07 | 1992-10-13 | Quantum Chemical Corporation | Multiple site olefin polymerization catalysts |
| US5369194A (en) * | 1991-06-07 | 1994-11-29 | Quantum Chemical Corporation | Olefin polymerization method |
| US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
| US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| NL229912A (enrdf_load_stackoverflow) | |
| FR1142456A (fr) | 1957-09-18 |
| NL107439C (enrdf_load_stackoverflow) | |
| NL203032A (enrdf_load_stackoverflow) | |
| BE543941A (enrdf_load_stackoverflow) |
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