GB785314A - Improvements in and relating to the polymerisation of olefines - Google Patents
Improvements in and relating to the polymerisation of olefinesInfo
- Publication number
- GB785314A GB785314A GB3736154A GB3736154A GB785314A GB 785314 A GB785314 A GB 785314A GB 3736154 A GB3736154 A GB 3736154A GB 3736154 A GB3736154 A GB 3736154A GB 785314 A GB785314 A GB 785314A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aluminium
- group
- organo
- metal
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
Catalysts for the polymerization of olefines (see Group IV (a)) are obtained by reaction of a Group 4A, 5A or 6A metal compound with an organo-compound of a non-transition metal of Groups 1, 2 or 3, said organo-compound containing at least one hydrocarbon radical attached to the metal and any remaining valencies being satisfied by hydrogen or halogen. The Group 4A, 5A or 6A metal compound may be a halide, oxyhalide, complex halide, alcoholate, acetate, benzoate or acetylacetonate, e.g. the chlorides of titanium, vanadium, molybdenum, tungsten, tantalum, niobium and zirconium. Organo compounds of Groups 1 to 3 disclosed are aluminium trimethyl, triethyl, tripropyl, tributyl and triphenyl; alkyl and aryl aluminium halides, e.g. phenyl aluminium sesquiiodide; complex alkyls of an alkali metal and aluminium, gallium, indium or thallium, e.g. lithium aluminium tetraethyl and sodium aluminium tetrapropyl; alkali metal alkyls and aryls, e.g. lithium butyl, sodium phenyl and amyl, and zinc dibutyl and diethyl; alkyl hydrides such as aluminium ethyl dihydride and aluminium diethyl hydride; complex compounds such as sodium aluminium tetraphenyl or triethyl hydride, lithium aluminium propyl trihydride and potassium aluminium trimethyl fluoride; and molecular complexes thereof with ethers, thio ethers and amines. Optionally promoters such as ethyl aluminium sesquichloride and aluminium chloride may be included. In examples methanol, ethanol, acetone, ether, water, pentane, bromine water, caustic soda and hydrochloric acid are materials used for destroying the catalyst and purifying the product. Specifications 757,524 and 762,200, [both in Group IV (b)], are referred to.ALSO:Ethylene and a -olefines are polymerized in a medium comprising the reaction product of a Group 4A, 5A or 6A metal compound with an organo-compound of a non-transition metal of Groups 1, 2 or 3, said organo-compound containing at least one hydrocarbon radical attached to the metal and any remaining valencies being satisfied by hydrogen or halogen. Olefines specified are propylene, butene-1, isobutylene and styrene and may be pure or diluted with hydrogen or hydrocarbons, e.g. butene-2. The Group 4A, 5A or 6A metal compound may be a halide, oxyhalide, complex halide, alcoholate, acetate, benzoate or acetylacetonate, e.g. the chlorides of titanium, vanadium, molybdenum, tungsten, tantalum, niobium and zirconium. Organo compounds of Groups 1 to 3 disclosed are aluminium triethyl, trimethyl, tripropyl, tributyl and triphenyl; alkyl and aryl aluminium halides, e.g. phenyl aluminium sesquiiodide; complex alkyls of an alkali metal and aluminium, gallium, indium or thallium, e.g. lithium aluminium tetraethyl and sodium aluminium tetrapropyl; alkali metal alkyls and aryls, e.g. lithium butyl, sodium phenyl and amyl, and zinc dibutyl and diethyl; alkyl hydrides such as aluminium ethyl dihydride and aluminium diethyl hydride; complex compounds such as sodium aluminium tetraphenyl or triethyl hydride, lithium aluminium propyl tri-hydride and potassium aluminium trimethyl fluoride; and molecular complexes thereof with ethers, thio-ethers or amines. Optionally promoters, such as ethyl aluminium sesquichloride and aluminium chloride, may be included. The olefin may be polymerized in the vapour or liquid phase or may be passed into contact with the surface of an inert solvent such as butane, pentane, hexane, petroleum ether, cyclohexane, methyl cyclohexane or decahydronaphthalene. The polymerization is preferably carried out in the absence of water and oxygen and, optionally, in the presence of an anti-oxidant such as bis-(2-hydroxy - 3 - alpha - methylcyclohexyl - 5 - methyl-phenyl) methane. Preferred molar ratios of catalyst components are specified. Further catalyst components may be added during the reaction and in examples ethylene or styrene and/or solvent are added continuously. In examples methanol, ethanol, acetone, ether, water, pentane, bromine water, caustic soda and hydrochloric acid may be used for stopping the reaction and purifying the polymers. In Example 11 the polymerization is carried out at - 70 DEG C. The products may be highly crystalline and are useful in the manufacture of filaments, foils, sheets, tubes and chemical intermediates. Crystalline and oily polymers may be separated by fractionation with solvents. Specifications 757,524 and 762,200, [both in Group IV (b)], are referred to.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL107439D NL107439C (en) | 1954-12-24 | ||
NL203032D NL203032A (en) | 1954-12-24 | ||
BE543941D BE543941A (en) | 1954-12-24 | ||
NL229912D NL229912A (en) | 1954-12-24 | ||
GB3736154A GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
FR1142456D FR1142456A (en) | 1954-12-24 | 1955-12-23 | Polymerization of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3736154A GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB785314A true GB785314A (en) | 1957-10-23 |
Family
ID=10395877
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3736154A Expired GB785314A (en) | 1954-12-24 | 1954-12-24 | Improvements in and relating to the polymerisation of olefines |
Country Status (4)
Country | Link |
---|---|
BE (1) | BE543941A (en) |
FR (1) | FR1142456A (en) |
GB (1) | GB785314A (en) |
NL (3) | NL229912A (en) |
Cited By (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2930783A (en) * | 1955-11-04 | 1960-03-29 | Huels Chemische Werke Ag | Method of purifying low-pressure polyolefines |
US2935542A (en) * | 1958-09-09 | 1960-05-03 | Exxon Research Engineering Co | Propylene polymers oils |
US2935498A (en) * | 1957-07-01 | 1960-05-03 | Eastman Kodak Co | Polymerization of alpha-olefins to solid polymers with a three-component catalyst |
US2945018A (en) * | 1958-01-21 | 1960-07-12 | Shell Oil Co | Olefin polymerization |
US2962490A (en) * | 1955-08-22 | 1960-11-29 | Phillips Petroleum Co | Process and catalyst for production of olefin polymers |
US2965626A (en) * | 1956-03-28 | 1960-12-20 | Standard Oil Co | Ethylene polymerization process |
US2965625A (en) * | 1958-01-27 | 1960-12-20 | Shell Oil Co | Process of polymerizing a conjugated diene |
US2976260A (en) * | 1958-11-28 | 1961-03-21 | Eastman Kodak Co | Poly-alpha-olefins containing certain 4-alkoxy-2-hydroxybenzophenones and alkylene-bis-phenols |
US2993883A (en) * | 1959-03-25 | 1961-07-25 | Phillips Petroleum Co | Production of polymers of ethylene with a catalyst of a chromyl halide, an aluminum halide, and a hydrocarbon metal halide |
US2996459A (en) * | 1958-02-03 | 1961-08-15 | Monsanto Chemicals | Method for preparing a ziegler polymerization catalyst |
US3012024A (en) * | 1957-11-25 | 1961-12-05 | Celanese Corp | Dry feed in forming slurry in olefin polymerization |
US3032509A (en) * | 1958-02-03 | 1962-05-01 | Exxon Research Engineering Co | Partially-reduced cocrystallized transition metal halide polymerization catalyst |
US3040014A (en) * | 1959-05-27 | 1962-06-19 | Exxon Research Engineering Co | Melt index and brittleness of polypropylene |
US3042626A (en) * | 1956-05-21 | 1962-07-03 | Du Pont | Polymerization catalyst and process |
US3047557A (en) * | 1957-10-19 | 1962-07-31 | Hoechst Ag | Process for polymerizing olefins with catalysts of ticl dialkyl aluminum fluorides in combination with another dialkyl aluminum halide |
US3051692A (en) * | 1960-06-06 | 1962-08-28 | Phillips Petroleum Co | Production of solid olefin polymers |
US3063979A (en) * | 1959-03-11 | 1962-11-13 | Du Pont | Polymerization catalysts |
US3066127A (en) * | 1959-09-30 | 1962-11-27 | Shell Oil Co | Polymerization process |
US3073809A (en) * | 1958-07-31 | 1963-01-15 | Union Carbide Corp | Process for producing ethylene-1-olefin copolymers |
US3076796A (en) * | 1958-04-11 | 1963-02-05 | Union Carbide Corp | Ethylene polymerization catalysts |
US3078264A (en) * | 1956-01-30 | 1963-02-19 | Celanese Corp | Polymerization of ethylene and catalyst therefor |
US3103501A (en) * | 1961-08-03 | 1963-09-10 | - olefins containing alkylidene- | |
US3108145A (en) * | 1960-11-29 | 1963-10-22 | Sun Oil Co | Preparation of olefin polymers |
US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
US3131171A (en) * | 1958-11-14 | 1964-04-28 | Monsanto Chemicals | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride |
US3134822A (en) * | 1959-12-01 | 1964-05-26 | Gulf Research Development Co | Benzene alkylation with a catalyst consisting essentially of either sbcl or sncl and an alkyl aluminum sesquichloride |
US3143537A (en) * | 1959-03-05 | 1964-08-04 | Eastman Kodak Co | Olefin polymerization using an aluminum alkyl-transition element compound-alkali metal fluoride catalyst composition |
US3156736A (en) * | 1959-01-08 | 1964-11-10 | Shell Oil Co | Process for preparation of synthetic lubricants |
US3159607A (en) * | 1958-05-20 | 1964-12-01 | Dal Mon Research Co | Polymerization process |
US3162620A (en) * | 1961-05-04 | 1964-12-22 | Du Pont | Ethylene polymers prepared in the form of a coherent film at a quiescent liquid catalyst surface |
US3164577A (en) * | 1960-10-12 | 1965-01-05 | Grace W R & Co | Propylene polymerization catalyst |
US3165503A (en) * | 1959-04-07 | 1965-01-12 | Goodrich Gulf Chem Inc | Method of polymerizing butadiene-1, 3-hydrocarbons |
US3179649A (en) * | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
US3208985A (en) * | 1957-12-11 | 1965-09-28 | Wacker Chemie Gmbh | Olefin polymerization with a heavy metal compound-organohydrogen siloxane catalyst |
US3225022A (en) * | 1960-12-27 | 1965-12-21 | Monsanto Co | Catalyst compositions comprising aluminum chloride |
US3313792A (en) * | 1962-03-16 | 1967-04-11 | Shell Oil Co | Process for polymerizing conjugated dienes with a catalyst comprising an aluminum halide, a salt of cobalt or nickel, and a compound of the formula sihxy (4-x) |
US3328378A (en) * | 1961-05-17 | 1967-06-27 | Wacker Chemie Gmbh | Method for polymerizing unsaturated organic compounds |
US3342793A (en) * | 1962-05-07 | 1967-09-19 | Snia Viscosa | Polymerization of alpha-olefins in the presence of ticl3.1/3alcl3, alkali metal and an alkyl phosphoramide or sulfuric amide |
US3370052A (en) * | 1957-12-11 | 1968-02-20 | Montedison Spa | Process for the production of high molecular weight amorphous copolymerizates of ethylene and a higher alpha-olefin in increased yields |
US3378606A (en) * | 1962-09-10 | 1968-04-16 | Uniroyal Inc | Semicrystalline stereoblock copolymers |
US3418304A (en) * | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
US3450682A (en) * | 1963-11-14 | 1969-06-17 | Mitsui Petrochemical Ind | Process for preparation of crystalline high polymers of olefins |
US3453250A (en) * | 1961-10-18 | 1969-07-01 | Montedison Spa | Cyclic polyene/mono-olefin copolymerizates and processes for producing them |
US3502637A (en) * | 1958-02-11 | 1970-03-24 | Montedison Spa | Homogeneous stereospecific catalysts and polymerization of butadiene therewith |
US3511821A (en) * | 1963-10-23 | 1970-05-12 | Exxon Research Engineering Co | Terpolymers of isobutylene-methylcyclopentadiene and a crosslinking agent |
US3678025A (en) * | 1970-05-22 | 1972-07-18 | Dow Chemical Co | Preparation of linear alpha olefin polymers having broad molecular weight distributions |
US4304890A (en) | 1976-04-19 | 1981-12-08 | Chisso Corporation | Method for producing propylene copolymers using a catalyst activated prior to copolymerization |
US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
US5155079A (en) * | 1991-06-07 | 1992-10-13 | Quantum Chemical Corporation | Multiple site olefin polymerization catalysts |
US5204304A (en) * | 1991-06-04 | 1993-04-20 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL129662C (en) * | 1955-10-19 | |||
US3021320A (en) * | 1956-01-30 | 1962-02-13 | Celanese Corp | Polymerization of ethylene with catalysts of alkali metal borohydrides, aluminum halides and group ivb metal halides |
NL215123A (en) * | 1956-03-08 | |||
NL216345A (en) * | 1956-04-16 | |||
DE1180135B (en) * | 1956-04-18 | 1964-10-22 | Du Pont | Process for the catalytic polymerization of alkenes |
BE559842A (en) * | 1956-08-06 | |||
BE559674A (en) * | 1956-08-08 | |||
NL106201C (en) * | 1956-09-17 | |||
DE1166478B (en) * | 1956-11-01 | 1964-03-26 | Hoechst Ag | Process for the purification of polymers from olefinically unsaturated hydrocarbons |
US3107236A (en) * | 1956-12-17 | 1963-10-15 | Sun Oil Co | Preparation of polypropylene |
US3210334A (en) * | 1957-03-25 | 1965-10-05 | Union Carbide Corp | Catalytic polymerization of ethylene |
NL120959C (en) * | 1957-04-27 | |||
BE574129A (en) * | 1957-12-23 | |||
US3008942A (en) * | 1958-01-16 | 1961-11-14 | American Cyanamid Co | Polymerization system for vinyl aromatic monomers |
US2996494A (en) * | 1958-11-06 | 1961-08-15 | Eastman Kodak Co | Olefin polymerization catalysts containing alkali metal tetraphenylborate, aluminum chloride and transition element compounds |
DE1115453B (en) * | 1958-12-05 | 1961-10-19 | Basf Ag | Process for the production of isotactic polypropylene |
DE1139646B (en) * | 1958-12-19 | 1962-11-15 | Goodrich Gulf Chem Inc | Process for the polymerization of butadiene (1,3) hydrocarbons |
DE1105618B (en) * | 1959-01-26 | 1961-04-27 | Huels Chemische Werke Ag | Process for the production of isotactic polystyrenes |
DE1273818B (en) * | 1959-02-24 | 1968-07-25 | Hibernia Ag | Process for the production of olefin polymers |
DE1301901B (en) * | 1959-03-02 | 1969-08-28 | Gulf Oil Corp | Process for the polymerization of alpha-olefins having at least three carbon atoms |
US3000867A (en) * | 1959-04-15 | 1961-09-19 | Du Pont | Novel ethylene-propylene copolymer and method for producing same |
BE591405A (en) * | 1959-06-12 | |||
DE1183245B (en) * | 1959-06-24 | 1964-12-10 | Huels Chemische Werke Ag | Process for the production of polyolefins with a uniform degree of polymerization |
IT989188B (en) * | 1973-06-15 | 1975-05-20 | Snam Progetti | PROCESS FOR THE POLYMERIZATION OF ETHYLENE |
-
0
- NL NL203032D patent/NL203032A/xx unknown
- BE BE543941D patent/BE543941A/xx unknown
- NL NL107439D patent/NL107439C/xx active
- NL NL229912D patent/NL229912A/xx unknown
-
1954
- 1954-12-24 GB GB3736154A patent/GB785314A/en not_active Expired
-
1955
- 1955-12-23 FR FR1142456D patent/FR1142456A/en not_active Expired
Cited By (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2962490A (en) * | 1955-08-22 | 1960-11-29 | Phillips Petroleum Co | Process and catalyst for production of olefin polymers |
US2930783A (en) * | 1955-11-04 | 1960-03-29 | Huels Chemische Werke Ag | Method of purifying low-pressure polyolefines |
US3078264A (en) * | 1956-01-30 | 1963-02-19 | Celanese Corp | Polymerization of ethylene and catalyst therefor |
US2965626A (en) * | 1956-03-28 | 1960-12-20 | Standard Oil Co | Ethylene polymerization process |
US3042626A (en) * | 1956-05-21 | 1962-07-03 | Du Pont | Polymerization catalyst and process |
US2935498A (en) * | 1957-07-01 | 1960-05-03 | Eastman Kodak Co | Polymerization of alpha-olefins to solid polymers with a three-component catalyst |
US3047557A (en) * | 1957-10-19 | 1962-07-31 | Hoechst Ag | Process for polymerizing olefins with catalysts of ticl dialkyl aluminum fluorides in combination with another dialkyl aluminum halide |
US3012024A (en) * | 1957-11-25 | 1961-12-05 | Celanese Corp | Dry feed in forming slurry in olefin polymerization |
US3370052A (en) * | 1957-12-11 | 1968-02-20 | Montedison Spa | Process for the production of high molecular weight amorphous copolymerizates of ethylene and a higher alpha-olefin in increased yields |
US3208985A (en) * | 1957-12-11 | 1965-09-28 | Wacker Chemie Gmbh | Olefin polymerization with a heavy metal compound-organohydrogen siloxane catalyst |
US2945018A (en) * | 1958-01-21 | 1960-07-12 | Shell Oil Co | Olefin polymerization |
US2965625A (en) * | 1958-01-27 | 1960-12-20 | Shell Oil Co | Process of polymerizing a conjugated diene |
US3032509A (en) * | 1958-02-03 | 1962-05-01 | Exxon Research Engineering Co | Partially-reduced cocrystallized transition metal halide polymerization catalyst |
US2996459A (en) * | 1958-02-03 | 1961-08-15 | Monsanto Chemicals | Method for preparing a ziegler polymerization catalyst |
US3502637A (en) * | 1958-02-11 | 1970-03-24 | Montedison Spa | Homogeneous stereospecific catalysts and polymerization of butadiene therewith |
US3076796A (en) * | 1958-04-11 | 1963-02-05 | Union Carbide Corp | Ethylene polymerization catalysts |
US3159607A (en) * | 1958-05-20 | 1964-12-01 | Dal Mon Research Co | Polymerization process |
US3073809A (en) * | 1958-07-31 | 1963-01-15 | Union Carbide Corp | Process for producing ethylene-1-olefin copolymers |
US2935542A (en) * | 1958-09-09 | 1960-05-03 | Exxon Research Engineering Co | Propylene polymers oils |
US3131171A (en) * | 1958-11-14 | 1964-04-28 | Monsanto Chemicals | Catalyst for the polymerization of olefins containing the product of a titanium halide and an organoaluminum compound mixed with a lower alkyl halide solution of aluminum chloride |
US2976260A (en) * | 1958-11-28 | 1961-03-21 | Eastman Kodak Co | Poly-alpha-olefins containing certain 4-alkoxy-2-hydroxybenzophenones and alkylene-bis-phenols |
US3156736A (en) * | 1959-01-08 | 1964-11-10 | Shell Oil Co | Process for preparation of synthetic lubricants |
US3143537A (en) * | 1959-03-05 | 1964-08-04 | Eastman Kodak Co | Olefin polymerization using an aluminum alkyl-transition element compound-alkali metal fluoride catalyst composition |
US3063979A (en) * | 1959-03-11 | 1962-11-13 | Du Pont | Polymerization catalysts |
US2993883A (en) * | 1959-03-25 | 1961-07-25 | Phillips Petroleum Co | Production of polymers of ethylene with a catalyst of a chromyl halide, an aluminum halide, and a hydrocarbon metal halide |
US3165503A (en) * | 1959-04-07 | 1965-01-12 | Goodrich Gulf Chem Inc | Method of polymerizing butadiene-1, 3-hydrocarbons |
US3040014A (en) * | 1959-05-27 | 1962-06-19 | Exxon Research Engineering Co | Melt index and brittleness of polypropylene |
US3066127A (en) * | 1959-09-30 | 1962-11-27 | Shell Oil Co | Polymerization process |
US3129255A (en) * | 1959-12-01 | 1964-04-14 | Gulf Research Development Co | Alkylation of benzene with propylene in the presence of ticl4 and alkyl aluminum sesquichloride |
US3134822A (en) * | 1959-12-01 | 1964-05-26 | Gulf Research Development Co | Benzene alkylation with a catalyst consisting essentially of either sbcl or sncl and an alkyl aluminum sesquichloride |
US3051692A (en) * | 1960-06-06 | 1962-08-28 | Phillips Petroleum Co | Production of solid olefin polymers |
US3164577A (en) * | 1960-10-12 | 1965-01-05 | Grace W R & Co | Propylene polymerization catalyst |
US3108145A (en) * | 1960-11-29 | 1963-10-22 | Sun Oil Co | Preparation of olefin polymers |
US3225022A (en) * | 1960-12-27 | 1965-12-21 | Monsanto Co | Catalyst compositions comprising aluminum chloride |
US3162620A (en) * | 1961-05-04 | 1964-12-22 | Du Pont | Ethylene polymers prepared in the form of a coherent film at a quiescent liquid catalyst surface |
US3328378A (en) * | 1961-05-17 | 1967-06-27 | Wacker Chemie Gmbh | Method for polymerizing unsaturated organic compounds |
US3103501A (en) * | 1961-08-03 | 1963-09-10 | - olefins containing alkylidene- | |
US3453250A (en) * | 1961-10-18 | 1969-07-01 | Montedison Spa | Cyclic polyene/mono-olefin copolymerizates and processes for producing them |
US3179649A (en) * | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
US3313792A (en) * | 1962-03-16 | 1967-04-11 | Shell Oil Co | Process for polymerizing conjugated dienes with a catalyst comprising an aluminum halide, a salt of cobalt or nickel, and a compound of the formula sihxy (4-x) |
US3342793A (en) * | 1962-05-07 | 1967-09-19 | Snia Viscosa | Polymerization of alpha-olefins in the presence of ticl3.1/3alcl3, alkali metal and an alkyl phosphoramide or sulfuric amide |
US3378606A (en) * | 1962-09-10 | 1968-04-16 | Uniroyal Inc | Semicrystalline stereoblock copolymers |
US3418304A (en) * | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
US3511821A (en) * | 1963-10-23 | 1970-05-12 | Exxon Research Engineering Co | Terpolymers of isobutylene-methylcyclopentadiene and a crosslinking agent |
US3450682A (en) * | 1963-11-14 | 1969-06-17 | Mitsui Petrochemical Ind | Process for preparation of crystalline high polymers of olefins |
US3678025A (en) * | 1970-05-22 | 1972-07-18 | Dow Chemical Co | Preparation of linear alpha olefin polymers having broad molecular weight distributions |
US4304890A (en) | 1976-04-19 | 1981-12-08 | Chisso Corporation | Method for producing propylene copolymers using a catalyst activated prior to copolymerization |
US5116795A (en) * | 1985-08-02 | 1992-05-26 | Quantum Chemical Corporation | Alpha olefin oligomerization catalyst |
US5122581A (en) * | 1985-08-02 | 1992-06-16 | Quantum Chemical Corporation | Polymerization method |
US5204304A (en) * | 1991-06-04 | 1993-04-20 | Quantum Chemical Corporation | Vanadium-containing polymerization catalyst |
US5155079A (en) * | 1991-06-07 | 1992-10-13 | Quantum Chemical Corporation | Multiple site olefin polymerization catalysts |
US5369194A (en) * | 1991-06-07 | 1994-11-29 | Quantum Chemical Corporation | Olefin polymerization method |
US5399540A (en) * | 1993-02-12 | 1995-03-21 | Quantum Chemical Corporation | ZR/V multi-site olefin polymerization catalyst |
US5405817A (en) * | 1993-02-12 | 1995-04-11 | Quantum Chemical Corporation | V/TI multi-site olefin polymerization catalyst |
Also Published As
Publication number | Publication date |
---|---|
BE543941A (en) | |
NL229912A (en) | |
NL107439C (en) | |
NL203032A (en) | |
FR1142456A (en) | 1957-09-18 |
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