GB752940A - Method of chemically cleaning the surface of articles of zirconium or hafnium or alloys thereof and of applying adherent electrophates to zirconium or hafnium surfaces or to the surfaces of alloys of these metals - Google Patents

Method of chemically cleaning the surface of articles of zirconium or hafnium or alloys thereof and of applying adherent electrophates to zirconium or hafnium surfaces or to the surfaces of alloys of these metals

Info

Publication number
GB752940A
GB752940A GB13582/54A GB1358254A GB752940A GB 752940 A GB752940 A GB 752940A GB 13582/54 A GB13582/54 A GB 13582/54A GB 1358254 A GB1358254 A GB 1358254A GB 752940 A GB752940 A GB 752940A
Authority
GB
United Kingdom
Prior art keywords
alloys
hafnium
zirconium
articles
electrophates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13582/54A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Atomic Energy Commission (AEC)
Original Assignee
US Atomic Energy Commission (AEC)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by US Atomic Energy Commission (AEC) filed Critical US Atomic Energy Commission (AEC)
Publication of GB752940A publication Critical patent/GB752940A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10Other heavy metals
    • C23G1/106Other heavy metals refractory metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

In a method of cleaning the surface of articles of Zr or Hf, or alloys of Zr or Hf, the article is first physically cleaned, e.g. by sand-blasting, and then immersed in an aqueous solution containing NH4F and HF in a molar ratio of 1,2-3 for 10-240 seconds at a temperature of 70 DEG -120 DEG F. The solution may contain 0,25-1 per cent. of an aliphatic amine of formula CnH2n + 1 NH2. Where 12\sEn\sE18, when the said molar ratio may be 1-3 and the quantities of NH4F and HF are preferably 0,44-1,32 and 0,44-0,88 moles/litre respectively. A surface prepared in this way is stated to be particularly suitable for receiving an electroplated metallic coating.
GB13582/54A 1953-05-15 1954-05-10 Method of chemically cleaning the surface of articles of zirconium or hafnium or alloys thereof and of applying adherent electrophates to zirconium or hafnium surfaces or to the surfaces of alloys of these metals Expired GB752940A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US752940XA 1953-05-15 1953-05-15

Publications (1)

Publication Number Publication Date
GB752940A true GB752940A (en) 1956-07-18

Family

ID=22124763

Family Applications (1)

Application Number Title Priority Date Filing Date
GB13582/54A Expired GB752940A (en) 1953-05-15 1954-05-10 Method of chemically cleaning the surface of articles of zirconium or hafnium or alloys thereof and of applying adherent electrophates to zirconium or hafnium surfaces or to the surfaces of alloys of these metals

Country Status (1)

Country Link
GB (1) GB752940A (en)

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