GB738289A - Improvements in or relating to the production of organic halogen compounds - Google Patents
Improvements in or relating to the production of organic halogen compoundsInfo
- Publication number
- GB738289A GB738289A GB2456852A GB2456852A GB738289A GB 738289 A GB738289 A GB 738289A GB 2456852 A GB2456852 A GB 2456852A GB 2456852 A GB2456852 A GB 2456852A GB 738289 A GB738289 A GB 738289A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chlorine
- monofluoride
- reaction
- halogenated
- octachloronaphthalene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/204—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being a halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the manufacture of organic fluorine compounds comprises reacting chlorine monofluoride with an unsaturated hydrocarbon wherein all the hydrogen has been substituted by halogen (none or not all of which is fluorine). The unsaturated hydrocarbons specified are hexachlorobutadiene, hexachlorobenzene, octachloronaphthalene and decachlorodiphenyl. Solid halogenated unsaturated hydrocarbons, such as octachloronaphthalene, are reacted with chlorine monofluoride when suspended in a halogenated material made by the reaction of chlorine trifluoride with a halogenated aromatic hydrocarbon according to the process of the parent Specification or in a halogenated material produced by a previous reaction of chlorine monofluoride with the same or different halogenated aromatic hydrocarbon, or in a mixture of these two materials. The temperature for this reaction is 100 DEG to 180 DEG C. Other solid reactants are hexachlorobenzene and decachlorodiphenyl. A mixture of octachloronaphthalene, hexachlorobenzene and decachlorodiphenyl may be reacted with chlorine monofluoride. With a liquid reactant such as hexachlorobutadiene, chlorine monofluoride may be passed directly into the reactant. The reaction temperature is 90 DEG to 115 DEG C.ALSO:Chlorine monofluoride is prepared by reacting equal volumes of chlorine trifluoride and chlorine at a temperature of 325 DEG to 370 DEG C.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2456852A GB738289A (en) | 1952-10-01 | 1952-10-01 | Improvements in or relating to the production of organic halogen compounds |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2456852A GB738289A (en) | 1952-10-01 | 1952-10-01 | Improvements in or relating to the production of organic halogen compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB738289A true GB738289A (en) | 1955-10-12 |
Family
ID=10213685
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2456852A Expired GB738289A (en) | 1952-10-01 | 1952-10-01 | Improvements in or relating to the production of organic halogen compounds |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB738289A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3099695A (en) * | 1960-08-04 | 1963-07-30 | Ici Ltd | Vapor phase fluorination with cif and cif3 |
-
1952
- 1952-10-01 GB GB2456852A patent/GB738289A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3099695A (en) * | 1960-08-04 | 1963-07-30 | Ici Ltd | Vapor phase fluorination with cif and cif3 |
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