GB760489A - Improvements in or relating to the manufacture of organic halogen compounds - Google Patents

Improvements in or relating to the manufacture of organic halogen compounds

Info

Publication number
GB760489A
GB760489A GB2846953A GB2846953A GB760489A GB 760489 A GB760489 A GB 760489A GB 2846953 A GB2846953 A GB 2846953A GB 2846953 A GB2846953 A GB 2846953A GB 760489 A GB760489 A GB 760489A
Authority
GB
United Kingdom
Prior art keywords
solvent
chlorinated
chlorine
chlorine monofluoride
containing hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2846953A
Inventor
Jan Muray
Kenneth Duncan Wadsworth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB2846953A priority Critical patent/GB760489A/en
Publication of GB760489A publication Critical patent/GB760489A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00Preparation of halogenated hydrocarbons
    • C07C17/093Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/202Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
    • C07C17/204Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being a halogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for the manufacture of fluorinecontaining organic compounds comprises reacting chlorine monofluoride with an organic compound containing hydrogen at least part of which is directly attached to carbon in the presence of an organic solvent containing fluorine or fluorine and chlorine substituents inert to the reactants and reaction products. The starting material may be a hydrocarbon or halogenated hydrocarbon containing hydrogen, such as n-heptane, trimethylpentane, a paraffin oil, naphthalene, decalin, chlorinated paraffin wax, chlorinated naphthalene, and chlorinated rubber. The solvent may be perfluoromethylcyclohexane or a halogenated material obtained by reacting chlorine monofluoride or trifluoride with an organic compound containing hydrogen. The chlorine monofluoride may be diluted with an inert gas such as nitrogen. The reaction product may be further reacted with chlorine monofluoride or trifluoride at an elevated temperature up to 160 DEG C. In examples: (1) chlorofluorinated paraffin wax dissolved in chlorofluorobutanes is further fluorinated with chlorine monofluoride, and (2) chlorinated paraffin wax is first fluorinated with the product of Example (1) as solvent and then with chlorofluorobutanes as solvent.
GB2846953A 1953-10-15 1953-10-15 Improvements in or relating to the manufacture of organic halogen compounds Expired GB760489A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2846953A GB760489A (en) 1953-10-15 1953-10-15 Improvements in or relating to the manufacture of organic halogen compounds

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2846953A GB760489A (en) 1953-10-15 1953-10-15 Improvements in or relating to the manufacture of organic halogen compounds

Publications (1)

Publication Number Publication Date
GB760489A true GB760489A (en) 1956-10-31

Family

ID=10276133

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2846953A Expired GB760489A (en) 1953-10-15 1953-10-15 Improvements in or relating to the manufacture of organic halogen compounds

Country Status (1)

Country Link
GB (1) GB760489A (en)

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