GB712728A - Process for the production of new thioethers - Google Patents

Process for the production of new thioethers

Info

Publication number
GB712728A
GB712728A GB2001652A GB2001652A GB712728A GB 712728 A GB712728 A GB 712728A GB 2001652 A GB2001652 A GB 2001652A GB 2001652 A GB2001652 A GB 2001652A GB 712728 A GB712728 A GB 712728A
Authority
GB
United Kingdom
Prior art keywords
methoxyphenyl
thioethers
alkyl
hexanone
dimethylamino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2001652A
Inventor
Ernst Habicht
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cilag AG
Original Assignee
Cilag AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cilag AG filed Critical Cilag AG
Priority to GB2001652A priority Critical patent/GB712728A/en
Publication of GB712728A publication Critical patent/GB712728A/en
Expired legal-status Critical Current

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

An improvement in or modification of the process described and claimed in the parent Specification for the production of new thioethers having ketone groups having the formula <FORM:0712728/IV (b)/1> wherein R1 and R2 are hydrogen atoms, halogen atoms, hydroxy or alkoxy groups, X is an acyl group, R3 are alkyl radicals containing a maximum of 6 carbon atoms, R4 is an alkyl or aralkyl radical containing a maximum of 7 carbon atoms, n denotes the numbers 1 or 2, as well as salts of such thioethers, consists in reacting a nitrile of the formula <FORM:0712728/IV (b)/2> with an alkyl magnesium halide in a halogenated benzene as solvent, e.g. chlorbenzene, and hydrolysing the resultant ketimine under acid conditions. Examples describe the preparation of 1-dimethylamino-3-methylthioethyl-3-phenyl, -3-(41-chlorophenyl), -3-(21-methoxyphenyl) and -3-(31-methoxyphenyl)-hexanone-4 and of 1 - dimethylamino - 3 - ethylthioethyl-3-(41-methoxyphenyl)-hexanone-4.
GB2001652A 1952-08-08 1952-08-08 Process for the production of new thioethers Expired GB712728A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2001652A GB712728A (en) 1952-08-08 1952-08-08 Process for the production of new thioethers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2001652A GB712728A (en) 1952-08-08 1952-08-08 Process for the production of new thioethers

Publications (1)

Publication Number Publication Date
GB712728A true GB712728A (en) 1954-07-28

Family

ID=10138945

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2001652A Expired GB712728A (en) 1952-08-08 1952-08-08 Process for the production of new thioethers

Country Status (1)

Country Link
GB (1) GB712728A (en)

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