GB653879A - Improvements in or relating to the production of fluoro- and fluorochloro carbons - Google Patents
Improvements in or relating to the production of fluoro- and fluorochloro carbonsInfo
- Publication number
- GB653879A GB653879A GB2261848A GB2261848A GB653879A GB 653879 A GB653879 A GB 653879A GB 2261848 A GB2261848 A GB 2261848A GB 2261848 A GB2261848 A GB 2261848A GB 653879 A GB653879 A GB 653879A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chlorine
- products
- fluorine
- carbon
- passed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/007—Preparation of halogenated hydrocarbons from carbon or from carbides and halogens
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Fluorocarbons and/or fluorochlorocarbons are made by reacting on carbon jointly with fluorine and chlorine at above 350 DEG C. Amongst the products of reaction there are specified tetrafluorochloroethane and tetrafluorodichloroethane together with compounds such as hydrogen fluoride, carbon dioxide and silicon tetrafluoride. The reactive gases may be derived from a mixture of these gases or a compound thereof, e.g. chlorine mono- or tri-fluoride, or from mixtures of such compounds with themselves or with chlorine or fluorine. The carbon may be in the form of graphite or wood charcoal. Reactor temperatures of 500-550 DEG C. are given and the gases may be preheated. Ratios of fluorine to chlorine may be widely varied, e.g. 1 : 3 to 3 : 1 ratios are quoted, and where large proportions of chlorine are used only small amounts of tetrafluoromethane are obtained. The reactor should be made of material such as recrystalline alumina or a metal such as nickel which is resistant to reactants and products. The gases may be passed through a bed of carbon or a fluidized technique may be used. In examples: (1) fluorine and chlorine in mol. ratio of 0.9 : 1 are passed through Acheson graphite at 500 DEG C. in a stream of nitrogen products being collected in a catch-pot at 5-10 DEG C. and then in traps immersed in liquid air, the pot providing a brown resinous material, possibly a polynuclear aromatic fluorocarbon, and the traps yielding on fractionation after scrubbing with caustic soda solution the above specified compounds, mainly trifluorochloromethane and tetrafluorodichloroethane, and some heptafluorochloropropane; (2) fluorine and chlorine in a mol. ratio of 1.8 : 1 are passed through wood charcoal at 500 DEG C. in a stream of nitrogen and products isolated as in (1) save that HF is removed before the traps by NaF treatment, trifluorochloromethane and tetrafluoromethane are the chief products, and in (3) chlorine trifluoride diluted in a ratio of 1 : 3 with nitrogen is passed through artificial graphite at 500 DEG C. and products are isolated as before excess chlorine trifluoride and its derivatives being removed by scrubbing with sodium hydroxide and sulphite, the main products being trifluorochloromethane and carbon tetrafluoride.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2261848A GB653879A (en) | 1948-08-27 | 1948-08-27 | Improvements in or relating to the production of fluoro- and fluorochloro carbons |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2261848A GB653879A (en) | 1948-08-27 | 1948-08-27 | Improvements in or relating to the production of fluoro- and fluorochloro carbons |
Publications (1)
Publication Number | Publication Date |
---|---|
GB653879A true GB653879A (en) | 1951-05-30 |
Family
ID=10182357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2261848A Expired GB653879A (en) | 1948-08-27 | 1948-08-27 | Improvements in or relating to the production of fluoro- and fluorochloro carbons |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB653879A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732411A (en) * | 1956-01-24 | Preparation of tetrafluorgethylene | ||
CN106397104A (en) * | 2016-10-27 | 2017-02-15 | 广东华特气体股份有限公司 | Carbon tetrafluoride purification system with nitrogen recycling function |
CN106397107A (en) * | 2016-10-27 | 2017-02-15 | 广东华特气体股份有限公司 | Purification system for carbon tetrafluoride |
-
1948
- 1948-08-27 GB GB2261848A patent/GB653879A/en not_active Expired
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2732411A (en) * | 1956-01-24 | Preparation of tetrafluorgethylene | ||
CN106397104A (en) * | 2016-10-27 | 2017-02-15 | 广东华特气体股份有限公司 | Carbon tetrafluoride purification system with nitrogen recycling function |
CN106397107A (en) * | 2016-10-27 | 2017-02-15 | 广东华特气体股份有限公司 | Purification system for carbon tetrafluoride |
CN106397107B (en) * | 2016-10-27 | 2019-05-03 | 广东华特气体股份有限公司 | A kind of purification system of carbon tetrafluoride |
CN106397104B (en) * | 2016-10-27 | 2019-05-07 | 广东华特气体股份有限公司 | A kind of carbon tetrafluoride purification system with nitrogen recycling function |
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