GB628347A - An improved manufacture of hydrocarbon diesel fuels - Google Patents

An improved manufacture of hydrocarbon diesel fuels

Info

Publication number
GB628347A
GB628347A GB18717/47A GB1871747A GB628347A GB 628347 A GB628347 A GB 628347A GB 18717/47 A GB18717/47 A GB 18717/47A GB 1871747 A GB1871747 A GB 1871747A GB 628347 A GB628347 A GB 628347A
Authority
GB
United Kingdom
Prior art keywords
alkyl
hydroperoxide
perester
tertiary butyl
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB18717/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Development Co
Original Assignee
Standard Oil Development Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Development Co filed Critical Standard Oil Development Co
Publication of GB628347A publication Critical patent/GB628347A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B47/00Methods of operating engines involving adding non-fuel substances or anti-knock agents to combustion air, fuel, or fuel-air mixtures of engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A fuel for compression-ignition engines of the Diesel type comprises a hydrocarbon fuel and a small amount of an organic perester. The hydrocarbon fuel may have a boiling range above that of gasoline. A perester specified is t-butyl perbenzoate, and others mentioned are alkyl perfuroates, alkyl perstearates, alkyl perundecylenates, alkyl percrotonates, alkyl dipersuccinates, alkyl diperadipates and alkyl diperphthalates. 0.025-5 per cent of the perester may be used. Other ignition promoters may be added, and also agents such as oiliness agents, sludge dispersers and the like. The organic peresters are compared with tertiary butyl hydroperoxide and with 1-hydroxy cyclohexyl-1-hydroperoxide.ALSO:Organic per-esters are prepared by reacting an acid chloride with an alkyl hydroperoxide in alkaline solution. In an example, tertiary butyl perbenzoate is prepared from tertiary butyl hydroperoxide and benzoyl chloride in potassium hydroxide solution. Other alkyl per-esters such as alkyl perfuroates, alkyl perstearates, alkyl perundecylenates, alkyl percrotonates, alkyl dipersuccinates, alkyl diperadipates and alkyl diperphthalates may be similarly prepared.
GB18717/47A 1946-08-31 1947-07-14 An improved manufacture of hydrocarbon diesel fuels Expired GB628347A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US628347XA 1946-08-31 1946-08-31

Publications (1)

Publication Number Publication Date
GB628347A true GB628347A (en) 1949-08-26

Family

ID=22045131

Family Applications (1)

Application Number Title Priority Date Filing Date
GB18717/47A Expired GB628347A (en) 1946-08-31 1947-07-14 An improved manufacture of hydrocarbon diesel fuels

Country Status (1)

Country Link
GB (1) GB628347A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405417A (en) * 1990-07-16 1995-04-11 Ethyl Corporation Fuel compositions with enhanced combustion characteristics
NL1034160C2 (en) * 2007-07-19 2009-01-20 Univ Eindhoven Tech Fuel mixture and method for its application.
US9303224B2 (en) 2011-11-16 2016-04-05 United Initiators Gmbh & Co. Kg Tert-butyl hydroperoxide (TBHP) as a diesel additive
US9476004B2 (en) 2009-09-08 2016-10-25 Technische Universiteit Eindhoven Liquid fuel composition and the use thereof
EP2115102B1 (en) * 2007-01-15 2017-05-10 Technische Universiteit Eindhoven A liquid fuel composition and the use thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5405417A (en) * 1990-07-16 1995-04-11 Ethyl Corporation Fuel compositions with enhanced combustion characteristics
EP2115102B1 (en) * 2007-01-15 2017-05-10 Technische Universiteit Eindhoven A liquid fuel composition and the use thereof
NL1034160C2 (en) * 2007-07-19 2009-01-20 Univ Eindhoven Tech Fuel mixture and method for its application.
US9476004B2 (en) 2009-09-08 2016-10-25 Technische Universiteit Eindhoven Liquid fuel composition and the use thereof
US9303224B2 (en) 2011-11-16 2016-04-05 United Initiators Gmbh & Co. Kg Tert-butyl hydroperoxide (TBHP) as a diesel additive

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