GB602617A - Improvements in or relating to emulsions - Google Patents
Improvements in or relating to emulsionsInfo
- Publication number
- GB602617A GB602617A GB21918/45A GB2191845A GB602617A GB 602617 A GB602617 A GB 602617A GB 21918/45 A GB21918/45 A GB 21918/45A GB 2191845 A GB2191845 A GB 2191845A GB 602617 A GB602617 A GB 602617A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- palmitic
- triethanolamine
- salt
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title abstract 6
- 239000002253 acid Substances 0.000 abstract 8
- 125000004432 carbon atom Chemical group C* 0.000 abstract 6
- 239000003995 emulsifying agent Substances 0.000 abstract 6
- 150000002357 guanidines Chemical class 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 6
- 150000003839 salts Chemical class 0.000 abstract 6
- 229920006395 saturated elastomer Polymers 0.000 abstract 6
- 235000021314 Palmitic acid Nutrition 0.000 abstract 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 4
- 229960004418 trolamine Drugs 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 3
- 150000002169 ethanolamines Chemical class 0.000 abstract 3
- 239000000194 fatty acid Substances 0.000 abstract 3
- 229930195729 fatty acid Natural products 0.000 abstract 3
- 150000004665 fatty acids Chemical class 0.000 abstract 3
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 3
- 239000007764 o/w emulsion Substances 0.000 abstract 3
- ZHALDANPYXAMJF-UHFFFAOYSA-N octadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCC[NH+](CCO)CCO.CCCCCCCCCCCCCCCCCC([O-])=O ZHALDANPYXAMJF-UHFFFAOYSA-N 0.000 abstract 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 3
- 235000021313 oleic acid Nutrition 0.000 abstract 3
- 150000002889 oleic acids Chemical class 0.000 abstract 3
- 150000002943 palmitic acids Chemical class 0.000 abstract 3
- 150000003152 propanolamines Chemical class 0.000 abstract 3
- 229940029614 triethanolamine stearate Drugs 0.000 abstract 3
- AOHAPDDBNAPPIN-UHFFFAOYSA-N 3-Methoxy-4,5-methylenedioxybenzoic acid Chemical compound COC1=CC(C(O)=O)=CC2=C1OCO2 AOHAPDDBNAPPIN-UHFFFAOYSA-N 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 abstract 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 abstract 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 abstract 2
- 239000011874 heated mixture Substances 0.000 abstract 2
- 239000000314 lubricant Substances 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- 239000012258 stirred mixture Substances 0.000 abstract 2
- 235000021357 Behenic acid Nutrition 0.000 abstract 1
- 229940116226 behenic acid Drugs 0.000 abstract 1
- NDRMWPVNHDJUCA-UHFFFAOYSA-N carbamimidoylazanium;octadecanoate Chemical compound NC(N)=N.CCCCCCCCCCCCCCCCCC(O)=O NDRMWPVNHDJUCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002537 cosmetic Substances 0.000 abstract 1
- 238000005188 flotation Methods 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/18—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/10—Amides of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Lubricants (AREA)
Abstract
An oil-in-water emulsion comprises a guanidine salt of a saturated open chain monocarboxylic acid containing at least 10 carbon atoms as the emulsifying agent. The preferred acid is a soap-forming saturated acid, such as stearic, lauric, palmitic, myristic and behenic acid. Alternatively the emulsifying agent may comprise the said guanidine salt in combination with an alkylolamine salt of a carboxylic acid containing at least 10 carbon atoms, such as triethanolamine stearate, or the salts of commercial mixtures of various ethanolamines and propanolamines or their alkylated derivatives with fatty acids, such as palmitic and oleic acids. The emulsion composition also desirably includes a small amount of a free alkylolamine such as triethanolamine. The emulsions find application as lubricants for air compressors. According to an example, a lubricant is prepared by adding guanidine carbonate dissolved in a minimum amount of water to stirred and heated mixture of stearic acid and water, followed by the addition of a pale mineral oil having a viscosity of 88-92 Saybolt at 210 DEG F., and aqueous triethanolamine, the temperature being maintained at 180 DEG F. or above until the emulsion is formed.ALSO:Guanidine stearate is obtained by adding guanidine carbonate, dissolved in a minimum amount of water, to a stirred and heated mixture of stearic acid and water.ALSO:An oil-in-water emulsion suitable as a flotation oil comprises a guanidine salt of a saturated open chain monocarboxylic acid containing at least 10 carbon atoms as the emulsifying agent. The preferred acid is a soap-forming saturated acid, such as stearic, lauric, palmitic, myristic and behemic acid. Alternatively the emulsifying agent may comprise the said guanidine salt in combination with an alkylolamine salt of a carboxylic acid containing at least 10 carbon atoms, such as triethanolamine stearate, or the salts of commercial mixtures of various ethanolamines and propanolamines or their alkylated derivatives with fatty acids, such as palmitic and oleic acids. The emulsion composition also desirably includes a small amount of a free alkylolamine such as triethanolamine.ALSO:An oil-in-water emulsion suitable as an insecticide spray or cosmetic base comprises a guanidine salt of a saturated open chain monocarboxylic acid containing at least 10 carbon atoms as the emulsifying agent. The preferred acid is a soap-forming saturated acid, such as stearic, lauric, palmitic, myristic and behemic acid. Alternatively the emulsifying agent may comprise the said guanidine salt in combination with an alkylolamine salt of a carboxylic acid containing at least 10 carbon atoms, such as triethanolamine stearate, or the salts of commercial mixtures of various ethanolamines and propanolamines or their alkylated derivatives with fatty acids, such as palmitic and oleic acids. The emulsion composition also desirably includes a small amount of a free alkylolamine such as triethanolamine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US602617XA | 1944-08-31 | 1944-08-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB602617A true GB602617A (en) | 1948-05-31 |
Family
ID=22028390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21918/45A Expired GB602617A (en) | 1944-08-31 | 1945-08-27 | Improvements in or relating to emulsions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB602617A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1038688B (en) * | 1956-06-08 | 1958-09-11 | Esso A G | Cylinder lubricant for the lubrication of large diesel engines operated with diesel or heating oils with a high sulfur content |
| CN114007575A (en) * | 2019-08-07 | 2022-02-01 | 拜尔斯道夫股份有限公司 | Cosmetic nanoemulsions |
-
1945
- 1945-08-27 GB GB21918/45A patent/GB602617A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1038688B (en) * | 1956-06-08 | 1958-09-11 | Esso A G | Cylinder lubricant for the lubrication of large diesel engines operated with diesel or heating oils with a high sulfur content |
| CN114007575A (en) * | 2019-08-07 | 2022-02-01 | 拜尔斯道夫股份有限公司 | Cosmetic nanoemulsions |
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