GB467839A - Improved rust-removing and rust-proofing compositions - Google Patents

Improved rust-removing and rust-proofing compositions

Info

Publication number
GB467839A
GB467839A GB35630/35A GB3563035A GB467839A GB 467839 A GB467839 A GB 467839A GB 35630/35 A GB35630/35 A GB 35630/35A GB 3563035 A GB3563035 A GB 3563035A GB 467839 A GB467839 A GB 467839A
Authority
GB
United Kingdom
Prior art keywords
alcohols
sulphation
phosphoric acid
salts
products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35630/35A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grasselli Chemical Co
Original Assignee
Grasselli Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grasselli Chemical Co filed Critical Grasselli Chemical Co
Publication of GB467839A publication Critical patent/GB467839A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08Orthophosphates

Abstract

A mixture of phosphoric acid and a sulphation product of an alcohol containing six or more carbon atoms is used for rust removing or rust proofing. In modifications, salts of the sulphation products may be employed and also products obtained by sulphonating esters of the higher alcohols, or ether-alcohols such as mono octadecyl, octadecenyl and hexadecyl glyceryl ethers. In the case of the esters such as octylacetate, hydrolysis takes place simultaneously with the sulphonation. In examples: (1) a sulphation product of a mixture of stearyl and cetyl alcohols is mixed and heated with phosphoric acid solution; (2) phosphoric acid is mixed with the sodium salts of the sulphation products of alcohols containing 12 to 18 carbon atoms. The compositions are sufficiently viscous to be applied to vertical steel panels. Oleyl, lauryl, carnaubyl, melissyl, myristyl, linoleyl and ricinoleyl alcohols are mentioned and also chlorinated or other halogenated alcohols. Lithium, magnesium, pyridine, piperidine, cyclohexylamine, alkylcyclohexylamine, mono-, di- and tri-alkylamine and alkylolamine salts of the sulphated alcohols may be used, and salts present as impurities such as sodium sulphate or chloride need not be removed.ALSO:A mixture of phosphoric acid and a sulphation product of an alcohol containing six or more carbon atoms is used for rust proofing or rust removing. According to modifications, salts of the sulphation products may be employed, and also products obtained by sulphonating esters of the higher alcohols, or p etheralcohols, e.g. monooctadecyl-, octadecenyl-, and hexadecyl-glyceryl ethers. In examples: (1) a 33 per cent phosphoric acid solution has 3 per cent of the sulphation product of a mixture of stearyl and cetyl alcohols added thereto: (2) 5 per cent of the sodium salts of the sulphation products of alcohols with 12 to 18 carbon atoms, containing sodium sulphate and chloride as impurities, is added to a 35 per cent phosphoric acid solution. Oleyl, lauryl, carnaubyl, myristyl, linoleyl and ricinoleyl alcohols are mentioned and also chlorinated alcohols. Lithium, magnesium, pyridine, piperidine, cyclohexylamine, alkylamine and alkylolamine salts of the sulphated alcohols may be used.ALSO:A mixture of phosphoric acid and a sulphation product of an alcohol containing six or more carbon atoms is used for rust-removing or rustproofing. In modifications, salts of the sulphation products may be employed and also products obtained by sulphonating esters of the higher alcohols, or ether-alcohols such as monooctadecyl-, octadecenyl- and hexadecylglyceryl ethers. According to examples: (1) a sulphation product of a mixture of stearyl and cetyl alcohols is mixed with a phosphoric acid solution; (2) phosphoric acid is mixed with the sodium salts of the sulphation products of alcohols containing 12 to 18 carbon atoms. The compositions are sufficiently viscous to be applied to vertical steel panels. Oleyl, lauryl, carnaubyl, melissyl, myristyl, linoleyl and ricinoleyl alcohols are mentioned and also chlorinated and other halogenated alcohols. Lithium, magnesium, pyridine, piperidine, cyclohexylamine, alkylcyclohexylamine, mono-, di- and tri-alkylamine and alkylolamine salts of the sulphonated alcohols may be used.
GB35630/35A 1934-12-24 1935-12-23 Improved rust-removing and rust-proofing compositions Expired GB467839A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US467839XA 1934-12-24 1934-12-24

Publications (1)

Publication Number Publication Date
GB467839A true GB467839A (en) 1937-06-23

Family

ID=21945375

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35630/35A Expired GB467839A (en) 1934-12-24 1935-12-23 Improved rust-removing and rust-proofing compositions

Country Status (1)

Country Link
GB (1) GB467839A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1072053B (en) * 1959-12-24 Metallgesellschaft Aktiengesellschaft, Frankfurt/M Rust removal paste
DE1091400B (en) * 1956-04-13 1960-10-20 Metallgesellschaft Ag Rust removal paste

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1072053B (en) * 1959-12-24 Metallgesellschaft Aktiengesellschaft, Frankfurt/M Rust removal paste
DE1091400B (en) * 1956-04-13 1960-10-20 Metallgesellschaft Ag Rust removal paste

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