GB240087A - Improvements in the manufacture and production of formamide - Google Patents

Improvements in the manufacture and production of formamide

Info

Publication number
GB240087A
GB240087A GB1136125A GB1136125A GB240087A GB 240087 A GB240087 A GB 240087A GB 1136125 A GB1136125 A GB 1136125A GB 1136125 A GB1136125 A GB 1136125A GB 240087 A GB240087 A GB 240087A
Authority
GB
United Kingdom
Prior art keywords
formamide
ammonia
formate
action
methyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1136125A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Priority to GB1136125A priority Critical patent/GB240087A/en
Publication of GB240087A publication Critical patent/GB240087A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/01Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Formamide is made by the action of ammonia on an alkyl formate at a pressure exceeding atmospheric pressure. Liquid ammonia is preferably used, but gaseous ammonia or a strong aqueous ammonia may be employed; in the latter case more or less ammonium formate is formed at the same time. When the pressure is released the heat of the reaction serves to evaporate the alcohol formed, leaving a residue of nearly pure formamide. Methyl formate, which may be obtained by the action of carbon monoxide on methyl alcohol or as a bye-product in the catalytic hydrogenation of oxides of carbon to methyl alcohol, is the alkyl formate preferably employed. The alkyl formate may be produced in the same reaction chamber as the formamide by the action of carbon monoxide on methyl alcohol in the presence of an alkali metal or alcoholate; the ammonia required for the production of formamide being introduced at the same time or subsequently.
GB1136125A 1925-05-01 1925-05-01 Improvements in the manufacture and production of formamide Expired GB240087A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1136125A GB240087A (en) 1925-05-01 1925-05-01 Improvements in the manufacture and production of formamide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1136125A GB240087A (en) 1925-05-01 1925-05-01 Improvements in the manufacture and production of formamide

Publications (1)

Publication Number Publication Date
GB240087A true GB240087A (en) 1925-09-24

Family

ID=9984823

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1136125A Expired GB240087A (en) 1925-05-01 1925-05-01 Improvements in the manufacture and production of formamide

Country Status (1)

Country Link
GB (1) GB240087A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019111071A1 (en) * 2019-04-29 2020-10-29 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Process for the catalytic production of formamide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102019111071A1 (en) * 2019-04-29 2020-10-29 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Process for the catalytic production of formamide

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