GB2160535A - Zirconium and/or hafnium based catalyst for the polymerization of unsaturated compounds - Google Patents
Zirconium and/or hafnium based catalyst for the polymerization of unsaturated compounds Download PDFInfo
- Publication number
- GB2160535A GB2160535A GB08515470A GB8515470A GB2160535A GB 2160535 A GB2160535 A GB 2160535A GB 08515470 A GB08515470 A GB 08515470A GB 8515470 A GB8515470 A GB 8515470A GB 2160535 A GB2160535 A GB 2160535A
- Authority
- GB
- United Kingdom
- Prior art keywords
- titanium
- compound
- zirconium
- inclusive
- hafnium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 20
- 150000001875 compounds Chemical class 0.000 title claims abstract description 18
- 229910052726 zirconium Inorganic materials 0.000 title claims abstract description 17
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 229910052735 hafnium Inorganic materials 0.000 title claims abstract description 14
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000006116 polymerization reaction Methods 0.000 title description 16
- 239000010936 titanium Substances 0.000 claims abstract description 36
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 31
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000011777 magnesium Substances 0.000 claims abstract description 18
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000002367 halogens Chemical class 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 238000007669 thermal treatment Methods 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 9
- -1 organometallic aluminium compound Chemical class 0.000 claims abstract description 9
- 238000009834 vaporization Methods 0.000 claims abstract description 7
- 230000008016 vaporization Effects 0.000 claims abstract description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 6
- 125000005843 halogen group Chemical group 0.000 claims abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
- 125000003118 aryl group Chemical group 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 32
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 12
- 230000003197 catalytic effect Effects 0.000 claims description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 150000002430 hydrocarbons Chemical group 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 2
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 claims description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims 2
- 150000001398 aluminium Chemical class 0.000 claims 1
- 239000013522 chelant Substances 0.000 claims 1
- 229910001502 inorganic halide Inorganic materials 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 13
- 239000000725 suspension Substances 0.000 description 13
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 238000009826 distribution Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 230000006353 environmental stress Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 229910010066 TiC14 Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000000075 primary alcohol group Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT21559/84A IT1176299B (it) | 1984-06-22 | 1984-06-22 | Metodo per la preparazione di un catalizzatore a base di zirconio o afnio e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante lo stesso |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB8515470D0 GB8515470D0 (en) | 1985-07-24 |
| GB2160535A true GB2160535A (en) | 1985-12-24 |
Family
ID=11183595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08515470A Withdrawn GB2160535A (en) | 1984-06-22 | 1985-06-19 | Zirconium and/or hafnium based catalyst for the polymerization of unsaturated compounds |
Country Status (18)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015511A (en) * | 1988-05-12 | 1991-05-14 | The Dow Chemical Company | Linear low density ethylene interpolymers for injection molding |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2740922B2 (ja) * | 1989-11-21 | 1998-04-15 | 石原産業株式会社 | 磁気記録材料用金属磁性粉末の製造方法 |
| IT1311978B1 (it) * | 1999-03-25 | 2002-03-22 | Polimeri Europa Srl | Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine. |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1464451A (en) * | 1973-09-08 | 1977-02-16 | Chubu Chem Inc | Solid catalytic complexes and their use in olefin polymerization |
| GB1493159A (en) * | 1974-10-18 | 1977-11-23 | Chubu Chem Inc | Catalyst composition and a process for the production of olefin polymers |
| GB1578745A (en) * | 1976-05-24 | 1980-11-12 | Bp Chem Int Ltd | Polymerisation catalyst component |
| GB2103226A (en) * | 1981-07-29 | 1983-02-16 | Agip Petroli | Process for the polymerization of olefinically unsaturated compounds |
| GB2114584A (en) * | 1982-02-12 | 1983-08-24 | Enoxy Chimica | Ethylene copolymers having a linear structure |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1130243B (it) * | 1980-02-01 | 1986-06-11 | Anic Spa | Composizione chimica a base di titanio trialogenuro,metodo per la sua preparazione e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante la stessa |
| US4396747A (en) * | 1981-05-22 | 1983-08-02 | Phillips Petroleum Company | Zirconium-titanium catalyzed olefin polymerization |
-
1984
- 1984-06-22 IT IT21559/84A patent/IT1176299B/it active
-
1985
- 1985-06-18 SE SE8503033A patent/SE8503033L/xx not_active Application Discontinuation
- 1985-06-18 NO NO852451A patent/NO852451L/no unknown
- 1985-06-18 ZA ZA854595A patent/ZA854595B/xx unknown
- 1985-06-19 GB GB08515470A patent/GB2160535A/en not_active Withdrawn
- 1985-06-20 IL IL75590A patent/IL75590A0/xx unknown
- 1985-06-20 LU LU85968A patent/LU85968A1/fr unknown
- 1985-06-20 DK DK279185A patent/DK279185A/da not_active Application Discontinuation
- 1985-06-21 DE DE19853522295 patent/DE3522295A1/de not_active Ceased
- 1985-06-21 FR FR8509510A patent/FR2566412A1/fr not_active Withdrawn
- 1985-06-21 BE BE0/215248A patent/BE902730A/fr not_active IP Right Cessation
- 1985-06-21 GR GR851522A patent/GR851522B/el unknown
- 1985-06-21 RO RO119262A patent/RO92339B/ro unknown
- 1985-06-21 PL PL25412085A patent/PL254120A1/xx unknown
- 1985-06-21 JP JP60134440A patent/JPS6114202A/ja active Pending
- 1985-06-21 PT PT80685A patent/PT80685B/pt unknown
- 1985-06-21 ES ES544981A patent/ES8609372A1/es not_active Expired
- 1985-06-24 NL NL8501815A patent/NL8501815A/nl not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1464451A (en) * | 1973-09-08 | 1977-02-16 | Chubu Chem Inc | Solid catalytic complexes and their use in olefin polymerization |
| GB1493159A (en) * | 1974-10-18 | 1977-11-23 | Chubu Chem Inc | Catalyst composition and a process for the production of olefin polymers |
| US4245071A (en) * | 1974-10-18 | 1981-01-13 | Solvay & Cie. | Low pressure polymerization of olefins |
| GB1578745A (en) * | 1976-05-24 | 1980-11-12 | Bp Chem Int Ltd | Polymerisation catalyst component |
| GB2103226A (en) * | 1981-07-29 | 1983-02-16 | Agip Petroli | Process for the polymerization of olefinically unsaturated compounds |
| GB2114584A (en) * | 1982-02-12 | 1983-08-24 | Enoxy Chimica | Ethylene copolymers having a linear structure |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015511A (en) * | 1988-05-12 | 1991-05-14 | The Dow Chemical Company | Linear low density ethylene interpolymers for injection molding |
Also Published As
| Publication number | Publication date |
|---|---|
| BE902730A (fr) | 1985-12-23 |
| DK279185D0 (da) | 1985-06-20 |
| IL75590A0 (en) | 1985-10-31 |
| PT80685B (en) | 1987-03-31 |
| SE8503033L (sv) | 1985-12-23 |
| PT80685A (en) | 1985-07-01 |
| RO92339B (ro) | 1987-09-01 |
| DE3522295A1 (de) | 1985-12-19 |
| PL254120A1 (en) | 1986-05-20 |
| DK279185A (da) | 1985-12-23 |
| NL8501815A (nl) | 1986-01-16 |
| NO852451L (no) | 1985-12-23 |
| ES8609372A1 (es) | 1986-07-16 |
| IT1176299B (it) | 1987-08-18 |
| IT8421559A0 (it) | 1984-06-22 |
| LU85968A1 (fr) | 1986-01-24 |
| FR2566412A1 (fr) | 1985-12-27 |
| ES544981A0 (es) | 1986-07-16 |
| GB8515470D0 (en) | 1985-07-24 |
| GR851522B (enrdf_load_stackoverflow) | 1985-11-25 |
| SE8503033D0 (sv) | 1985-06-18 |
| ZA854595B (en) | 1986-02-26 |
| IT8421559A1 (it) | 1985-12-22 |
| RO92339A (ro) | 1987-08-31 |
| JPS6114202A (ja) | 1986-01-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |