GB2135295B - Steam reforming of methanol - Google Patents

Steam reforming of methanol

Info

Publication number
GB2135295B
GB2135295B GB08403537A GB8403537A GB2135295B GB 2135295 B GB2135295 B GB 2135295B GB 08403537 A GB08403537 A GB 08403537A GB 8403537 A GB8403537 A GB 8403537A GB 2135295 B GB2135295 B GB 2135295B
Authority
GB
United Kingdom
Prior art keywords
methanol
steam reforming
reforming
steam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB08403537A
Other languages
English (en)
Other versions
GB2135295A (en
GB8403537D0 (en
Inventor
Mikio Yoneoka
Tomiyoshi Furuta
Yasuo Yamamoto
Sadao Nozaki
Kazuo Takada
Kumiko Watabe
Takeo Ikarashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Publication of GB8403537D0 publication Critical patent/GB8403537D0/en
Publication of GB2135295A publication Critical patent/GB2135295A/en
Application granted granted Critical
Publication of GB2135295B publication Critical patent/GB2135295B/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01B—BOILING; BOILING APPARATUS ; EVAPORATION; EVAPORATION APPARATUS
    • B01B1/00—Boiling; Boiling apparatus for physical or chemical purposes ; Evaporation in general
    • B01B1/005—Evaporation for physical or chemical purposes; Evaporation apparatus therefor, e.g. evaporation of liquids for gas phase reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalysts
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048—Purification of waste water by evaporation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M57/00—Fuel-injectors combined or associated with other devices
    • F02M57/02—Injectors structurally combined with fuel-injection pumps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M59/00—Pumps specially adapted for fuel-injection and not provided for in groups F02M39/00 -F02M57/00, e.g. rotary cylinder-block type of pumps
    • F02M59/20—Varying fuel delivery in quantity or timing
    • F02M59/24—Varying fuel delivery in quantity or timing with constant-length-stroke pistons having variable effective portion of stroke
    • F02M59/26—Varying fuel delivery in quantity or timing with constant-length-stroke pistons having variable effective portion of stroke caused by movements of pistons relative to their cylinders
    • F02M59/265—Varying fuel delivery in quantity or timing with constant-length-stroke pistons having variable effective portion of stroke caused by movements of pistons relative to their cylinders characterised by the arrangement or form of spill port of spill contour on the piston
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
GB08403537A 1983-02-14 1984-02-10 Steam reforming of methanol Expired GB2135295B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58022493A JPS59152205A (ja) 1983-02-14 1983-02-14 メタノ−ルの水蒸気改質法

Publications (3)

Publication Number Publication Date
GB8403537D0 GB8403537D0 (en) 1984-03-14
GB2135295A GB2135295A (en) 1984-08-30
GB2135295B true GB2135295B (en) 1986-09-17

Family

ID=12084253

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08403537A Expired GB2135295B (en) 1983-02-14 1984-02-10 Steam reforming of methanol

Country Status (4)

Country Link
US (1) US4913842A (enExample)
JP (1) JPS59152205A (enExample)
DE (1) DE3405217A1 (enExample)
GB (1) GB2135295B (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU4695985A (en) * 1984-09-04 1986-03-13 Mitsubishi Jukogyo Kabushiki Kaisha Process for reforming methanol
JPS61109741A (ja) * 1984-11-05 1986-05-28 Res Assoc Petroleum Alternat Dev<Rapad> 含酸素有機化合物を製造する方法
JPS61183101A (ja) * 1985-02-07 1986-08-15 Mitsubishi Heavy Ind Ltd メタノ−ル分解または改質反応における副生物の処理方法
DE3688990T2 (de) * 1985-06-10 1994-05-11 Us Energy Brennstoffzelle mit integriertem Wasserdampfumformer.
US4946667A (en) * 1985-06-10 1990-08-07 Engelhard Corporation Method of steam reforming methanol to hydrogen
JPS62193696A (ja) * 1986-02-20 1987-08-25 Nomura Micro Sci Kk 超純水の製造法
US4892712A (en) * 1987-09-04 1990-01-09 Nutech Energy Systems Inc. Fluid purification
US5055599A (en) * 1989-06-23 1991-10-08 The Standard Oil Company Process for the hydrogenation of maleic anhydride to tetrahydrofuran and gamma-butyrolactone
US5904880A (en) * 1996-12-31 1999-05-18 Exxon Chemical Patents Inc. One step conversion of methanol to hydrogen and carbon dioxide
DE19725009C1 (de) * 1997-06-13 1999-03-04 Dbb Fuel Cell Engines Gmbh Verfahren zur Behandlung eines Methanolreformierungskatalysators
DE19725006C2 (de) * 1997-06-13 1999-04-29 Dbb Fuel Cell Engines Gmbh Methanolreformierungsreaktor und Behandlungsverfahren für einen Katalysator hierfür
DE19739773A1 (de) * 1997-09-10 1999-03-11 Basf Ag Verfahren und Katalysator zur Dampfreformierung von Methanol
DE59900542D1 (de) * 1999-05-22 2002-01-24 Omg Ag & Co Kg Verwendung eines Katalysators für die Dampfreformierung von Methanol
FR2795339B1 (fr) * 1999-06-24 2001-09-21 Peugeot Citroen Automobiles Sa Catalyseur et procede de reformage de l'ethanol ainsi que systeme de pile a combustible les utilisant
JP3743995B2 (ja) 1999-12-15 2006-02-08 日産自動車株式会社 メタノール改質触媒
KR100400591B1 (ko) * 2000-07-18 2003-10-08 미쯔이카가쿠 가부시기가이샤 메탄올의 수증기개질촉매 및 그것을 이용한 수소제조법
DE10111198A1 (de) * 2001-03-08 2002-09-19 Basf Ag Methanolreformierungskatalysator mit verringertem Volumenschwund
DE10116152A1 (de) * 2001-03-31 2002-10-10 Mg Technologies Ag Verfahren zur Herstellung von Ammoniak aus Methanol
US6924399B2 (en) * 2001-12-28 2005-08-02 Mitsubishi Heavy Industries, Ltd. Method of manufacturing dimethyl ether
FR2857003B1 (fr) * 2003-07-02 2006-08-11 Inst Francais Du Petrole Nouveau catalyseur pour le vaporeformage de l'ethanol
US8394863B2 (en) * 2003-08-21 2013-03-12 Pearson Technologies, Inc. Process and apparatus for the production of useful products from carbonaceous feedstock
TW200519073A (en) * 2003-08-21 2005-06-16 Pearson Technologies Inc Process and apparatus for the production of useful products from carbonaceous feedstock
CA2559028A1 (en) * 2004-03-30 2005-10-20 California Institute Of Technology Direct alcohol fuel cells using solid acid electrolytes
BRPI0716517B1 (pt) * 2006-09-08 2018-03-06 Gelato Corporation N.V. Processos para a produção de uma mistura em fase vapor e para a produção de metanol
US8581010B2 (en) * 2011-05-04 2013-11-12 John E. Stauffer Formation of ethanol from methanol
US8720390B2 (en) * 2011-09-19 2014-05-13 Northern Technologies International Corporation Fuel performance booster
US10040737B2 (en) 2015-07-14 2018-08-07 John E. Stauffer Methanol production from methane and carbon dioxide
US10293304B2 (en) 2015-07-14 2019-05-21 John E. Stauffer Carbon dioxide recovery using an absorption column in combination with osmotic filters
US10493397B2 (en) 2015-07-14 2019-12-03 John E. Stauffer Carbon dioxide recovery
WO2018216555A1 (ja) * 2017-05-25 2018-11-29 大阪瓦斯株式会社 ガスの脱硫剤および脱硫方法
US11987497B2 (en) * 2019-12-06 2024-05-21 Palo Alto Research Center Incorporated Liquid metal condensate catalyzed hydrocarbon pyrolysis
US20230398520A1 (en) * 2022-06-09 2023-12-14 Clariant International Ltd High temperature methanol steam reforming catalyst
CN115155582B (zh) * 2022-08-22 2024-04-09 上海交通大学绍兴新能源与分子工程研究院 一种活性炭负载的甲醇重整制氢催化剂及其制备方法与应用
CN115888754B (zh) * 2022-12-30 2024-07-05 广西民族师范学院 一种低铜含量的甲醇重整制氢催化剂的制备方法
CN119591052B (zh) * 2024-12-06 2025-08-08 四川科鸿旺源科技发展有限责任公司 一种甲醇制氢联产高纯co2的方法

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DE1299567B (de) * 1964-01-03 1969-07-17 Hoechst Ag Verfahren zum Reinigen von Abwaessern
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DE2624975A1 (de) * 1975-07-28 1977-02-17 Engelhard Min & Chem Einstufiges katalytisches verfahren zur herstellung von brenngas
US4072608A (en) * 1976-01-13 1978-02-07 Phillips Petroleum Company Polluted water purification
US4110256A (en) * 1976-06-22 1978-08-29 Nippon Soken, Inc. Catalyst for reforming fuel and method for producing same
GB1577069A (en) * 1977-07-27 1980-10-15 British Petroleum Co Process for the production of synthesis gas by the catalysed decomposition of methanol
US4268399A (en) * 1978-02-13 1981-05-19 Phillips Petroleum Company Purification of polluted water
EP0010779B1 (de) * 1978-03-04 1981-11-04 Metallgesellschaft Ag Verfahren zur Erzeugung von Stadtgas aus Methanol
BE884720A (fr) * 1980-08-11 1981-02-11 Catalysts & Chem Europ Procede de reformage de methanol et dispositif mis en oeuvre

Also Published As

Publication number Publication date
DE3405217A1 (de) 1984-08-16
JPH0261402B2 (enExample) 1990-12-20
JPS59152205A (ja) 1984-08-30
GB2135295A (en) 1984-08-30
GB8403537D0 (en) 1984-03-14
US4913842A (en) 1990-04-03
DE3405217C2 (enExample) 1987-12-10

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee