GB1588521A - Metal complexes - Google Patents
Metal complexes Download PDFInfo
- Publication number
- GB1588521A GB1588521A GB5095/77A GB509577A GB1588521A GB 1588521 A GB1588521 A GB 1588521A GB 5095/77 A GB5095/77 A GB 5095/77A GB 509577 A GB509577 A GB 509577A GB 1588521 A GB1588521 A GB 1588521A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixed
- metal
- metal complex
- alkanolamine
- complexes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 57
- 239000002184 metal Substances 0.000 title claims description 57
- 150000004696 coordination complex Chemical class 0.000 claims description 30
- 239000000084 colloidal system Substances 0.000 claims description 27
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 24
- 239000010936 titanium Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 19
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 18
- 229910052719 titanium Inorganic materials 0.000 claims description 18
- 150000004703 alkoxides Chemical class 0.000 claims description 17
- 150000005846 sugar alcohols Polymers 0.000 claims description 17
- 239000004411 aluminium Substances 0.000 claims description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 11
- 230000009974 thixotropic effect Effects 0.000 claims description 10
- -1 zirconium alkoxides Chemical class 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 229910052726 zirconium Inorganic materials 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- 238000004821 distillation Methods 0.000 claims description 8
- 238000002474 experimental method Methods 0.000 claims description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 235000021317 phosphate Nutrition 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 159000000007 calcium salts Chemical class 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000011068 loading method Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001398 aluminium Chemical class 0.000 claims description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 2
- 239000006227 byproduct Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 238000001879 gelation Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 238000009877 rendering Methods 0.000 claims description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 238000007792 addition Methods 0.000 description 4
- 239000008139 complexing agent Substances 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000003754 zirconium Chemical class 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Colloid Chemistry (AREA)
- Paints Or Removers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5095/77A GB1588521A (en) | 1977-02-08 | 1977-02-08 | Metal complexes |
| NLAANVRAGE7801191,A NL184627C (nl) | 1977-02-08 | 1978-02-02 | Metaalcomplex en samenstelling, die dit complex bevat. |
| DE19782804355 DE2804355A1 (de) | 1977-02-08 | 1978-02-02 | Metallkomplexe, verfahren zu ihrer herstellung und ihre verwendung in thixotropen zubereitungen |
| FR7803062A FR2379589A1 (fr) | 1977-02-08 | 1978-02-03 | Complexes metalliques |
| SE7801418A SE7801418L (sv) | 1977-02-08 | 1978-02-07 | Metallkomplex och forfarande for dess framstellning |
| CA296,587A CA1112654A (en) | 1977-02-08 | 1978-02-07 | Metal complexes prepared by reacting an alkanolamine, a mixture of metal alkoxides and a polyhydric alcohol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB5095/77A GB1588521A (en) | 1977-02-08 | 1977-02-08 | Metal complexes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1588521A true GB1588521A (en) | 1981-04-23 |
Family
ID=9789659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5095/77A Expired GB1588521A (en) | 1977-02-08 | 1977-02-08 | Metal complexes |
Country Status (6)
| Country | Link |
|---|---|
| CA (1) | CA1112654A (nl) |
| DE (1) | DE2804355A1 (nl) |
| FR (1) | FR2379589A1 (nl) |
| GB (1) | GB1588521A (nl) |
| NL (1) | NL184627C (nl) |
| SE (1) | SE7801418L (nl) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5076847A (en) * | 1987-07-25 | 1991-12-31 | Tioxide Group Plc | Titanium compounds, composition containing them and their preparation |
| US9169432B2 (en) | 2012-06-29 | 2015-10-27 | Schlumberger Technology Corporation | Spread crosslinker and method of water control downhole |
| CN113461359A (zh) * | 2021-06-29 | 2021-10-01 | 江苏先帅科技有限公司 | 一种管片预制件用复合聚羧酸减水剂及其制备方法 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4683068A (en) * | 1981-10-29 | 1987-07-28 | Dowell Schlumberger Incorporated | Fracturing of subterranean formations |
| US4534870A (en) * | 1982-06-28 | 1985-08-13 | The Western Company Of North America | Crosslinker composition for high temperature hydraulic fracturing fluids |
| GB8410497D0 (en) * | 1984-04-25 | 1984-05-31 | Allied Colloids Ltd | Synthesis of vinyl esters |
| GB8621714D0 (en) * | 1986-09-09 | 1986-10-15 | Manchem Ltd | Binders for refractories |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL121863C (nl) * | 1959-04-02 | |||
| GB1101427A (en) * | 1963-12-02 | 1968-01-31 | Ici Ltd | Thixotropic polymer dispersions |
| GB1029723A (en) * | 1964-01-21 | 1966-05-18 | Ass Lead Mfg Ltd | Improvements in thixotropic emulsion compositions |
| GB1123559A (en) * | 1966-09-14 | 1968-08-14 | British Titan Products | Film forming compositions |
| GB1362054A (en) * | 1971-10-28 | 1974-07-30 | British Titan Ltd | Aqueous emulsion paints |
| DE2620189C3 (de) * | 1976-05-07 | 1980-06-12 | Hoechst Ag, 6000 Frankfurt | Thixotrope Mischung |
-
1977
- 1977-02-08 GB GB5095/77A patent/GB1588521A/en not_active Expired
-
1978
- 1978-02-02 NL NLAANVRAGE7801191,A patent/NL184627C/nl not_active IP Right Cessation
- 1978-02-02 DE DE19782804355 patent/DE2804355A1/de active Granted
- 1978-02-03 FR FR7803062A patent/FR2379589A1/fr active Granted
- 1978-02-07 SE SE7801418A patent/SE7801418L/xx unknown
- 1978-02-07 CA CA296,587A patent/CA1112654A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5076847A (en) * | 1987-07-25 | 1991-12-31 | Tioxide Group Plc | Titanium compounds, composition containing them and their preparation |
| US9169432B2 (en) | 2012-06-29 | 2015-10-27 | Schlumberger Technology Corporation | Spread crosslinker and method of water control downhole |
| CN113461359A (zh) * | 2021-06-29 | 2021-10-01 | 江苏先帅科技有限公司 | 一种管片预制件用复合聚羧酸减水剂及其制备方法 |
| CN113461359B (zh) * | 2021-06-29 | 2022-05-10 | 江苏先帅科技有限公司 | 一种管片预制件用复合聚羧酸减水剂及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| SE7801418L (sv) | 1978-08-09 |
| CA1112654A (en) | 1981-11-17 |
| FR2379589A1 (fr) | 1978-09-01 |
| NL184627B (nl) | 1989-04-17 |
| NL184627C (nl) | 1989-09-18 |
| FR2379589B1 (nl) | 1984-09-21 |
| NL7801191A (nl) | 1978-08-10 |
| DE2804355A1 (de) | 1978-08-10 |
| DE2804355C2 (nl) | 1989-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee | ||
| 728C | Application made for restoration (sect. 28/1977) | ||
| 728A | Order made restoring the patent (sect. 28/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |