GB1365557A - Process for preparing graft copolymer emulsions - Google Patents
Process for preparing graft copolymer emulsionsInfo
- Publication number
- GB1365557A GB1365557A GB3521271A GB3521271A GB1365557A GB 1365557 A GB1365557 A GB 1365557A GB 3521271 A GB3521271 A GB 3521271A GB 3521271 A GB3521271 A GB 3521271A GB 1365557 A GB1365557 A GB 1365557A
- Authority
- GB
- United Kingdom
- Prior art keywords
- graft
- polyvinyl alcohol
- weight
- cerium
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000578 graft copolymer Polymers 0.000 title abstract 4
- 239000000839 emulsion Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 9
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 7
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- 150000000703 Cerium Chemical class 0.000 abstract 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 3
- 229920001400 block copolymer Polymers 0.000 abstract 3
- 238000012661 block copolymerization Methods 0.000 abstract 3
- 238000010559 graft polymerization reaction Methods 0.000 abstract 3
- 239000011541 reaction mixture Substances 0.000 abstract 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 2
- HKVFISRIUUGTIB-UHFFFAOYSA-O azanium;cerium;nitrate Chemical compound [NH4+].[Ce].[O-][N+]([O-])=O HKVFISRIUUGTIB-UHFFFAOYSA-O 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 230000009477 glass transition Effects 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- PGJHGXFYDZHMAV-UHFFFAOYSA-K azanium;cerium(3+);disulfate Chemical compound [NH4+].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O PGJHGXFYDZHMAV-UHFFFAOYSA-K 0.000 abstract 1
- PTPCOFYZPRTMPE-UHFFFAOYSA-K azanium;cerium(3+);phosphonato phosphate Chemical compound [NH4+].[Ce+3].[O-]P([O-])(=O)OP([O-])([O-])=O PTPCOFYZPRTMPE-UHFFFAOYSA-K 0.000 abstract 1
- ZEDZJUDTPVFRNB-UHFFFAOYSA-K cerium(3+);triiodide Chemical compound I[Ce](I)I ZEDZJUDTPVFRNB-UHFFFAOYSA-K 0.000 abstract 1
- OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- 229920001567 vinyl ester resin Polymers 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F261/00—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00
- C08F261/02—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols
- C08F261/04—Macromolecular compounds obtained by polymerising monomers on to polymers of oxygen-containing monomers as defined in group C08F16/00 on to polymers of unsaturated alcohols on to polymers of vinyl alcohol
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP45067202A JPS4838789B1 (enExample) | 1970-07-31 | 1970-07-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1365557A true GB1365557A (en) | 1974-09-04 |
Family
ID=13338070
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3521271A Expired GB1365557A (en) | 1970-07-31 | 1971-07-27 | Process for preparing graft copolymer emulsions |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3755234A (enExample) |
| JP (1) | JPS4838789B1 (enExample) |
| DE (1) | DE2138202A1 (enExample) |
| FR (1) | FR2099404A5 (enExample) |
| GB (1) | GB1365557A (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3839081A (en) * | 1973-08-22 | 1974-10-01 | American Cyanamid Co | Acrylic fiber having a high water absorbency and a wool-like hand and process therefore |
| US4002589A (en) * | 1975-01-13 | 1977-01-11 | Calgon Corporation | Preparation of water soluble segmented polymers |
| DE2620738C2 (de) * | 1976-05-11 | 1983-04-28 | Wacker-Chemie GmbH, 8000 München | Verfahren zur Herstellung wäßriger Copolymerdispersionen und deren Verwendung in Vermischung mit sauren, wasserlöslichen Härtezusätzen für Klebemittel |
| US4296175A (en) * | 1979-02-21 | 1981-10-20 | American Cyanamid Company | Hollow acrylonitrile polymer fiber |
| JPS61124088U (enExample) * | 1985-01-22 | 1986-08-05 | ||
| JP2609895B2 (ja) * | 1988-03-11 | 1997-05-14 | 荒川化学工業株式会社 | 感熱記録体用オーバーコート剤 |
| EP0561507A1 (en) * | 1992-03-16 | 1993-09-22 | Mizu Systems, Inc. | Method for grafting preformed hydrophilic polymers onto hydrophobic polymer substrates |
| JP2639770B2 (ja) * | 1992-09-09 | 1997-08-13 | 信越化学工業株式会社 | ポリビニルアルコール系グラフト共重合体 |
| JP3426358B2 (ja) * | 1994-07-19 | 2003-07-14 | 日本合成化学工業株式会社 | ポリビニルアルコール系樹脂微粒子の製造法 |
| US5563187A (en) * | 1995-02-16 | 1996-10-08 | Rohm And Haas Company | Grafted polymer composition |
| US5814374A (en) * | 1996-06-19 | 1998-09-29 | Rohm And Haas Company | Low VOC aqueous coating composition |
| EP1634051A4 (en) * | 2003-05-28 | 2009-03-25 | Univ Auburn | SOFTMAKER-FREE COPOLYMERS COMPRISING ION WELDING SENSORS |
| DE102004013391A1 (de) * | 2004-03-17 | 2005-10-06 | Basf Ag | Cer-Verbindungen als Initiatoren für die Dual-Cure Härtung |
| DE102004013389A1 (de) * | 2004-03-17 | 2005-10-06 | Basf Ag | Cer-Verbindungen als Initiatoren für die thermische Härtung |
| KR100830909B1 (ko) * | 2007-04-27 | 2008-05-22 | (주)영우켐텍 | 아크릴산 에스테르 공중합체 조성물 및 재분산성 분말 |
| JP5460608B2 (ja) * | 2007-11-30 | 2014-04-02 | ヒューレット−パッカード デベロップメント カンパニー エル．ピー． | 立体安定化ラテックス粒子 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2922768A (en) * | 1956-04-12 | 1960-01-26 | Mino Guido | Process for polymerization of a vinylidene monomer in the presence of a ceric salt and an organic reducing agent |
-
1970
- 1970-07-31 JP JP45067202A patent/JPS4838789B1/ja active Pending
-
1971
- 1971-07-27 US US00166567A patent/US3755234A/en not_active Expired - Lifetime
- 1971-07-27 GB GB3521271A patent/GB1365557A/en not_active Expired
- 1971-07-30 DE DE19712138202 patent/DE2138202A1/de active Pending
- 1971-07-30 FR FR7128120A patent/FR2099404A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4838789B1 (enExample) | 1973-11-20 |
| DE2138202A1 (de) | 1972-02-10 |
| US3755234A (en) | 1973-08-28 |
| FR2099404A5 (enExample) | 1972-03-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1365557A (en) | Process for preparing graft copolymer emulsions | |
| US4265796A (en) | Preparation of aqueous polyacrylate dispersions having improved flow characteristics | |
| US4371659A (en) | Preparation of aqueous polymer dispersions having a polymer content of up to 75% by weight | |
| GB1438449A (en) | Preparation of aqueous polymer emulsions | |
| KR890006776A (ko) | 저분자량 중합 첨가제 함유 접착 조성물 | |
| US2842492A (en) | Process for increasing the yield of oil upon the flooding with water of oil deposits | |
| GB1245498A (en) | Process for the production of aqueous polymer dispersions which are substantially free from residual monomer | |
| US3431226A (en) | Acrylic polymer emulsions | |
| KR860001139A (ko) | 방사선 중합성 혼합물 | |
| GB605517A (en) | A process for the manufacture of co-polymerisation products | |
| KR910009752A (ko) | (메트)아크릴산의 에스테르 및 분지쇄 카르복실산의 비닐 에스테르로 부터의 공중합체 락텍스 | |
| GB1182149A (en) | Polymer Composition. | |
| US3198775A (en) | Copolymers having improved optical clarity | |
| EP0255363B1 (en) | Terpolymer emulsions | |
| JPS6261048B2 (enExample) | ||
| US4048192A (en) | Water-dilutable tetrapolymers of vinyl acetate, maleic diesters, crotonic acid and hydrophilic unsaturated copolymerizable esters | |
| ATE14889T1 (de) | Verfahren zur herstellung von waessrigen polyacrylat-dispersionen mit verbessertem fliessverhalten. | |
| AU597526B2 (en) | Modified terpolymer emulsions | |
| US3449282A (en) | Method of preparing polymer emulsion using nonionic phosphate triester surfactant | |
| US4452949A (en) | Water-soluble partially saponified copolymers based on vinyl acetate and methyl acrylate and their use for delaying the polymerization of styrene | |
| JPS5571747A (en) | Aqueous dispersion composition for coating | |
| JPS6040445B2 (ja) | ポリ酢酸ビニル系エマルジヨンの製造方法 | |
| JPS6039686B2 (ja) | 乳化重合体の製造法 | |
| GB1050664A (enExample) | ||
| GB1415060A (en) | Method for polymerizing n-alkyl-n-arylaminoethyl esters of acrylic acid and acrylic acid derivatives |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |