GB1318377A - Carbon fibres and process for their production - Google Patents
Carbon fibres and process for their productionInfo
- Publication number
- GB1318377A GB1318377A GB4137870A GB4137870A GB1318377A GB 1318377 A GB1318377 A GB 1318377A GB 4137870 A GB4137870 A GB 4137870A GB 4137870 A GB4137870 A GB 4137870A GB 1318377 A GB1318377 A GB 1318377A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibre
- copolymer
- carbon
- aug
- units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
- D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/16—Monomers containing no hetero atoms other than the ether oxygen
- C08F216/18—Acyclic compounds
- C08F216/20—Monomers containing three or more carbon atoms in the unsaturated aliphatic radical
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
Abstract
1318377 Carbon fibres TORAY INDUSTRIES Inc 27 Aug 1970 [28 Aug 1969] 41378/70 Heading C1A [Also in Divisions C2 and C3] Carbon fibre products are obtained by heattreating a fibre of a copolymer comprising from 80-99À95 mol per cent of units of acrylonitrile and from 0À05 to 20 mol per cent of units of a hydroxymethyl vinyl aromatic compound of the formula wherein X is an optionally substituted phenyl or naphthyl group and R is H or an alkyl, aryl, cycloalkyl or aralkyl group having up to 12 carbon atoms. The compound of the above formula is preferably #-methylene phenethyl alcohol or a ring-substituted derivative thereof. A third vinyl comonomer (e.g. sodium allylsulphonate) may optionally be included in the copolymer. Heat-treatment of the copolymer fibre is effected at not less than 700‹ C., preferably 1000-1800‹ C.; to obtain graphite fibres, temperatures of 2500-3300‹ C. are used. In a preferred procedure, the fibre is first heated at 150-350‹ C. in air or oxygen (to oxidize the fibre) or in sulphurous acid gas (to sulphurize the fibre) or in nitrogen monoxide (to nitrosate the fibre), and then at 700‹ C. or above under reduced pressure in a non-oxidizing atmosphere (e.g. nitrogen, argon or hydrogen) or in an acidic atmosphere (e.g. hydrogen chloride gas).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6759769 | 1969-08-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1318377A true GB1318377A (en) | 1973-05-31 |
Family
ID=13349470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4137870A Expired GB1318377A (en) | 1969-08-28 | 1970-08-27 | Carbon fibres and process for their production |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE2042358B2 (en) |
FR (1) | FR2059389A5 (en) |
GB (1) | GB1318377A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11180869B2 (en) | 2016-03-22 | 2021-11-23 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Melt spinnable copolymers from polyacrylonitrile, method for producing fibers or fiber precursors by means of melt spinning, and fibers produced accordingly |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU3365400A (en) * | 1999-02-22 | 2000-09-14 | Standard Oil Company, The | Carbon fibers or sheets made from copolymers of acrylonitrile |
DE102014219707A1 (en) * | 2014-09-29 | 2016-03-31 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Melt spinnable copolymers of polyacrylonitrile, process for producing fibers or fiber precursors by means of melt spinning and correspondingly produced fibers |
-
1970
- 1970-08-26 DE DE19702042358 patent/DE2042358B2/en active Granted
- 1970-08-27 GB GB4137870A patent/GB1318377A/en not_active Expired
- 1970-08-28 FR FR7031546A patent/FR2059389A5/fr not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11180869B2 (en) | 2016-03-22 | 2021-11-23 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Melt spinnable copolymers from polyacrylonitrile, method for producing fibers or fiber precursors by means of melt spinning, and fibers produced accordingly |
Also Published As
Publication number | Publication date |
---|---|
DE2042358A1 (en) | 1971-04-22 |
DE2042358B2 (en) | 1973-07-12 |
FR2059389A5 (en) | 1971-05-28 |
DE2042358C3 (en) | 1974-02-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |