GB1218093A - Process for modifying glass and other bodies - Google Patents
Process for modifying glass and other bodiesInfo
- Publication number
- GB1218093A GB1218093A GB638868A GB638868A GB1218093A GB 1218093 A GB1218093 A GB 1218093A GB 638868 A GB638868 A GB 638868A GB 638868 A GB638868 A GB 638868A GB 1218093 A GB1218093 A GB 1218093A
- Authority
- GB
- United Kingdom
- Prior art keywords
- medium
- regenerator
- ions
- substance
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
- C03C21/001—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
1,218,093. Chemical-tempering of vitreous materials. GLAVERBEL. 8 Feb., 1968 [25 April, 1967; 30 Aug., 1967], No. 6388/68. Heading C1M. A process for modifying a physical and/or chemical property of a body of glass, vitrocrystalline or ceramic material, comprises an ion-exchange between the body and a contacting medium which is itself in contact with a regenerator material present as a separate phase and composed so that ions entering the medium from the article are taken up by the regenerator material in exchange for further amounts of ions which diffuse into the body. The medium may be gaseous in contact with a solid regenerator or it may be in a liquid state, e.g. a bath of molten salts with the regenerator material present as a disperse phase in the medium. The regenerator is advantageously significantly heavier or lighter in density than the medium and is maintained in dispersed condition by agitation of the medium. The regenerator preferably captures and releases ions more readily than the material of the body. The regenerator may be a natural mineral or glass, or ion-exchange material charged or enriched with ions which are to diffuse into the body, particularly clays, silicates, borates, vitreous and non-vitreous aluminosilicates and solid gels capable of fixing protons or alkali metal ions. At least one substance called an adjuvant which weakens the diffusion barrier at the interface between the body and medium is preferably present in the medium. The adjuvant, or part thereof, can be incorporated in the regenerator material. Different degrees of modification can be achieved wherein portions of the medium in contact with different zones of the body are separated and an adjuvant is present in one or more but not all of the portions and/or is present in different concentrations in the different portions. The adjuvant may be a halogen, an alkaline earth metal or salt containing an anion which is not present in the material undergoing treatment, a substance which functions as an acceptor of oxygen ions, e.g. CO 2 , NO 2 <SP>+</SP>, S 2 O 7 <SP>2-</SP>, Cr 2 O 7 <SP>2</SP>-, PO 3 -, a substance having an acid function, e.g. SO 4 <SP>2-</SP>, PO 4 <SP>2-</SP>, aromatic organic compounds such as polyphenylene oxides and polysulphones, a substance which gives rise to the formation of complexes, e.g. [FeM(CN) 5 ]Li, where M is a substituted monovalent ion migrating from the article, e.g. K +or Na<SP>+</SP>. The diffusion barrier can also be reduced by incorporating in the medium a substance which modifies the valency state of ions of the or at least one element which migrates from article, e.g. oxides, cyanides and chromates; this can be assisted by generating an electric field. Specific examples of treatments and temperatures are given. In the examples sheets of soda-lime glass, and a glass comprising in per cent by weight SiO 2 : 70, Na 2 O: 14, CaO: 13, Al 2 O 3 : 3, and bottles of soda-lime borosilicate glass are treated. A vitro-crystalline sheet comprising SiO 2 : 42À3, Al 2 O 3 : 31À2, Na 2 O: 10À4, K 2 O: 6À2, CaO: 1À8, TiO 2 : 7À4, As 2 O 3 : 0À7% by weight is also treated.
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB638868A GB1218093A (en) | 1967-04-25 | 1968-02-08 | Process for modifying glass and other bodies |
IL2961768A IL29617A (en) | 1967-08-30 | 1968-03-11 | Ion exchange process for modifying physical and/or chemical properties of glass and product obtained thereby |
CH361968A CH490287A (en) | 1967-04-25 | 1968-03-12 | Process for subjecting a body of glass, vitrocrystalline material, ceramic or rock to ion exchange |
BE712091D BE712091A (en) | 1967-04-25 | 1968-03-13 | |
NL6803908A NL6803908A (en) | 1967-04-25 | 1968-03-19 | |
FR1581492D FR1581492A (en) | 1967-04-25 | 1968-03-26 | |
AT352968A AT288622B (en) | 1967-04-25 | 1968-04-10 | Method for modifying a physical and / or chemical property of a body made of glass, vitro-crystalline material, ceramic or rock |
FI107068A FI49148C (en) | 1967-04-25 | 1968-04-18 | Method for modifying the physical and / or chemical properties of glass, translucent or ceramic articles. |
NO154668A NO123238B (en) | 1967-04-25 | 1968-04-23 | |
SE550368A SE351415B (en) | 1967-04-25 | 1968-04-24 | |
DE19681771232 DE1771232C3 (en) | 1967-04-25 | 1968-04-24 | Process for the exchange of ions between a molten salt and glass, glass ceramic or ceramic for the purpose of changing their properties |
YU97468A YU32540B (en) | 1967-04-25 | 1968-04-24 | Postopek za modifikacijo fizikalne in/ali kemicne lastnosti navadnega stekla ali steklasto-kristalnega materiala |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
LU53514 | 1967-04-25 | ||
LU54402 | 1967-08-30 | ||
GB638868A GB1218093A (en) | 1967-04-25 | 1968-02-08 | Process for modifying glass and other bodies |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1218093A true GB1218093A (en) | 1971-01-06 |
Family
ID=27254819
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB638868A Expired GB1218093A (en) | 1967-04-25 | 1968-02-08 | Process for modifying glass and other bodies |
Country Status (11)
Country | Link |
---|---|
AT (1) | AT288622B (en) |
BE (1) | BE712091A (en) |
CH (1) | CH490287A (en) |
DE (1) | DE1771232C3 (en) |
FI (1) | FI49148C (en) |
FR (1) | FR1581492A (en) |
GB (1) | GB1218093A (en) |
NL (1) | NL6803908A (en) |
NO (1) | NO123238B (en) |
SE (1) | SE351415B (en) |
YU (1) | YU32540B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1361599A1 (en) * | 2002-01-22 | 2003-11-12 | Asahi Glass Company Ltd. | Glass bulb for cathode ray tube and method for manufacturing the same |
EP1376647A2 (en) * | 2002-06-24 | 2004-01-02 | Asahi Glass Company Ltd. | Glas funnel for a cathode ray tube and process for its production |
US8919150B2 (en) | 2011-09-09 | 2014-12-30 | Hoya Corporation | Method of manufacturing an ion-exchanged glass article |
US11034613B2 (en) * | 2017-11-21 | 2021-06-15 | Corning Incorporated | Methods for ion exchanging glass articles |
WO2024040686A1 (en) * | 2022-08-25 | 2024-02-29 | 北京大学深圳研究生院 | Mother glass, and cyclic utilization method and system for alkali metal element in mother glass |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005023753B4 (en) * | 2004-06-03 | 2008-01-24 | Ceramtec Ag Innovative Ceramic Engineering | Use of a molten salt for the surface hardening of a SiAION ceramic |
LU102047B1 (en) | 2020-09-03 | 2022-03-03 | Univ Freiberg Tech Bergakademie | Regeneration material for regenerating a molten salt used for a glass hardening and/or glass strengthening process |
LU102042B1 (en) | 2020-09-03 | 2022-03-03 | 2Mh Glas Gmbh | Apparatus and method for tempering and/or strengthening glass objects |
LU500467B1 (en) | 2021-07-23 | 2023-01-23 | Univ Freiberg Tech Bergakademie | Method and device for tempering and/or strengthening glass objects |
LU500468B1 (en) | 2021-07-23 | 2023-01-23 | Univ Freiberg Tech Bergakademie | Plant and method for tempering and/or strengthening glass objects |
LU500469B1 (en) | 2021-07-23 | 2023-01-23 | Univ Freiberg Tech Bergakademie | Method for regenerating a molten salt for a glass tempering and/or glass strengthening process |
-
1968
- 1968-02-08 GB GB638868A patent/GB1218093A/en not_active Expired
- 1968-03-12 CH CH361968A patent/CH490287A/en not_active IP Right Cessation
- 1968-03-13 BE BE712091D patent/BE712091A/xx unknown
- 1968-03-19 NL NL6803908A patent/NL6803908A/xx not_active Application Discontinuation
- 1968-03-26 FR FR1581492D patent/FR1581492A/fr not_active Expired
- 1968-04-10 AT AT352968A patent/AT288622B/en not_active IP Right Cessation
- 1968-04-18 FI FI107068A patent/FI49148C/en active
- 1968-04-23 NO NO154668A patent/NO123238B/no unknown
- 1968-04-24 YU YU97468A patent/YU32540B/en unknown
- 1968-04-24 SE SE550368A patent/SE351415B/xx unknown
- 1968-04-24 DE DE19681771232 patent/DE1771232C3/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1361599A1 (en) * | 2002-01-22 | 2003-11-12 | Asahi Glass Company Ltd. | Glass bulb for cathode ray tube and method for manufacturing the same |
EP1361599A4 (en) * | 2002-01-22 | 2006-11-22 | Asahi Glass Co Ltd | Glass bulb for cathode ray tube and method for manufacturing the same |
EP1376647A2 (en) * | 2002-06-24 | 2004-01-02 | Asahi Glass Company Ltd. | Glas funnel for a cathode ray tube and process for its production |
EP1376647A3 (en) * | 2002-06-24 | 2004-01-14 | Asahi Glass Company Ltd. | Glas funnel for a cathode ray tube and process for its production |
US8919150B2 (en) | 2011-09-09 | 2014-12-30 | Hoya Corporation | Method of manufacturing an ion-exchanged glass article |
US11034613B2 (en) * | 2017-11-21 | 2021-06-15 | Corning Incorporated | Methods for ion exchanging glass articles |
WO2024040686A1 (en) * | 2022-08-25 | 2024-02-29 | 北京大学深圳研究生院 | Mother glass, and cyclic utilization method and system for alkali metal element in mother glass |
Also Published As
Publication number | Publication date |
---|---|
DE1771232B2 (en) | 1977-09-08 |
NL6803908A (en) | 1968-10-28 |
YU97468A (en) | 1974-08-31 |
CH490287A (en) | 1970-05-15 |
NO123238B (en) | 1971-10-18 |
DE1771232C3 (en) | 1978-05-03 |
FI49148C (en) | 1975-04-10 |
FI49148B (en) | 1974-12-31 |
SE351415B (en) | 1972-11-27 |
DE1771232A1 (en) | 1971-12-23 |
BE712091A (en) | 1968-07-15 |
AT288622B (en) | 1971-03-10 |
FR1581492A (en) | 1969-09-19 |
YU32540B (en) | 1975-02-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
435 | Patent endorsed 'licences of right' on the date specified (sect. 35/1949) | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |