GB1096356A - Strengthened glass article and method of production - Google Patents
Strengthened glass article and method of productionInfo
- Publication number
- GB1096356A GB1096356A GB5305865A GB5305865A GB1096356A GB 1096356 A GB1096356 A GB 1096356A GB 5305865 A GB5305865 A GB 5305865A GB 5305865 A GB5305865 A GB 5305865A GB 1096356 A GB1096356 A GB 1096356A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- glass
- surface layer
- salt
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000006058 strengthened glass Substances 0.000 title 1
- 239000011521 glass Substances 0.000 abstract 5
- 239000002344 surface layer Substances 0.000 abstract 4
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 3
- 150000002500 ions Chemical class 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- GOLCXWYRSKYTSP-UHFFFAOYSA-N Arsenious Acid Chemical compound O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 abstract 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 abstract 1
- 229910001416 lithium ion Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000006132 parent glass Substances 0.000 abstract 1
- 230000008707 rearrangement Effects 0.000 abstract 1
- 239000005368 silicate glass Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C21/00—Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
To strengthen a glass article formed from a parent alkali metal silicate glass in which the primary alkali metal ion has a radius larger than the lithium ion, an encasing surface layer differing in molecular structure is formed by contacting the surface with a salt of an alkali metal of relatively smaller alkali metal ion at a temperature above the strain point of the glass and thereafter exchanging a portion of the smaller ions from the surface layer with ions of larger ionic radius without rearrangement of the glass structure. The second part of the process may be effected either by heating so that alkali metal ions from the parent inner structure diffuse into the surface layer or by contacting the surface layer with a further molten bath of a salt of the larger ion such as an alkali metal or silver salt, both processes being at a temperature below the strain point of the glass. Preferably the first ion exchange is effected with a Li salt and the examples give the parent glass as within the following ranges in percentages by weight: SiO2 45-80; Na2O and/or K2O 5-25; Al2O3 and/or ZrO2 5-25; and optionally P2O5 2-20; and the following up to 5, Li2O; unspecified alkali metal oxides; unspecified alkaline earth oxides; Sb2O3, As2O3, PbO, TiO2. A number of examples of glasses, compositions of treating baths and temperature and time schedules are given.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41930864A | 1964-12-18 | 1964-12-18 | |
| US41955064A | 1964-12-18 | 1964-12-18 | |
| US419307A US3395998A (en) | 1964-12-18 | 1964-12-18 | Method for production of glass article having increased mechanical strength |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1096356A true GB1096356A (en) | 1967-12-29 |
Family
ID=27411226
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5305865A Expired GB1096356A (en) | 1964-12-18 | 1965-12-14 | Strengthened glass article and method of production |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE673866A (en) |
| DE (1) | DE1496470B2 (en) |
| ES (1) | ES320825A1 (en) |
| FR (1) | FR1498273A (en) |
| GB (1) | GB1096356A (en) |
| NL (1) | NL136096C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2012375A1 (en) * | 1968-07-05 | 1970-03-20 | Nippon Selfoc Co Ltd | |
| EP2762460A4 (en) * | 2011-09-29 | 2015-10-28 | Central Glass Co Ltd | Chemically strengthened glass plate and method for manufacturing same |
-
1965
- 1965-12-14 GB GB5305865A patent/GB1096356A/en not_active Expired
- 1965-12-15 FR FR42389A patent/FR1498273A/en not_active Expired
- 1965-12-16 ES ES0320825A patent/ES320825A1/en not_active Expired
- 1965-12-16 BE BE673866D patent/BE673866A/xx unknown
- 1965-12-17 DE DE19651496470 patent/DE1496470B2/en active Pending
- 1965-12-17 NL NL6516495A patent/NL136096C/xx active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2012375A1 (en) * | 1968-07-05 | 1970-03-20 | Nippon Selfoc Co Ltd | |
| EP2762460A4 (en) * | 2011-09-29 | 2015-10-28 | Central Glass Co Ltd | Chemically strengthened glass plate and method for manufacturing same |
| US9206079B2 (en) | 2011-09-29 | 2015-12-08 | Central Glass Company, Limited | Chemically strengthened glass plate and method for manufacturing same |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1498273A (en) | 1967-10-20 |
| NL136096C (en) | 1973-01-15 |
| BE673866A (en) | 1966-06-16 |
| NL6516495A (en) | 1966-06-20 |
| DE1496470A1 (en) | 1969-07-10 |
| DE1496470B2 (en) | 1971-07-29 |
| ES320825A1 (en) | 1966-09-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2779136A (en) | Method of making a glass article of high mechanical strength and article made thereby | |
| GB1292539A (en) | Method of strengthening a silicate glass article | |
| GB1076602A (en) | Glass articles having surface compressive stress | |
| US3607172A (en) | Tripotassium phosphate treatment for strengthening glass | |
| ES354347A1 (en) | Method for thermochemical strengthening of glass articles | |
| GB970463A (en) | Glass-ceramic article and method of making it | |
| GB1115972A (en) | Strengthened glass articles | |
| GB1076894A (en) | Method of strengthening glassware | |
| GB1322228A (en) | Method of strengthening a glass article and a strengthened glass article | |
| GB1181581A (en) | Process for Treating Glass | |
| GB1346747A (en) | Method for strengthening glass by ion exchange | |
| GB1220292A (en) | Process for tempering vitreous and vitro-crystalline bodies | |
| GB955437A (en) | Process for manufacturing ceramic-like products from glass by microscopic crystallization | |
| JPS60180936A (en) | Production of heat resistant glass product having high strength | |
| GB1026770A (en) | Glass article and method of treatment | |
| ES294612A1 (en) | Method of manufacture of glass articles of high mechanical resistance (Machine-translation by Google Translate, not legally binding) | |
| GB924996A (en) | Improvements in or relating to devitrified glass ceramies and their production | |
| US3556757A (en) | Alkali metal salt bath with alkali metal acetate additive for treatment of glasses and glass-ceramics | |
| GB1108476A (en) | Surface-devitrified glasses | |
| US3356477A (en) | Method of increasing stain resistance of a glass body subjected to an ion exchange strengthening set-up | |
| GB1005335A (en) | Phototropic glass article and method of making it | |
| GB1096356A (en) | Strengthened glass article and method of production | |
| GB1021998A (en) | Improvements in or relating to enameling frit compositions | |
| US3661545A (en) | Method for treating a molten salt with water vapor | |
| GB1069357A (en) | Glass |