GB1181376A - Electrodeposition of Nickel - Google Patents

Electrodeposition of Nickel

Info

Publication number
GB1181376A
GB1181376A GB01965/67A GB1196567A GB1181376A GB 1181376 A GB1181376 A GB 1181376A GB 01965/67 A GB01965/67 A GB 01965/67A GB 1196567 A GB1196567 A GB 1196567A GB 1181376 A GB1181376 A GB 1181376A
Authority
GB
United Kingdom
Prior art keywords
nickel
bath
anode
march
electro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB01965/67A
Inventor
George Angelo Dibari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inco Ltd
Original Assignee
Inco Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inco Ltd filed Critical Inco Ltd
Publication of GB1181376A publication Critical patent/GB1181376A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/12Electroplating: Baths therefor from solutions of nickel or cobalt
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • C25D17/12Shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60Electroplating characterised by the structure or texture of the layers
    • C25D5/605Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611Smooth layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Nozzles (AREA)

Abstract

1,181,376. Electro-depositing nickel. INTERNATIONAL NICKEL Ltd. March 14, 1967 [March 24, 1966], No.11965/67. Heading C7B. Bright nickel is electro-deposited from an aqueous bath containing 50-140 g/1 Ni as nickel sulphamate, 0À3-1À5 g/1 Co, 0-10 g/1 S04 ion, 0-5 g/1 Cl ion and 30-40 g/1 H 3 BO 3 as a buffer, and having a pH of 3À5-4À5 and a temperature of 49-60‹C. The cathode current density is 5-100 A.S.F. and the bath is subjected to anodic oxidation with a subsidiary polarized insoluble anode, e.g. of C, Pt, platinized Ti or Ta, through which at least 2À 5% and preferably not more than 6% of the total plating current passes, to liberate oxygen from the electrolyte. The Co concentration can be maintained by periodically adding cobalt sulphamate to the bath, passing a proportion of the total plating current e.g. 1-10% through a separate anode of pure Co placed in the bath, or using an active Ni plating anode containing 1-10% Co and 0À01-0À03% S. The content of Co in the deposit may range from 6À53 to 19À6%
GB01965/67A 1966-03-24 1967-03-14 Electrodeposition of Nickel Expired GB1181376A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US53696566A 1966-03-24 1966-03-24

Publications (1)

Publication Number Publication Date
GB1181376A true GB1181376A (en) 1970-02-18

Family

ID=24140646

Family Applications (1)

Application Number Title Priority Date Filing Date
GB01965/67A Expired GB1181376A (en) 1966-03-24 1967-03-14 Electrodeposition of Nickel

Country Status (9)

Country Link
AT (1) AT267993B (en)
BE (1) BE696059A (en)
CH (1) CH466660A (en)
DE (1) DE1621089A1 (en)
ES (1) ES338396A1 (en)
FR (1) FR1515508A (en)
GB (1) GB1181376A (en)
NL (1) NL6704050A (en)
NO (1) NO117772B (en)

Also Published As

Publication number Publication date
CH466660A (en) 1968-12-15
FR1515508A (en) 1968-03-01
NO117772B (en) 1969-09-22
DE1621089A1 (en) 1971-04-22
ES338396A1 (en) 1968-04-01
NL6704050A (en) 1967-09-25
AT267993B (en) 1969-01-27
BE696059A (en) 1967-09-25

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