GB1149106A - Acid brilliant zinc electroplating bath - Google Patents
Acid brilliant zinc electroplating bathInfo
- Publication number
- GB1149106A GB1149106A GB24483/67A GB2448367A GB1149106A GB 1149106 A GB1149106 A GB 1149106A GB 24483/67 A GB24483/67 A GB 24483/67A GB 2448367 A GB2448367 A GB 2448367A GB 1149106 A GB1149106 A GB 1149106A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- zinc
- geldbach
- compound
- chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
1,149,106. Bright zinc electro-plating baths. I. GELDBACH, A. GELDBACH, U. GELDBACH and S. GELDBACH [trading as FIRMA DR. -ING. MAX SCHLÍTTER FABRIK FUR GALVANOTECHNIK]. May 26, 1967 [May 28, 1966], No.24483/67. Heading C7B. An acid bright zinc electro-plating bath having good throwing power comprises an aqueous solution of at least one single zinc salt including an aromatic carbonyl or carboxylic compound, a non-ionic polyoxyethylene surfactant compound, and ammonium chloride and/or another compound capable of forming soluble complex salts with zinc salts in the pH range 2À5 to 5À5. The zinc salt may be the sulphate, chloride, acetate or fluoborate and instead of ammonium chloride per se another ammonium salt such as the sulphate or acetate may be used in combination with zinc chloride or sodium chloride. The complex-forming compound may be sodium glycerophosphate, triethanolamine, ethylenediamine or the mono- or di sodium salt of E. D. T. A. The aromatic carbonyl or carboxylic compound may be cinnamaldehyde, m -hydroxybenzaldehyde, acetophenone benzophenone, benzal acetone, bensoic acid, cinnamic acid, salicylic acid, phenylpropiolic acid, benzoyl acetic acid or its ethyl ester, or o-coumaric acid. The non-ionic surfactant preferably includes at least 6 ethylene oxide molecules condensed with a long chain (C 6 or more) fatty alcohol, acid, or amine or an alkylphenol. To provide water solubility the surfactant should include 10 or more ethylene oxide moles and one example relates to a condensation product of tributyl phenol with 50 moles ethylene oxide. Typical bath temperatures used are 15 to 30C. providing a bright deposit current density range of 1 to 5 amps/ sq. dm. The bright zinc layers formed may be phosphated or chromated to a colourless, bluish, yellow, brown or olive finish.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DESC039046 | 1966-05-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1149106A true GB1149106A (en) | 1969-04-16 |
Family
ID=7434969
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24483/67A Expired GB1149106A (en) | 1966-05-28 | 1967-05-26 | Acid brilliant zinc electroplating bath |
Country Status (8)
Country | Link |
---|---|
US (1) | USRE27999E (en) |
AT (1) | AT268807B (en) |
BE (1) | BE699085A (en) |
CH (1) | CH488814A (en) |
DE (1) | DE1521029C3 (en) |
GB (1) | GB1149106A (en) |
NL (1) | NL149237B (en) |
SE (1) | SE342262B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3669854A (en) * | 1970-08-03 | 1972-06-13 | M & T Chemicals Inc | Zinc electroplating electrolyte and process |
US3729394A (en) * | 1972-04-17 | 1973-04-24 | Conversion Chem Corp | Composition and method for electrodeposition of zinc |
JPS5029699B1 (en) * | 1971-06-18 | 1975-09-25 | ||
US4496439A (en) * | 1982-12-29 | 1985-01-29 | Basf Aktiengesellschaft | Acidic zinc-plating bath |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1919305C3 (en) * | 1969-04-12 | 1981-04-30 | Schering Ag Berlin Und Bergkamen, 1000 Berlin | Acid electrolytic bright zinc bath containing no organic complexing agents |
DE2111602C2 (en) * | 1970-03-18 | 1982-07-01 | The Udylite Corp., Detroit, Mich. | Cyanide-free aqueous galvanic bright zinc bath and method for the galvanic deposition of bright zinc using this bath |
US4138294A (en) | 1977-12-06 | 1979-02-06 | M&T Chemicals Inc. | Acid zinc electroplating process and composition |
US4137133A (en) | 1977-12-15 | 1979-01-30 | M&T Chemicals Inc. | Acid zinc electroplating process and composition |
JPS6012434B2 (en) * | 1981-08-21 | 1985-04-01 | 荏原ユ−ジライト株式会社 | Zinc-nickel alloy electroplating solution |
JPS58502221A (en) * | 1981-12-28 | 1983-12-22 | ザ ボ−イング コンパニ− | Manufacturing method of zinc-nickel electroplating |
DE4119341A1 (en) * | 1991-06-12 | 1992-12-17 | Basf Ag | METHOD FOR THE PRODUCTION OF GLAZING PLATED OR WITH ZINC ALLOYED TOOLS |
DE4446329A1 (en) | 1994-12-23 | 1996-06-27 | Basf Ag | Salts of aromatic hydroxyl compounds and their use as brighteners |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE731835C (en) * | 1941-07-20 | 1943-02-16 | Hoesch Ag | Acid galvanic zinc baths for the deposition of a high-quality, shiny zinc coating |
GB602591A (en) * | 1945-02-12 | 1948-05-31 | Du Pont | Improvements in or relating to the electro-deposition of metals |
-
1966
- 1966-05-28 DE DE1521029A patent/DE1521029C3/en not_active Expired
-
1967
- 1967-05-18 NL NL676706919A patent/NL149237B/en not_active IP Right Cessation
- 1967-05-23 CH CH721767A patent/CH488814A/en not_active IP Right Cessation
- 1967-05-23 AT AT479767A patent/AT268807B/en active
- 1967-05-24 SE SE7305/67A patent/SE342262B/xx unknown
- 1967-05-26 BE BE699085A patent/BE699085A/xx unknown
- 1967-05-26 GB GB24483/67A patent/GB1149106A/en not_active Expired
-
1973
- 1973-04-25 US US35445673 patent/USRE27999E/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3669854A (en) * | 1970-08-03 | 1972-06-13 | M & T Chemicals Inc | Zinc electroplating electrolyte and process |
JPS5029699B1 (en) * | 1971-06-18 | 1975-09-25 | ||
US3729394A (en) * | 1972-04-17 | 1973-04-24 | Conversion Chem Corp | Composition and method for electrodeposition of zinc |
US4496439A (en) * | 1982-12-29 | 1985-01-29 | Basf Aktiengesellschaft | Acidic zinc-plating bath |
Also Published As
Publication number | Publication date |
---|---|
CH488814A (en) | 1970-04-15 |
AT268807B (en) | 1969-02-25 |
DE1521029A1 (en) | 1969-07-24 |
NL6706919A (en) | 1967-11-29 |
DE1521029C3 (en) | 1984-01-19 |
USRE27999E (en) | 1974-04-30 |
SE342262B (en) | 1972-01-31 |
BE699085A (en) | 1967-11-03 |
DE1521029B2 (en) | 1974-05-16 |
NL149237B (en) | 1976-04-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1149106A (en) | Acid brilliant zinc electroplating bath | |
GB736145A (en) | Method of improving corrosion resistance of zinc | |
GB1469986A (en) | Chromium salt compositions and to a process for their production | |
GB1160314A (en) | Acidified Hydrogen Peroxide Solutions for Dissolving Metals | |
GB718574A (en) | Bath for the deposit of gold alloys by electroplating | |
GB367587A (en) | Improvements in or relating to the electro-deposition of palladium | |
GB1224507A (en) | Electrodepositing a pink gold alloy | |
GB641435A (en) | Aldonate compositions and method for the production thereof | |
GB1179017A (en) | Improvements in or relating to Gold Electroplating | |
ES382607A1 (en) | Electrodeposition of gold and gold alloys | |
US3694330A (en) | Electroplating bath for depositing bright zinc plates | |
GB1111091A (en) | Improvements in or relating to electroplating | |
GB1327303A (en) | Acidic zinc electroplating bath | |
GB1234793A (en) | Brightening and hardening additive for electrolytic silvering baths | |
GB1285256A (en) | Improvements in or relating to zinc electroplating baths | |
ES336414A1 (en) | Acid zinc electrodepositing | |
GB998279A (en) | Improvements in zinc electroplating with brightener compositions for cyanide baths | |
GB1212536A (en) | Improvements in or relating to bright zinc electroplating | |
GB1180299A (en) | A Method for Producing Corrosion-Preventing Protective Layers on Bodies of Aluminium or Aluminium Alloys by Anodising in Acid Baths | |
ES393019A1 (en) | Acidic zinc plating electrolytes | |
GB1145619A (en) | Acid electroplating bath for depositing brilliant layers of zinc | |
GB1200110A (en) | Electroplating of smooth, semi-bright gold deposits | |
ES356925A1 (en) | Coating of Iron or Iron Alloys | |
GB1125165A (en) | Bright silver electroplating bath | |
GB1149011A (en) | Improvements in or relating to the electro-deposition of stainless steel coatings onthe surfaces of metals |