GB1140649A - Process for the polymerization and the copolymerization of olefines - Google Patents
Process for the polymerization and the copolymerization of olefinesInfo
- Publication number
- GB1140649A GB1140649A GB4724967A GB4724967A GB1140649A GB 1140649 A GB1140649 A GB 1140649A GB 4724967 A GB4724967 A GB 4724967A GB 4724967 A GB4724967 A GB 4724967A GB 1140649 A GB1140649 A GB 1140649A
- Authority
- GB
- United Kingdom
- Prior art keywords
- magnesium
- polymers
- acid
- solution
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007334 copolymerization reaction Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 6
- 229910052749 magnesium Inorganic materials 0.000 abstract 6
- 239000011777 magnesium Substances 0.000 abstract 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 5
- 229920000642 polymer Polymers 0.000 abstract 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 229920002125 Sokalan® Polymers 0.000 abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 abstract 2
- 239000011654 magnesium acetate Substances 0.000 abstract 2
- 229940069446 magnesium acetate Drugs 0.000 abstract 2
- 235000011285 magnesium acetate Nutrition 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 239000004584 polyacrylic acid Substances 0.000 abstract 2
- 230000000379 polymerizing effect Effects 0.000 abstract 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 abstract 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical class OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- 229920002521 macromolecule Polymers 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 150000002688 maleic acid derivatives Chemical class 0.000 abstract 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011343 solid material Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003623 transition metal compounds Chemical class 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Chemically Coating (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR81066A FR1516800A (fr) | 1966-10-21 | 1966-10-21 | Procédé de polymérisation et copolymérisation d'oléfines. |
| FR119682A FR93816E (fr) | 1966-10-21 | 1967-09-01 | Procédé de polymérisation et copolymérisation d'oléfines. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1140649A true GB1140649A (en) | 1969-01-22 |
Family
ID=26173849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4724967A Expired GB1140649A (en) | 1966-10-21 | 1967-10-17 | Process for the polymerization and the copolymerization of olefines |
Country Status (14)
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1928772A1 (de) * | 1969-06-06 | 1970-12-10 | Hoechst Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| DE2461187A1 (de) * | 1973-12-27 | 1975-07-10 | Nippon Oil Co Ltd | Verfahren zur herstellung von polyolefinen |
| US3953414A (en) | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| US3984389A (en) * | 1970-10-23 | 1976-10-05 | Solvay & Cie | Process for the polymerization of olefins and catalytic products |
| US3989879A (en) | 1971-02-25 | 1976-11-02 | Solvay & Cie | Process and catalysts for the polymerization and copolymerization of olefins |
| US3989880A (en) * | 1971-02-18 | 1976-11-02 | Solvay & Cie | Catalyst and process for the polymerization of olefins |
| US4016344A (en) | 1971-07-01 | 1977-04-05 | Gulf Research & Development Company | Olefin polymerization catalyst |
| US4021599A (en) | 1975-08-04 | 1977-05-03 | Gulf Research & Development Company | Olefin polymerization process and catalyst |
| US4022958A (en) | 1973-03-26 | 1977-05-10 | Nippon Oil Company Ltd. | Process for preparing polyolefins |
| US4027088A (en) | 1974-07-19 | 1977-05-31 | Nippon Oil Company Ltd. | Process of preparing polyolefins |
| US4056668A (en) | 1966-10-21 | 1977-11-01 | Solvay & Cie | Process for the polymerization and copolymerization of olefins with a solid support catalyst |
| US4103078A (en) | 1969-08-01 | 1978-07-25 | Chisso Corporation | Method for producing polymers of alpha-olefin |
| US4144390A (en) * | 1970-10-06 | 1979-03-13 | Solvay & Cie | Process for the polymerization of olefins and catalysts therefor |
| US4167493A (en) | 1977-03-22 | 1979-09-11 | Arco Polymers, Inc. | High efficiency catalyst for high bulk density polyethylene |
| US4247669A (en) * | 1970-06-18 | 1981-01-27 | Solvay & Cie | Process for the polymerization of olefins |
| US4262105A (en) | 1970-10-20 | 1981-04-14 | Solvay & Cie | Process for the polymerization of olefins and catalytic products |
| US4544717A (en) * | 1969-06-20 | 1985-10-01 | Montecatini Edison S.P.A. | Polymerization catalysts |
| US4613655A (en) * | 1970-07-20 | 1986-09-23 | Montedison S.P.A. | Catalysts for the polymerization of olefins |
| US5496782A (en) * | 1992-12-17 | 1996-03-05 | Solvay (Socie/ te/ Anonyme) | Catalyst system, use of this catalyst system for the (co)polymerization of olefins, process for preparing this catalyst system and olefin (co) polymerization process |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL135327C (enrdf_load_stackoverflow) * | 1968-06-20 | Solvay | ||
| DE1770730C2 (de) * | 1968-06-27 | 1982-05-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Homo- und Mischpolymerisation von Äthylen |
| US3676415A (en) * | 1968-06-27 | 1972-07-11 | Hoechst Ag | Process for polymerizing {60 -olefins |
| BG17623A3 (bg) * | 1968-06-27 | 1973-11-10 | Hoechst Aktiengesellschaft | Метод за полимеризация на алфаолефини |
| CA920299A (en) * | 1968-08-01 | 1973-01-30 | Mitsui Petrochemical Industries | Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier |
| DE1795197C2 (de) * | 1968-08-21 | 1981-08-13 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Polymerisation von -Olefinen |
| DE1795272C2 (de) * | 1968-08-31 | 1981-10-22 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Homo- und Mischpolymerisation von Äthylen |
| US3839313A (en) * | 1968-10-09 | 1974-10-01 | Montedison Spa | Catalysts for the polymerization of olefins |
| YU35844B (en) | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
| BE791676A (fr) * | 1971-12-08 | 1973-05-21 | Solvay | Procédé pour la polymérisation des oléfines |
| US3907759A (en) * | 1972-10-06 | 1975-09-23 | Nissan Chemical Ind Ltd | Catalyst for polymerization of olefins and process for polymerization of olefins with use of said catalyst |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3008943A (en) * | 1955-12-01 | 1961-11-14 | Exxon Research Engineering Co | Polymerization catalyst |
| FR1208332A (fr) * | 1957-06-07 | 1960-02-23 | Bataafsche Petroleum | Procédé de polymérisation des alpha-oléfines et préparation de catalyseurs nouveaux à cette fin |
| LU39635A1 (enrdf_load_stackoverflow) * | 1960-01-18 | |||
| AT232520B (de) * | 1960-03-01 | 1964-03-25 | Cabot Corp | Verfahren zur Herstellung von neuen Polymerisationskatalysatoren |
| US3400110A (en) * | 1963-08-01 | 1968-09-03 | Solvay | Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal |
| NL135604C (enrdf_load_stackoverflow) * | 1965-06-25 |
-
0
- NL NL137056D patent/NL137056C/xx active
-
1967
- 1967-09-01 FR FR119682A patent/FR93816E/fr not_active Expired
- 1967-09-18 GR GR670134924A patent/GR34924B/el unknown
- 1967-10-09 NO NO17004767A patent/NO130009B/no unknown
- 1967-10-09 YU YU196467A patent/YU32533B/xx unknown
- 1967-10-11 CH CH1421567A patent/CH477223A/fr not_active IP Right Cessation
- 1967-10-12 FI FI274067A patent/FI48100C/fi active
- 1967-10-16 NL NL6714024A patent/NL6714024A/xx unknown
- 1967-10-17 BE BE705220D patent/BE705220A/xx not_active IP Right Cessation
- 1967-10-17 GB GB4724967A patent/GB1140649A/en not_active Expired
- 1967-10-18 DE DE1745415A patent/DE1745415C2/de not_active Expired
- 1967-10-20 SE SE247571A patent/SE374925B/xx unknown
- 1967-10-20 SE SE1441267A patent/SE359845B/xx unknown
- 1967-10-20 DK DK523267A patent/DK125425B/da not_active IP Right Cessation
- 1967-10-20 AT AT952267A patent/AT278350B/de not_active IP Right Cessation
- 1967-10-20 ES ES346261A patent/ES346261A1/es not_active Expired
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4056668A (en) | 1966-10-21 | 1977-11-01 | Solvay & Cie | Process for the polymerization and copolymerization of olefins with a solid support catalyst |
| DE1928772A1 (de) * | 1969-06-06 | 1970-12-10 | Hoechst Ag | Verfahren zur Polymerisation von alpha-Olefinen |
| US4544717A (en) * | 1969-06-20 | 1985-10-01 | Montecatini Edison S.P.A. | Polymerization catalysts |
| US4103078A (en) | 1969-08-01 | 1978-07-25 | Chisso Corporation | Method for producing polymers of alpha-olefin |
| US4247669A (en) * | 1970-06-18 | 1981-01-27 | Solvay & Cie | Process for the polymerization of olefins |
| US4613655A (en) * | 1970-07-20 | 1986-09-23 | Montedison S.P.A. | Catalysts for the polymerization of olefins |
| US4144390A (en) * | 1970-10-06 | 1979-03-13 | Solvay & Cie | Process for the polymerization of olefins and catalysts therefor |
| US4262105A (en) | 1970-10-20 | 1981-04-14 | Solvay & Cie | Process for the polymerization of olefins and catalytic products |
| US3984389A (en) * | 1970-10-23 | 1976-10-05 | Solvay & Cie | Process for the polymerization of olefins and catalytic products |
| US3989880A (en) * | 1971-02-18 | 1976-11-02 | Solvay & Cie | Catalyst and process for the polymerization of olefins |
| US3989879A (en) | 1971-02-25 | 1976-11-02 | Solvay & Cie | Process and catalysts for the polymerization and copolymerization of olefins |
| US4016344A (en) | 1971-07-01 | 1977-04-05 | Gulf Research & Development Company | Olefin polymerization catalyst |
| US3953414A (en) | 1972-09-13 | 1976-04-27 | Montecatini Edison S.P.A., | Catalysts for the polymerization of olefins to spherically shaped polymers |
| US4022958A (en) | 1973-03-26 | 1977-05-10 | Nippon Oil Company Ltd. | Process for preparing polyolefins |
| DE2461187A1 (de) * | 1973-12-27 | 1975-07-10 | Nippon Oil Co Ltd | Verfahren zur herstellung von polyolefinen |
| US4088812A (en) | 1973-12-27 | 1978-05-09 | Nippon Oil Company, Limited | Process for preparing polyolefins |
| US4027088A (en) | 1974-07-19 | 1977-05-31 | Nippon Oil Company Ltd. | Process of preparing polyolefins |
| US4021599A (en) | 1975-08-04 | 1977-05-03 | Gulf Research & Development Company | Olefin polymerization process and catalyst |
| US4167493A (en) | 1977-03-22 | 1979-09-11 | Arco Polymers, Inc. | High efficiency catalyst for high bulk density polyethylene |
| US5496782A (en) * | 1992-12-17 | 1996-03-05 | Solvay (Socie/ te/ Anonyme) | Catalyst system, use of this catalyst system for the (co)polymerization of olefins, process for preparing this catalyst system and olefin (co) polymerization process |
| US5719235A (en) * | 1992-12-17 | 1998-02-17 | Solvay (Societe Anonyme) | Catalyst system, use of this catalyst system for the (co)polymerization of olefins, process for preparing this catalyst system and olefin (co)polymerization process |
Also Published As
| Publication number | Publication date |
|---|---|
| FI48100B (enrdf_load_stackoverflow) | 1974-02-28 |
| DE1745415B1 (de) | 1972-06-29 |
| DE1745415C2 (de) | 1982-11-18 |
| CH477223A (fr) | 1969-08-31 |
| FR93816E (fr) | 1969-05-23 |
| SE374925B (enrdf_load_stackoverflow) | 1975-03-24 |
| AT278350B (de) | 1970-01-26 |
| ES346261A1 (es) | 1969-04-16 |
| NL6714024A (enrdf_load_stackoverflow) | 1968-04-22 |
| DK125425B (da) | 1973-02-19 |
| YU32533B (en) | 1975-02-28 |
| GR34924B (el) | 1968-07-22 |
| NL137056C (enrdf_load_stackoverflow) | |
| NO130009B (enrdf_load_stackoverflow) | 1974-06-24 |
| YU196467A (en) | 1974-08-31 |
| FI48100C (fi) | 1980-01-04 |
| BE705220A (enrdf_load_stackoverflow) | 1968-04-17 |
| SE359845B (enrdf_load_stackoverflow) | 1973-09-10 |
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