GB1101611A - Conversion of cycloalkane to cyclohydroperoxide, cycloalkanol, cycloalkanone and alkanedioic acid - Google Patents

Conversion of cycloalkane to cyclohydroperoxide, cycloalkanol, cycloalkanone and alkanedioic acid

Info

Publication number
GB1101611A
GB1101611A GB886165A GB886165A GB1101611A GB 1101611 A GB1101611 A GB 1101611A GB 886165 A GB886165 A GB 886165A GB 886165 A GB886165 A GB 886165A GB 1101611 A GB1101611 A GB 1101611A
Authority
GB
United Kingdom
Prior art keywords
cycloalkane
cycloalkanone
cycloalkanol
conversion
cyclohydroperoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB886165A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
US Filter Wallace and Tiernan Inc
Original Assignee
Wallace and Tiernan Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wallace and Tiernan Inc filed Critical Wallace and Tiernan Inc
Publication of GB1101611A publication Critical patent/GB1101611A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/316—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with oxides of nitrogen or nitrogen-containing mineral acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • C07C407/003—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A cycloalkane, in which the ring is at least C8, is oxidized, in the liquid state with free O2 in absence of an oxidation catalyst at 80-225 DEG , to a cycloalkyl hydroperoxide, the conversion to the latter of the cycloalkane being controlled to be not more than 30%. The product may be reduced (e.g. with a sulphide) to give a cycloalkanol/cycloalkanone mixture which may be oxidized with HNO3 to the corresponding alkanedioic acid. Specified starting materials are cyclooctane, cyclodecane and cyclododecane.
GB886165A 1964-03-03 1965-03-02 Conversion of cycloalkane to cyclohydroperoxide, cycloalkanol, cycloalkanone and alkanedioic acid Expired GB1101611A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US34915664A 1964-03-03 1964-03-03

Publications (1)

Publication Number Publication Date
GB1101611A true GB1101611A (en) 1968-01-31

Family

ID=23371138

Family Applications (2)

Application Number Title Priority Date Filing Date
GB886165A Expired GB1101611A (en) 1964-03-03 1965-03-02 Conversion of cycloalkane to cyclohydroperoxide, cycloalkanol, cycloalkanone and alkanedioic acid
GB2706167A Expired GB1101612A (en) 1964-03-03 1965-03-02 Nitric acid oxidation of cycloalkanols and cycloalkanones to alkanedioic acids

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB2706167A Expired GB1101612A (en) 1964-03-03 1965-03-02 Nitric acid oxidation of cycloalkanols and cycloalkanones to alkanedioic acids

Country Status (6)

Country Link
JP (1) JPS4826737B1 (en)
BE (1) BE660522A (en)
CH (1) CH467230A (en)
FR (1) FR1429569A (en)
GB (2) GB1101611A (en)
NL (1) NL6502597A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11370752B2 (en) 2017-02-03 2022-06-28 Evonik Operations Gmbh Process for preparing cyclododecanone

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL9201269A (en) * 1992-07-15 1994-02-01 Dsm Nv PROCESS FOR THE PREPARATION OF CYCLOHEXYL HYDROPEROXIDE.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11370752B2 (en) 2017-02-03 2022-06-28 Evonik Operations Gmbh Process for preparing cyclododecanone

Also Published As

Publication number Publication date
JPS4826737B1 (en) 1973-08-15
FR1429569A (en) 1966-02-25
CH467230A (en) 1969-01-15
GB1101612A (en) 1968-01-31
NL6502597A (en) 1965-09-06
BE660522A (en) 1965-09-02

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