GB1113075A - Process for the production of cyclohexanone - Google Patents
Process for the production of cyclohexanoneInfo
- Publication number
- GB1113075A GB1113075A GB4732666A GB4732666A GB1113075A GB 1113075 A GB1113075 A GB 1113075A GB 4732666 A GB4732666 A GB 4732666A GB 4732666 A GB4732666 A GB 4732666A GB 1113075 A GB1113075 A GB 1113075A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cyclohexanone
- cyclohexane
- cyclohexane oxidation
- production
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for producing cyclohexanone comprises oxidizing a liquid mixture of cyclohexane and cyclohexanol containing 0.04 to 0.85 mole of oxygen containing gas at elevated temperature and superatmospheric pressure in the presence of a metal cyclohexane oxidation catalyst which is insoluble in the reaction mixture and recovering the cyclohexanone thus produced. Preferred catalyst are manganese and cobalt in the forms of oxides or carbonates. Many other catalysts are specified. Known cyclohexane oxidation initiators may be employed in the process. Examples are furnished.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50421365A | 1965-10-23 | 1965-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1113075A true GB1113075A (en) | 1968-05-08 |
Family
ID=24005325
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4732666A Expired GB1113075A (en) | 1965-10-23 | 1966-10-21 | Process for the production of cyclohexanone |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE688741A (en) |
| DE (1) | DE1568048A1 (en) |
| GB (1) | GB1113075A (en) |
| NL (1) | NL6614908A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0063931A1 (en) * | 1981-04-29 | 1982-11-03 | Du Pont Canada Inc. | Catalytic oxidation of liquid cycloparaffins |
| CN110538668A (en) * | 2018-05-28 | 2019-12-06 | 中国石油化工股份有限公司 | Heteroatom-containing nano carbon material, preparation method thereof and cyclohexane oxidation method |
| CN110790659A (en) * | 2019-11-13 | 2020-02-14 | 江苏方时远略科技咨询有限公司 | Method for preparing cyclohexanone |
-
1966
- 1966-10-21 BE BE688741D patent/BE688741A/xx unknown
- 1966-10-21 NL NL6614908A patent/NL6614908A/xx unknown
- 1966-10-21 GB GB4732666A patent/GB1113075A/en not_active Expired
- 1966-10-21 DE DE19661568048 patent/DE1568048A1/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0063931A1 (en) * | 1981-04-29 | 1982-11-03 | Du Pont Canada Inc. | Catalytic oxidation of liquid cycloparaffins |
| CN110538668A (en) * | 2018-05-28 | 2019-12-06 | 中国石油化工股份有限公司 | Heteroatom-containing nano carbon material, preparation method thereof and cyclohexane oxidation method |
| CN110790659A (en) * | 2019-11-13 | 2020-02-14 | 江苏方时远略科技咨询有限公司 | Method for preparing cyclohexanone |
Also Published As
| Publication number | Publication date |
|---|---|
| BE688741A (en) | 1967-03-31 |
| NL6614908A (en) | 1967-04-24 |
| DE1568048A1 (en) | 1970-03-19 |
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