GB1113076A - Process for the production of cyclohexanone - Google Patents
Process for the production of cyclohexanoneInfo
- Publication number
- GB1113076A GB1113076A GB4732766A GB4732766A GB1113076A GB 1113076 A GB1113076 A GB 1113076A GB 4732766 A GB4732766 A GB 4732766A GB 4732766 A GB4732766 A GB 4732766A GB 1113076 A GB1113076 A GB 1113076A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cyclohexane
- cyclohexanone
- cyclohexanol
- production
- naphthenic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for producing cyclohexanone comprises oxidizing a liquid mixture of cyclohexane and cyclohexanol containing from 0.04 to 0.09 mole of cyclohexanol per mol. of cyclohexane, with an oxygen-containing gas at elevated temperature and superatmospheric pressure in the presence of a cyclohexane oxidation catalyst which is soluble in the reaction mixture and recovering the cyclohexanone thus produced. Preferred catalysts are cobalt and manganese salts of naphthenic, acetic and stearic acids. Organic peroxides, of which several are specified, hydrogen peroxide and sodium peroxide, may be employed as oxidation initiators. Examples are furnished.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50422765A | 1965-10-23 | 1965-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1113076A true GB1113076A (en) | 1968-05-08 |
Family
ID=24005383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4732766A Expired GB1113076A (en) | 1965-10-23 | 1966-10-21 | Process for the production of cyclohexanone |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE688742A (en) |
| DE (1) | DE1568049A1 (en) |
| GB (1) | GB1113076A (en) |
| NL (1) | NL6614909A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1326819C (en) * | 2004-11-15 | 2007-07-18 | 中国科学院大连化学物理研究所 | Accelerating agent for cyclohexane liquid-phase air oxidation reaction and its use |
-
1966
- 1966-10-21 DE DE19661568049 patent/DE1568049A1/en active Pending
- 1966-10-21 NL NL6614909A patent/NL6614909A/xx unknown
- 1966-10-21 GB GB4732766A patent/GB1113076A/en not_active Expired
- 1966-10-21 BE BE688742D patent/BE688742A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1326819C (en) * | 2004-11-15 | 2007-07-18 | 中国科学院大连化学物理研究所 | Accelerating agent for cyclohexane liquid-phase air oxidation reaction and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1568049A1 (en) | 1970-02-05 |
| NL6614909A (en) | 1967-04-24 |
| BE688742A (en) | 1967-03-31 |
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