GB1026971A - Oxidation of hydrocarbons to alcohols - Google Patents

Oxidation of hydrocarbons to alcohols

Info

Publication number
GB1026971A
GB1026971A GB3053/63A GB305363A GB1026971A GB 1026971 A GB1026971 A GB 1026971A GB 3053/63 A GB3053/63 A GB 3053/63A GB 305363 A GB305363 A GB 305363A GB 1026971 A GB1026971 A GB 1026971A
Authority
GB
United Kingdom
Prior art keywords
oxidation
hydrocarbons
alcohols
acid
dehydrated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3053/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon International Inc filed Critical Halcon International Inc
Publication of GB1026971A publication Critical patent/GB1026971A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Alcohols are produced by the liquid phase partial oxidation of hydrocarbons with molecular oxygen in the presence of a dehydrated form of ortho-boric acid, the reaction mixture being worked up to recover unreacted hydrocarbons and oxidation products including alcohols, the boron compound being recovered as orthoboric acid which is then dehydrated to metaboric acid in two successive stages at a temperature of from 75 to 300 DEG C. the metaboric acid then being recycled to the oxidation reaction step. Examples describe the oxidation of cyclohexane to cyclohexanol.
GB3053/63A 1962-02-01 1963-01-24 Oxidation of hydrocarbons to alcohols Expired GB1026971A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17060762A 1962-02-01 1962-02-01

Publications (1)

Publication Number Publication Date
GB1026971A true GB1026971A (en) 1966-04-20

Family

ID=22620573

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3053/63A Expired GB1026971A (en) 1962-02-01 1963-01-24 Oxidation of hydrocarbons to alcohols

Country Status (7)

Country Link
BE (1) BE627494A (en)
CH (1) CH416619A (en)
DE (1) DE1468619A1 (en)
ES (1) ES284765A1 (en)
GB (1) GB1026971A (en)
LU (1) LU43086A1 (en)
SE (1) SE325267B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3987069A (en) 1971-08-09 1976-10-19 Petro-Tex Chemical Corporation Preparation of oxirane compounds by autoxidation
US5708246A (en) * 1996-08-28 1998-01-13 Battelle Memorial Institute Method of photocatalytic conversion of C-H organics

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3987069A (en) 1971-08-09 1976-10-19 Petro-Tex Chemical Corporation Preparation of oxirane compounds by autoxidation
US5708246A (en) * 1996-08-28 1998-01-13 Battelle Memorial Institute Method of photocatalytic conversion of C-H organics

Also Published As

Publication number Publication date
SE325267B (en) 1970-06-29
ES284765A1 (en) 1963-06-01
BE627494A (en)
LU43086A1 (en) 1964-07-26
DE1468619A1 (en) 1969-01-23
CH416619A (en) 1966-07-15

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