GB1087221A - 12-aminonaphthindolizinediones and processes for their manufacture - Google Patents
12-aminonaphthindolizinediones and processes for their manufactureInfo
- Publication number
- GB1087221A GB1087221A GB10520/63A GB1052063A GB1087221A GB 1087221 A GB1087221 A GB 1087221A GB 10520/63 A GB10520/63 A GB 10520/63A GB 1052063 A GB1052063 A GB 1052063A GB 1087221 A GB1087221 A GB 1087221A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zinc
- aqueous sodium
- aminonaphthindolizinediones
- alkaline
- sulphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
Abstract
Novel 12-aminonaphthindolizinediones of the formula <FORM:1087221/C2/1> wherein Y is H or one CH3 group are obtained by treating the corresponding 12-nitro compound with an appropriate reducing agent. The reduction may suitably be carried out by heating the 12-nitronaphthindolizinedione with acid stannous chloride, iron powder under B<\>aechamp conditions, zinc and glacial acetic acid, alkaline ferrous hydroxide, alkaline glucose, zinc and dilute aqueous NaOH, aqueous sodium hydrosulphite, aqueous sodium or potassium sulphide, ammonium sulphide, or a zinc dust/ethanol mixture. The product may be isolated from the reaction mixture by filtration, washing and recrystallization from o-dichlorobenzene, monochlorobenzene or nitrobenzene. The products may be converted into acylated or aroylated amino derivatives or azomethine derivatives from which dyestuffs or pigments can be produced.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB23604/66A GB1087222A (en) | 1963-03-16 | 1963-03-16 | 12-nitronaphthindolizinediones and processes for their manufacture |
GB10520/63A GB1087221A (en) | 1963-03-16 | 1963-03-16 | 12-aminonaphthindolizinediones and processes for their manufacture |
CH288764A CH426836A (en) | 1963-03-16 | 1964-03-06 | Process for the preparation of naphthindolizinquinones |
GB12287/64A GB1090633A (en) | 1963-03-16 | 1964-03-24 | Aminobenzonaphthindolizinediones |
GB13701/66A GB1090635A (en) | 1963-03-16 | 1964-03-24 | Benzonaphthindolizinediones |
GB551065A GB1090634A (en) | 1963-03-16 | 1965-02-09 | Benzonaphthindolizinediones |
US442190A US3336317A (en) | 1963-03-16 | 1965-03-23 | Substituted naphthindolizinequinones |
FR10446A FR87588E (en) | 1963-03-16 | 1965-03-24 | Napthtindolizine-quinones and their preparation |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB10520/63A GB1087221A (en) | 1963-03-16 | 1963-03-16 | 12-aminonaphthindolizinediones and processes for their manufacture |
GB12287/64A GB1090633A (en) | 1963-03-16 | 1964-03-24 | Aminobenzonaphthindolizinediones |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1087221A true GB1087221A (en) | 1967-10-18 |
Family
ID=26247575
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23604/66A Expired GB1087222A (en) | 1963-03-16 | 1963-03-16 | 12-nitronaphthindolizinediones and processes for their manufacture |
GB10520/63A Expired GB1087221A (en) | 1963-03-16 | 1963-03-16 | 12-aminonaphthindolizinediones and processes for their manufacture |
GB12287/64A Expired GB1090633A (en) | 1963-03-16 | 1964-03-24 | Aminobenzonaphthindolizinediones |
GB13701/66A Expired GB1090635A (en) | 1963-03-16 | 1964-03-24 | Benzonaphthindolizinediones |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23604/66A Expired GB1087222A (en) | 1963-03-16 | 1963-03-16 | 12-nitronaphthindolizinediones and processes for their manufacture |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB12287/64A Expired GB1090633A (en) | 1963-03-16 | 1964-03-24 | Aminobenzonaphthindolizinediones |
GB13701/66A Expired GB1090635A (en) | 1963-03-16 | 1964-03-24 | Benzonaphthindolizinediones |
Country Status (3)
Country | Link |
---|---|
US (1) | US3336317A (en) |
CH (1) | CH426836A (en) |
GB (4) | GB1087222A (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1459137A (en) * | 1973-05-30 | 1976-12-22 | Sandoz Ltd | Naphthoquinone derivatives |
CA1268178A (en) * | 1984-05-03 | 1990-04-24 | Gordon H. Phillipps | Isoquinoline derivatives |
NO872963L (en) * | 1986-07-29 | 1988-02-01 | Glaxo Group Ltd | Isoquinoline derivatives. |
DK616087A (en) * | 1986-11-27 | 1988-05-28 | Glaxo Group Ltd | ISOQUINOLINE DERIVATIVES AND PHARMACEUTICAL PREPARATIONS CONTAINING THEM |
GB8800312D0 (en) * | 1988-01-07 | 1988-02-10 | Glaxo Group Ltd | Process |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2850503A (en) * | 1958-09-02 | Preparation of methyl and ethyl n- | ||
US2439120A (en) * | 1946-10-26 | 1948-04-06 | Eastman Kodak Co | 1-nitro-3-alkylanthrapyridone compounds and process for their preparation |
US3121086A (en) * | 1961-05-29 | 1964-02-11 | Du Pont | Naphthofuroquinolinediones and naphthofuroisoquinolinediones |
-
1963
- 1963-03-16 GB GB23604/66A patent/GB1087222A/en not_active Expired
- 1963-03-16 GB GB10520/63A patent/GB1087221A/en not_active Expired
-
1964
- 1964-03-06 CH CH288764A patent/CH426836A/en unknown
- 1964-03-24 GB GB12287/64A patent/GB1090633A/en not_active Expired
- 1964-03-24 GB GB13701/66A patent/GB1090635A/en not_active Expired
-
1965
- 1965-03-23 US US442190A patent/US3336317A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
GB1090635A (en) | 1967-11-15 |
GB1087222A (en) | 1967-10-18 |
CH426836A (en) | 1966-12-31 |
GB1090633A (en) | 1967-11-15 |
US3336317A (en) | 1967-08-15 |
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