GB688784A - Producing same vat dyestuffs of the phthalocyanine series and a process of - Google Patents

Producing same vat dyestuffs of the phthalocyanine series and a process of

Info

Publication number
GB688784A
GB688784A GB28519/50A GB2851950A GB688784A GB 688784 A GB688784 A GB 688784A GB 28519/50 A GB28519/50 A GB 28519/50A GB 2851950 A GB2851950 A GB 2851950A GB 688784 A GB688784 A GB 688784A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
vat
metal hydroxide
chloride
hydroxide solutions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28519/50A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB688784A publication Critical patent/GB688784A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B47/00Porphines; Azaporphines
    • C09B47/04Phthalocyanines abbreviation: Pc
    • C09B47/08Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
    • C09B47/24Obtaining compounds having —COOH or —SO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Vat dyestuffs are made by treating iron, nickel, or cobalt phthalocyanines insoluble in aqueous alkali metal hydroxide solutions at elevated temperatures and in presence of a diluent liquid at the reaction temperature with phosgene, oxalyl chloride, or sulphuryl chloride under such conditions as to time and temperature that, after saponifying introduced acid chloride groups, the dyestuffs have become vattable in alkaline hyposulphite solution, but remain substantially insoluble in aqueous alkali metal hydroxide solutions. The products contain one carboxylic group to 1-4 mols. phthalocyanine, or one sulpho group to 2-120 mols. The phthalocyanines may contain non-solubilizing substituents such as methyl, ethyl, propyl, hydroxyethyl, halogen, amino, nitro, and aryl. The products probably contain acid chloride groups which may be saponified in the vat or specially with alkali metal hydroxide solutions. They dye cotton blue shades from the vat. Examples describe the above reactions conducted in an aluminium chloride-sodium chloride melt or in trichlorbenzene. Specifications 496,970 and 510,901 are referred to.
GB28519/50A 1949-11-24 1950-11-22 Producing same vat dyestuffs of the phthalocyanine series and a process of Expired GB688784A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE688784X 1949-11-24

Publications (1)

Publication Number Publication Date
GB688784A true GB688784A (en) 1953-03-11

Family

ID=6598567

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28519/50A Expired GB688784A (en) 1949-11-24 1950-11-22 Producing same vat dyestuffs of the phthalocyanine series and a process of

Country Status (1)

Country Link
GB (1) GB688784A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2862929A (en) * 1955-03-18 1958-12-02 Ciba Ltd Process for halogenating compounds having a tetraza-porphin structure
US3009919A (en) * 1956-08-30 1961-11-21 Gen Aniline & Film Corp Phthalocyanine vat dyes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2862929A (en) * 1955-03-18 1958-12-02 Ciba Ltd Process for halogenating compounds having a tetraza-porphin structure
US3009919A (en) * 1956-08-30 1961-11-21 Gen Aniline & Film Corp Phthalocyanine vat dyes

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