GB1066709A - A process for the oxidation of unsaturated carbonyl compounds - Google Patents
A process for the oxidation of unsaturated carbonyl compoundsInfo
- Publication number
- GB1066709A GB1066709A GB37926/65A GB3792665A GB1066709A GB 1066709 A GB1066709 A GB 1066709A GB 37926/65 A GB37926/65 A GB 37926/65A GB 3792665 A GB3792665 A GB 3792665A GB 1066709 A GB1066709 A GB 1066709A
- Authority
- GB
- United Kingdom
- Prior art keywords
- products
- oxidation
- organic phase
- ethylenically unsaturated
- give
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 150000001728 carbonyl compounds Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- PLELHVCQAULGBH-OUKQBFOZSA-N (e)-1,3-diphenylbut-2-en-1-one Chemical compound C=1C=CC=CC=1C(/C)=C/C(=O)C1=CC=CC=C1 PLELHVCQAULGBH-OUKQBFOZSA-N 0.000 abstract 1
- GGBXJDKSEHTBLW-UHFFFAOYSA-N 5-methylhex-4-en-2-one Chemical compound CC(C)=CCC(C)=O GGBXJDKSEHTBLW-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- GGCLNOIGPMGLDB-GYKMGIIDSA-N cholest-5-en-3-one Chemical compound C1C=C2CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 GGCLNOIGPMGLDB-GYKMGIIDSA-N 0.000 abstract 1
- 150000001879 copper Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 abstract 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 abstract 1
- 125000005594 diketone group Chemical group 0.000 abstract 1
- 238000006471 dimerization reaction Methods 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
- C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/32—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by aldehydo- or ketonic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07J—STEROIDS
- C07J9/00—Normal steroids containing carbon, hydrogen, halogen or oxygen substituted in position 17 beta by a chain of more than two carbon atoms, e.g. cholane, cholestane, coprostane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL6410417A NL6410417A (enExample) | 1964-09-08 | 1964-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1066709A true GB1066709A (en) | 1967-04-26 |
Family
ID=19790964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB37926/65A Expired GB1066709A (en) | 1964-09-08 | 1965-09-06 | A process for the oxidation of unsaturated carbonyl compounds |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3354220A (enExample) |
| BE (1) | BE669244A (enExample) |
| DE (1) | DE1261510B (enExample) |
| FR (1) | FR1446246A (enExample) |
| GB (1) | GB1066709A (enExample) |
| NL (1) | NL6410417A (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3944620A (en) * | 1974-07-10 | 1976-03-16 | Firmenich S.A. | Process for the preparation of oxophorones |
| US4010205A (en) * | 1973-12-07 | 1977-03-01 | Firmenich S.A. | Process for the preparation of a diketone derivative |
| US4046813A (en) * | 1974-04-11 | 1977-09-06 | Hoffmann-La Roche Inc. | Process for producing ketoisophorone |
| RU2263657C1 (ru) * | 2004-05-06 | 2005-11-10 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ получения 1,3-дифенилбут-2-ен-1-она |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2303785A1 (fr) * | 1975-03-11 | 1976-10-08 | Rhone Poulenc Ind | Procede d'oxydation de cetones b-ethyleniques |
| FR2335487A1 (fr) * | 1975-12-19 | 1977-07-15 | Rhone Poulenc Ind | Procede de preparation de trimethyl-3,5,5 cyclohexene-2 dione-1,4 |
| JPH0819030B2 (ja) * | 1987-10-06 | 1996-02-28 | 曽田香料株式会社 | ３，５，５−トリメチルシクロヘキサ−２−エン−１，４−ジオンの製造方法 |
| DE19619570A1 (de) * | 1996-05-15 | 1997-11-20 | Degussa | Verfahren zur Herstellung von Ketoisophoron |
| JPH11342340A (ja) * | 1998-06-01 | 1999-12-14 | Daicel Chem Ind Ltd | 酸化触媒系及びそれを用いたケトイソホロンの製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2648638A (en) * | 1950-01-19 | 1953-08-11 | Socony Vacuum Oil Co Inc | Method for preparing a tellurium oxide-containing catalyst |
| US2688041A (en) * | 1951-01-26 | 1954-08-31 | Socony Vacuum Oil Co Inc | Tellurium catalyst and method of selective oxidation |
| US2883426A (en) * | 1956-10-05 | 1959-04-21 | Shell Dev | Process for the preparation of aldehydes and ketones |
-
1964
- 1964-09-08 NL NL6410417A patent/NL6410417A/xx unknown
-
1965
- 1965-04-30 US US452389A patent/US3354220A/en not_active Expired - Lifetime
- 1965-09-06 BE BE669244D patent/BE669244A/xx unknown
- 1965-09-06 FR FR30525A patent/FR1446246A/fr not_active Expired
- 1965-09-06 DE DES99259A patent/DE1261510B/de active Pending
- 1965-09-06 GB GB37926/65A patent/GB1066709A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4010205A (en) * | 1973-12-07 | 1977-03-01 | Firmenich S.A. | Process for the preparation of a diketone derivative |
| US4046813A (en) * | 1974-04-11 | 1977-09-06 | Hoffmann-La Roche Inc. | Process for producing ketoisophorone |
| US3944620A (en) * | 1974-07-10 | 1976-03-16 | Firmenich S.A. | Process for the preparation of oxophorones |
| RU2263657C1 (ru) * | 2004-05-06 | 2005-11-10 | Открытое акционерное общество "Нижнекамскнефтехим" | Способ получения 1,3-дифенилбут-2-ен-1-она |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1261510B (de) | 1968-02-22 |
| US3354220A (en) | 1967-11-21 |
| FR1446246A (fr) | 1966-07-15 |
| BE669244A (enExample) | 1966-03-07 |
| NL6410417A (enExample) | 1966-03-09 |
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