FR2187774A1 - 1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst - Google Patents

1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst

Info

Publication number
FR2187774A1
FR2187774A1 FR7221528A FR7221528A FR2187774A1 FR 2187774 A1 FR2187774 A1 FR 2187774A1 FR 7221528 A FR7221528 A FR 7221528A FR 7221528 A FR7221528 A FR 7221528A FR 2187774 A1 FR2187774 A1 FR 2187774A1
Authority
FR
France
Prior art keywords
prodn
epoxidation
epoxide
olefins
molecular oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7221528A
Other languages
French (fr)
Other versions
FR2187774B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7221528A priority Critical patent/FR2187774A1/en
Publication of FR2187774A1 publication Critical patent/FR2187774A1/en
Application granted granted Critical
Publication of FR2187774B1 publication Critical patent/FR2187774B1/fr
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase

Abstract

The catalyst contains (a) >=1 salt or complex of Mo or W, selected from peroxide cpds. of Mo or W complexed by (in)organic amides, and from Mo or W carboxylates, and (b) 1 salt or chelated of Fe, V, Ni, Ti or Zr, e.g. as the di-pi-cyclopentadienyl-, polyphthalocyanine- or dithiolate. Reaction is effected at 20-220 degrees C, using a catalyst concn. of 1-10-5 gm. atom metal/kg. charge.
FR7221528A 1972-06-14 1972-06-14 1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst Granted FR2187774A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7221528A FR2187774A1 (en) 1972-06-14 1972-06-14 1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7221528A FR2187774A1 (en) 1972-06-14 1972-06-14 1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst

Publications (2)

Publication Number Publication Date
FR2187774A1 true FR2187774A1 (en) 1974-01-18
FR2187774B1 FR2187774B1 (en) 1974-07-26

Family

ID=9100229

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7221528A Granted FR2187774A1 (en) 1972-06-14 1972-06-14 1,2-Epoxide prodn - by epoxidation of olefins with molecular oxygen using bimetallic catalyst

Country Status (1)

Country Link
FR (1) FR2187774A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4521609A (en) * 1983-07-01 1985-06-04 Texaco Inc. Cycloalkane epoxides produced by air oxidation of cycloalkenes over lead zirconate as catalyst
US5041142A (en) * 1990-03-23 1991-08-20 Lever Brothers Company, Division Of Conopco Inc. Peroxymetallates and their use as bleach activating catalysts

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2044007A5 (en) * 1969-05-05 1971-02-19 Inst Francais Du Petrole Epoxidising olefins using a transition metal - catalyst

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2044007A5 (en) * 1969-05-05 1971-02-19 Inst Francais Du Petrole Epoxidising olefins using a transition metal - catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4521609A (en) * 1983-07-01 1985-06-04 Texaco Inc. Cycloalkane epoxides produced by air oxidation of cycloalkenes over lead zirconate as catalyst
US5041142A (en) * 1990-03-23 1991-08-20 Lever Brothers Company, Division Of Conopco Inc. Peroxymetallates and their use as bleach activating catalysts

Also Published As

Publication number Publication date
FR2187774B1 (en) 1974-07-26

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ST Notification of lapse