GB1041946A - Production of carbonyl compounds - Google Patents

Production of carbonyl compounds

Info

Publication number
GB1041946A
GB1041946A GB21212/65A GB2121265A GB1041946A GB 1041946 A GB1041946 A GB 1041946A GB 21212/65 A GB21212/65 A GB 21212/65A GB 2121265 A GB2121265 A GB 2121265A GB 1041946 A GB1041946 A GB 1041946A
Authority
GB
United Kingdom
Prior art keywords
hydroperoxide
atom
catalyst
cumene
carbonyl compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21212/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Halcon International Inc filed Critical Halcon International Inc
Publication of GB1041946A publication Critical patent/GB1041946A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A process for producing carbonyl compounds comprises oxidizing an olefinic material with 2-20 C atoms, and at least one H atom attached to an unsaturated C atom, with an organic hydroperoxide, in the presence of a platinum group (i.e. Pd, Pt, Ru, Rh, Os or Ir) catalyst. The olefinic material may be straight chained or cyclic or aromatic, and may contain more than one double bond. It may also bear additional substituents, e.g. Cl. The products are generally ketones, exceptions being CH3CHO from CH2 = CH2, and aldehydes in general from dienes, e.g. butadiene yields crotonaldehyde. As organic hydroperoxides there may be used cumene hydroperoxide, t-butyl hydroperoxide, cyclohexyl hydroperoxide or a -phenethyl hydroperoxide. Preferred types are derived from an aralkyl hydrocarbon having at least one H atom on the C atom adjacent to the ring, e.g. cumene and ethylbenzene. Ketone and hydroxy hydroperoxides may also be used. The catalyst is preferably derived from Pd, and is most suitably a soluble salt thereof, e.g. chloride, nitrate or sulphate, used in an amount between 10-4-10-1 parts by weight per part of hydroperoxide. Reaction temperature is usually - 20 DEG - + 200 DEG C. at atmospheric pressure, but pressures up to 50 At. may be used. The reaction is preferably conducted in an acidic aqueous solution, but non-aqueous solvents may be present.
GB21212/65A 1964-05-20 1965-05-19 Production of carbonyl compounds Expired GB1041946A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36901764A 1964-05-20 1964-05-20

Publications (1)

Publication Number Publication Date
GB1041946A true GB1041946A (en) 1966-09-07

Family

ID=23453709

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21212/65A Expired GB1041946A (en) 1964-05-20 1965-05-19 Production of carbonyl compounds

Country Status (6)

Country Link
BE (1) BE664011A (en)
DE (1) DE1518991A1 (en)
ES (1) ES313179A1 (en)
FR (1) FR1454420A (en)
GB (1) GB1041946A (en)
NL (1) NL6505941A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0174194A2 (en) * 1984-09-05 1986-03-12 The British Petroleum Company P.L.C. Process for the oxidation of alkanes
EP0331590A1 (en) * 1988-03-03 1989-09-06 Rhone-Poulenc Chimie Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3940446A (en) * 1971-07-08 1976-02-24 Universal Oil Products Company Dehydrogenation of alcohols
CH643226A5 (en) * 1978-12-18 1984-05-30 Inst Francais Du Petrole PROCESS FOR THE MANUFACTURE OF CARBONYL COMPOUNDS BY OXIDATION OF OLEFINIC COMPOUNDS.
FR2446271A1 (en) * 1979-01-11 1980-08-08 Inst Francais Du Petrole Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0174194A2 (en) * 1984-09-05 1986-03-12 The British Petroleum Company P.L.C. Process for the oxidation of alkanes
EP0174194A3 (en) * 1984-09-05 1987-05-20 The British Petroleum Company P.L.C. Process for the oxidation of hydrocarbons
AU600431B2 (en) * 1984-09-05 1990-08-16 British Petroleum Company Plc, The Process for the oxidation of hydrocarbons
EP0331590A1 (en) * 1988-03-03 1989-09-06 Rhone-Poulenc Chimie Process for the catalytic oxidation of alkanes and aralkyl hydrocarbons into a mixture of alcohols and ketones
FR2628101A1 (en) * 1988-03-03 1989-09-08 Rhone Poulenc Chimie PROCESS FOR THE CATALYTIC OXIDATION OF ALKANES IN MIXTURES OF ALCOHOLS AND KETONES
US4918238A (en) * 1988-03-03 1990-04-17 Rhone-Poulenc Chimie Catalytic oxidation of alkanes into alcohol/ketone mixtures

Also Published As

Publication number Publication date
ES313179A1 (en) 1965-07-16
BE664011A (en) 1965-11-17
NL6505941A (en) 1965-11-22
FR1454420A (en) 1966-02-11
DE1518991A1 (en) 1969-08-21

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