FR2446271A1 - Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80) - Google Patents

Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)

Info

Publication number
FR2446271A1
FR2446271A1 FR7900828A FR7900828A FR2446271A1 FR 2446271 A1 FR2446271 A1 FR 2446271A1 FR 7900828 A FR7900828 A FR 7900828A FR 7900828 A FR7900828 A FR 7900828A FR 2446271 A1 FR2446271 A1 FR 2446271A1
Authority
FR
France
Prior art keywords
prodn
liq
olefin
hydrogen peroxide
complex catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR7900828A
Other languages
French (fr)
Inventor
Hubert Mimoun
Robert Charpentier
Michel Roussel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR7900828A priority Critical patent/FR2446271A1/en
Priority to CH1095879A priority patent/CH643226A5/en
Priority to DE19792949847 priority patent/DE2949847A1/en
Priority to IT28027/79A priority patent/IT1126576B/en
Priority to GB7943413A priority patent/GB2037768B/en
Priority to US06/104,941 priority patent/US4310704A/en
Publication of FR2446271A1 publication Critical patent/FR2446271A1/en
Priority to US06/265,488 priority patent/US4379942A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Carbonyl cpds. are produced in the liq. phase by oxidn. of olefins R-CH=CH-R' in which R and R' are each H or 1-20 C hydrocarbyl, or together form an alkylene gp. The reaction is carried out in the presence of (a) A catalyst of formula PdAA'Lm in which A and A' may be the same or different, A is fluoroborate, acetate or trifluoroacetate and A' is as for A or pi-allyl or OOR1 in which R1 is a hydrocarbon gp., m = O or 2, and L is a ligand chosen from amine, phosphine, arsine, stibine and amide; and (b) an oxidising agent chosen from H2O2 and organic peroxides R2OOH in which R2 is a tert. hydrocarbon gp., alkyl, aralkyl or alkylaryl with 4-20 C. Process is carried out in the absence of Cl ion, so that problems of corrosion are avoided. The process uses salts and complexes of a single metal (Pd) and gives high selectivity to the prodn. of the desired carbonyl cpds. with a wide range of olefin starting materials.
FR7900828A 1978-12-18 1979-01-11 Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80) Withdrawn FR2446271A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
FR7900828A FR2446271A1 (en) 1979-01-11 1979-01-11 Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)
CH1095879A CH643226A5 (en) 1978-12-18 1979-12-11 PROCESS FOR THE MANUFACTURE OF CARBONYL COMPOUNDS BY OXIDATION OF OLEFINIC COMPOUNDS.
DE19792949847 DE2949847A1 (en) 1978-12-18 1979-12-12 METHOD FOR PRODUCING CARBONYL COMPOUNDS BY OXIDATION OF OLEFINS
IT28027/79A IT1126576B (en) 1978-12-18 1979-12-17 CARBONYLATE COMPOUNDS MANUFACTURING PROCESS FOR OXIDATION OF OLEFINIC COMPOUNDS
GB7943413A GB2037768B (en) 1978-12-18 1979-12-17 Manufacture of carbonyl compounds
US06/104,941 US4310704A (en) 1978-12-18 1979-12-18 Process for manufacturing methyl ketones by oxidation of terminal olefins
US06/265,488 US4379942A (en) 1978-12-18 1981-05-20 Process for manufacturing methyl ketones by oxidation of terminal olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7900828A FR2446271A1 (en) 1979-01-11 1979-01-11 Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)

Publications (1)

Publication Number Publication Date
FR2446271A1 true FR2446271A1 (en) 1980-08-08

Family

ID=9220719

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7900828A Withdrawn FR2446271A1 (en) 1978-12-18 1979-01-11 Carbonyl cpds. prodn. - by liq. phase oxidn. of olefin(s) with hydrogen peroxide or organic hydroperoxide using palladium complex catalyst (BE 12.6.80)

Country Status (1)

Country Link
FR (1) FR2446271A1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1454420A (en) * 1964-05-20 1966-02-11 Halcon International Inc Process for preparing ketone and aldehyde by catalytic oxidation of olefin
FR2214677A1 (en) * 1973-01-24 1974-08-19 Burmah Oil Trading Ltd

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1454420A (en) * 1964-05-20 1966-02-11 Halcon International Inc Process for preparing ketone and aldehyde by catalytic oxidation of olefin
FR2214677A1 (en) * 1973-01-24 1974-08-19 Burmah Oil Trading Ltd
US3891711A (en) * 1973-01-24 1975-06-24 Burmah Oil Trading Ltd Production of ketones

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ST Notification of lapse