SE330008B - - Google Patents

Info

Publication number
SE330008B
SE330008B SE1612865A SE1612865A SE330008B SE 330008 B SE330008 B SE 330008B SE 1612865 A SE1612865 A SE 1612865A SE 1612865 A SE1612865 A SE 1612865A SE 330008 B SE330008 B SE 330008B
Authority
SE
Sweden
Prior art keywords
carbon
olefin
catalyst
carbon monoxide
fraction
Prior art date
Application number
SE1612865A
Inventor
Winkle J Van
U Hasserodt
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SE330008B publication Critical patent/SE330008B/xx

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2423—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Aldehydes and/or alcohols are obtained by reacting an olefin with carbon monoxide and hydrogen in the presence of a complex catalyst comprising cobalt, carbon monoxide and a tertiary five-membered heterocyclic phosphine, one of the members of the heterocyclic structure being a phosphorus atom. The reaction may be effected at 100-300 DEG C. and a pressure of 20.4-102 atmospheres and an inert organic solvent may be present. The catalyst may have the empirical formula <FORM:1110549/C2/1> where Q represents 1,4-hydrocarbylene, suitably containing from 4 to 32 carbon atoms, R represents hydrocarbyl, suitably of from 4 to 30 carbon atoms, m and n are integers, each having a value of at least 1 and whose sum is 4, and x is an integer from 1 to 3 and the molar ratio of catalyst to olefin in the reaction zone is generally less than 1:1. The olefin starting material may be any aliphatic or cycloaliphatic compound having at least one ethylenic carbon-to-carbon bond and it may be a mixture of olefins or an olefinic hydrocarbon fraction, such as a polymeric olefinic fraction or a cracked wax fraction. The catalysts may be obtained by mixing a cobalt salt with the phosphine ligand in the liquid phase and subsequently heating the product in an atmosphere of hydrogen and carbon monoxide, or heating dicobalt octacarbonyl with the phosphine ligand.
SE1612865A 1964-12-14 1965-12-13 SE330008B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41829664A 1964-12-14 1964-12-14

Publications (1)

Publication Number Publication Date
SE330008B true SE330008B (en) 1970-11-02

Family

ID=23657523

Family Applications (1)

Application Number Title Priority Date Filing Date
SE1612865A SE330008B (en) 1964-12-14 1965-12-13

Country Status (7)

Country Link
BE (1) BE673624A (en)
DE (1) DE1282633C2 (en)
ES (1) ES320627A1 (en)
FR (1) FR1458029A (en)
GB (1) GB1110549A (en)
NL (1) NL145215B (en)
SE (1) SE330008B (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1768391C2 (en) * 1968-05-09 1979-03-22 Basf Ag, 6700 Ludwigshafen Process for the preparation of aldehydes and alcohols according to the oxo synthesis
DE19921730A1 (en) * 1999-05-12 2000-11-16 Basf Ag Aldehyde preparation by hydroformylation of olefins uses (new) sub-group VIII catalysts with phospholyl or polyphospholyl complexing ligands, also useful in olefin hydrocyanation
JP4013217B2 (en) * 2002-01-31 2007-11-28 高砂香料工業株式会社 A novel phosphine compound, a transition metal complex having the compound as a ligand, and an asymmetric synthesis catalyst containing the complex.
CN115555053A (en) * 2022-09-22 2023-01-03 中化泉州石化有限公司 Ligand compound and application thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1146485B (en) * 1960-04-21 1963-04-04 Diamond Alkali Co Process for the production of aldehydes by the oxo synthesis and catalyst for this
BE606408A (en) * 1960-07-22
FR1290452A (en) * 1961-04-20 1962-04-13 Diamond Alkali Co Improvements to the process for preparing aldehydes, in particular by the oxo reaction

Also Published As

Publication number Publication date
DE1282633C2 (en) 1976-05-13
GB1110549A (en) 1968-04-18
ES320627A1 (en) 1966-06-01
NL6516164A (en) 1966-06-15
FR1458029A (en) 1966-11-04
DE1282633B (en) 1968-11-14
NL145215B (en) 1975-03-17
BE673624A (en) 1966-06-13

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