GB1110549A - A process for the preparation of aldehydes and/or alcohols - Google Patents

A process for the preparation of aldehydes and/or alcohols

Info

Publication number
GB1110549A
GB1110549A GB5286865A GB5286865A GB1110549A GB 1110549 A GB1110549 A GB 1110549A GB 5286865 A GB5286865 A GB 5286865A GB 5286865 A GB5286865 A GB 5286865A GB 1110549 A GB1110549 A GB 1110549A
Authority
GB
United Kingdom
Prior art keywords
carbon
olefin
catalyst
carbon monoxide
fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5286865A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1110549A publication Critical patent/GB1110549A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
    • B01J31/2423—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Aldehydes and/or alcohols are obtained by reacting an olefin with carbon monoxide and hydrogen in the presence of a complex catalyst comprising cobalt, carbon monoxide and a tertiary five-membered heterocyclic phosphine, one of the members of the heterocyclic structure being a phosphorus atom. The reaction may be effected at 100-300 DEG C. and a pressure of 20.4-102 atmospheres and an inert organic solvent may be present. The catalyst may have the empirical formula <FORM:1110549/C2/1> where Q represents 1,4-hydrocarbylene, suitably containing from 4 to 32 carbon atoms, R represents hydrocarbyl, suitably of from 4 to 30 carbon atoms, m and n are integers, each having a value of at least 1 and whose sum is 4, and x is an integer from 1 to 3 and the molar ratio of catalyst to olefin in the reaction zone is generally less than 1:1. The olefin starting material may be any aliphatic or cycloaliphatic compound having at least one ethylenic carbon-to-carbon bond and it may be a mixture of olefins or an olefinic hydrocarbon fraction, such as a polymeric olefinic fraction or a cracked wax fraction. The catalysts may be obtained by mixing a cobalt salt with the phosphine ligand in the liquid phase and subsequently heating the product in an atmosphere of hydrogen and carbon monoxide, or heating dicobalt octacarbonyl with the phosphine ligand.
GB5286865A 1964-12-14 1965-12-13 A process for the preparation of aldehydes and/or alcohols Expired GB1110549A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41829664A 1964-12-14 1964-12-14

Publications (1)

Publication Number Publication Date
GB1110549A true GB1110549A (en) 1968-04-18

Family

ID=23657523

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5286865A Expired GB1110549A (en) 1964-12-14 1965-12-13 A process for the preparation of aldehydes and/or alcohols

Country Status (7)

Country Link
BE (1) BE673624A (en)
DE (1) DE1282633C2 (en)
ES (1) ES320627A1 (en)
FR (1) FR1458029A (en)
GB (1) GB1110549A (en)
NL (1) NL145215B (en)
SE (1) SE330008B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000069801A1 (en) * 1999-05-12 2000-11-23 Basf Aktiengesellschaft Eta 5-phospholyl complexes and eta 5-polyphospholyl complexes and their use in hydroformylation
CN115555053A (en) * 2022-09-22 2023-01-03 中化泉州石化有限公司 Ligand compound and application thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1768391C2 (en) * 1968-05-09 1979-03-22 Basf Ag, 6700 Ludwigshafen Process for the preparation of aldehydes and alcohols according to the oxo synthesis
JP4013217B2 (en) * 2002-01-31 2007-11-28 高砂香料工業株式会社 A novel phosphine compound, a transition metal complex having the compound as a ligand, and an asymmetric synthesis catalyst containing the complex.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1146485B (en) * 1960-04-21 1963-04-04 Diamond Alkali Co Process for the production of aldehydes by the oxo synthesis and catalyst for this
NL146830C (en) * 1960-07-22
FR1290452A (en) * 1961-04-20 1962-04-13 Diamond Alkali Co Improvements to the process for preparing aldehydes, in particular by the oxo reaction

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000069801A1 (en) * 1999-05-12 2000-11-23 Basf Aktiengesellschaft Eta 5-phospholyl complexes and eta 5-polyphospholyl complexes and their use in hydroformylation
CN115555053A (en) * 2022-09-22 2023-01-03 中化泉州石化有限公司 Ligand compound and application thereof

Also Published As

Publication number Publication date
SE330008B (en) 1970-11-02
BE673624A (en) 1966-06-13
ES320627A1 (en) 1966-06-01
NL6516164A (en) 1966-06-15
DE1282633C2 (en) 1976-05-13
FR1458029A (en) 1966-11-04
DE1282633B (en) 1968-11-14
NL145215B (en) 1975-03-17

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