GB1029175A - Process for the preparation of carbonyl compounds - Google Patents

Process for the preparation of carbonyl compounds

Info

Publication number
GB1029175A
GB1029175A GB21162/63A GB2116263A GB1029175A GB 1029175 A GB1029175 A GB 1029175A GB 21162/63 A GB21162/63 A GB 21162/63A GB 2116263 A GB2116263 A GB 2116263A GB 1029175 A GB1029175 A GB 1029175A
Authority
GB
United Kingdom
Prior art keywords
compound
ethylene
preparation
group
carbonyl compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21162/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1029175A publication Critical patent/GB1029175A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

A carbonyl compound is prepared by reacting an olefin in the gaseous phase with molecular oxygen at a temperature below 350 DEG C. in the presence of water vapour, and of a halogen and/or a hydrogen halide, and of a catalyst comprising (a) a solid carrier, (b) a compound of a precious metal of Group VIII, (c) a compound of Fe, Co, Ni or a transition metal of Group I or VII and (d) a compound of an alkali metal having an atomic number from 11 to 55 inclusive. Olefins which may be so oxidized are ethylene, propylene, butane-1, pentene-1, butene-2, styrene, cyclopentene, butadiene, pentadiene-1 : 4 and isoprene. The products may be aldehydes, ketones or carboxylic acids. Examples comparatively describe the conversion of ethylene to acetaldehyde and acetic acid.
GB21162/63A 1962-05-29 1963-05-27 Process for the preparation of carbonyl compounds Expired GB1029175A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL279024 1962-05-29

Publications (1)

Publication Number Publication Date
GB1029175A true GB1029175A (en) 1966-05-11

Family

ID=19753855

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21162/63A Expired GB1029175A (en) 1962-05-29 1963-05-27 Process for the preparation of carbonyl compounds

Country Status (3)

Country Link
US (1) US3293291A (en)
ES (1) ES288401A1 (en)
GB (1) GB1029175A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528401A (en) * 1982-09-21 1985-07-09 Exxon Research & Engineering Co. Catalytic process for the manufacture of ketones
US4560805A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalysts and process for the conversion of olefins to ketones
US4560804A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalytic process for the manufacture of ketones
US4560803A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalysts and process for oxidation of olefins to ketones
US4649223A (en) * 1983-07-25 1987-03-10 Exxon Research & Engineering Co. Catalysts and process for the conversion of olefins to ketones
US4737482A (en) * 1983-07-25 1988-04-12 Exxon Research & Engineering Co. Catalysts for oxidation of olefins to ketones
US4876392A (en) * 1982-09-21 1989-10-24 Exxon Research & Engineering Company Process for preparation of keystones by oxidation of secondary alcohols using a trimetallic catalyst comprising molybdenum, rhenium and a group VIII noble metal

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3534093A (en) * 1966-03-21 1970-10-13 Gulf Research Development Co Ethylene oxidation in the presence of palladium metal
US3485877A (en) * 1966-10-21 1969-12-23 Eastman Kodak Co Process for converting ethylenically unsaturated hydrocarbons to carbonylic compounds
US3923881A (en) * 1971-11-10 1975-12-02 Nat Distillers Chem Corp Process for the preparation of C{HD 4 {B dicarboxylic acids from 2-butene
CN114618519A (en) * 2020-12-11 2022-06-14 中国科学院大连化学物理研究所 Method for preparing methyl propionate by using supported bimetallic catalyst

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2690457A (en) * 1954-09-28 Process fok the production of un
US1871117A (en) * 1930-11-10 1932-08-09 Allan R Day Catalyst for vapor phase oxidation of organic compounds
US3057915A (en) * 1957-09-14 1962-10-09 Hoechst Ag Process for oxidizing olefins to aldehydes, ketones and acids

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4528401A (en) * 1982-09-21 1985-07-09 Exxon Research & Engineering Co. Catalytic process for the manufacture of ketones
US4560805A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalysts and process for the conversion of olefins to ketones
US4560804A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalytic process for the manufacture of ketones
US4560803A (en) * 1982-09-21 1985-12-24 Exxon Research & Engineering Co. Catalysts and process for oxidation of olefins to ketones
US4876392A (en) * 1982-09-21 1989-10-24 Exxon Research & Engineering Company Process for preparation of keystones by oxidation of secondary alcohols using a trimetallic catalyst comprising molybdenum, rhenium and a group VIII noble metal
US4649223A (en) * 1983-07-25 1987-03-10 Exxon Research & Engineering Co. Catalysts and process for the conversion of olefins to ketones
US4737482A (en) * 1983-07-25 1988-04-12 Exxon Research & Engineering Co. Catalysts for oxidation of olefins to ketones

Also Published As

Publication number Publication date
ES288401A1 (en) 1963-12-01
US3293291A (en) 1966-12-20

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